Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers

Autores
Mosiewicki, Mirna Alejandra; Aranguren, Mirta Ines; Borrajo Fernandez, Julio
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this study, rigid thermoset polymers were prepared from radical copolymerization of linseed oil monoglyceride maleates with styrene (St). First, linseed oil monoglycerides (LOMGs) were obtained from the reaction of linseed oil with glycerol at 220-240°C. Then, LOMGs were reacted with maleic anhydride at 80°C to produce the LOMG maleate half esters. The reactions were followed by FTIR spectroscopy and size exclusion chromatography (SEC) and the final resin was characterized by 1H-NMR spectroscopy. Finally, radical copolymerization of the LOMG maleates with 20,40,60, and 80% by weight of St was performed to produce rigid, thermoset polymers. The thermomechanical properties and fracture behavior of the cured copolymers, as a function of the percentage of St, were measured and analyzed. The copolymer with 40% by weight of St was the material with better mechanical and fracture behavior.
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
LINSEED OIL
LINSEED OIL MONOGLYCERIDE
MECHANICAL PROPERTIES
MONOGLYCERIDE MALEATES
THERMAL PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/94362
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/94362
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Mechanical properties of linseed oil monoglyceride maleate/styrene copolymersMosiewicki, Mirna AlejandraAranguren, Mirta InesBorrajo Fernandez, JulioLINSEED OILLINSEED OIL MONOGLYCERIDEMECHANICAL PROPERTIESMONOGLYCERIDE MALEATESTHERMAL PROPERTIEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In this study, rigid thermoset polymers were prepared from radical copolymerization of linseed oil monoglyceride maleates with styrene (St). First, linseed oil monoglycerides (LOMGs) were obtained from the reaction of linseed oil with glycerol at 220-240°C. Then, LOMGs were reacted with maleic anhydride at 80°C to produce the LOMG maleate half esters. The reactions were followed by FTIR spectroscopy and size exclusion chromatography (SEC) and the final resin was characterized by 1H-NMR spectroscopy. Finally, radical copolymerization of the LOMG maleates with 20,40,60, and 80% by weight of St was performed to produce rigid, thermoset polymers. The thermomechanical properties and fracture behavior of the cured copolymers, as a function of the percentage of St, were measured and analyzed. The copolymer with 40% by weight of St was the material with better mechanical and fracture behavior.Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaJohn Wiley & Sons Inc2005-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/94362Mosiewicki, Mirna Alejandra; Aranguren, Mirta Ines; Borrajo Fernandez, Julio; Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers; John Wiley & Sons Inc; Journal of Applied Polymer Science; 97; 3; 8-2005; 825-8360021-8995CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/app.21790info:eu-repo/semantics/altIdentifier/doi/10.1002/app.21790info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:06:10Zoai:ri.conicet.gov.ar:11336/94362instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:06:10.581CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
title Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
spellingShingle Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
Mosiewicki, Mirna Alejandra
LINSEED OIL
LINSEED OIL MONOGLYCERIDE
MECHANICAL PROPERTIES
MONOGLYCERIDE MALEATES
THERMAL PROPERTIES
title_short Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
title_full Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
title_fullStr Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
title_full_unstemmed Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
title_sort Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
dc.creator.none.fl_str_mv Mosiewicki, Mirna Alejandra
Aranguren, Mirta Ines
Borrajo Fernandez, Julio
author Mosiewicki, Mirna Alejandra
author_facet Mosiewicki, Mirna Alejandra
Aranguren, Mirta Ines
Borrajo Fernandez, Julio
author_role author
author2 Aranguren, Mirta Ines
Borrajo Fernandez, Julio
author2_role author
author
dc.subject.none.fl_str_mv LINSEED OIL
LINSEED OIL MONOGLYCERIDE
MECHANICAL PROPERTIES
MONOGLYCERIDE MALEATES
THERMAL PROPERTIES
topic LINSEED OIL
LINSEED OIL MONOGLYCERIDE
MECHANICAL PROPERTIES
MONOGLYCERIDE MALEATES
THERMAL PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this study, rigid thermoset polymers were prepared from radical copolymerization of linseed oil monoglyceride maleates with styrene (St). First, linseed oil monoglycerides (LOMGs) were obtained from the reaction of linseed oil with glycerol at 220-240°C. Then, LOMGs were reacted with maleic anhydride at 80°C to produce the LOMG maleate half esters. The reactions were followed by FTIR spectroscopy and size exclusion chromatography (SEC) and the final resin was characterized by 1H-NMR spectroscopy. Finally, radical copolymerization of the LOMG maleates with 20,40,60, and 80% by weight of St was performed to produce rigid, thermoset polymers. The thermomechanical properties and fracture behavior of the cured copolymers, as a function of the percentage of St, were measured and analyzed. The copolymer with 40% by weight of St was the material with better mechanical and fracture behavior.
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description In this study, rigid thermoset polymers were prepared from radical copolymerization of linseed oil monoglyceride maleates with styrene (St). First, linseed oil monoglycerides (LOMGs) were obtained from the reaction of linseed oil with glycerol at 220-240°C. Then, LOMGs were reacted with maleic anhydride at 80°C to produce the LOMG maleate half esters. The reactions were followed by FTIR spectroscopy and size exclusion chromatography (SEC) and the final resin was characterized by 1H-NMR spectroscopy. Finally, radical copolymerization of the LOMG maleates with 20,40,60, and 80% by weight of St was performed to produce rigid, thermoset polymers. The thermomechanical properties and fracture behavior of the cured copolymers, as a function of the percentage of St, were measured and analyzed. The copolymer with 40% by weight of St was the material with better mechanical and fracture behavior.
publishDate 2005
dc.date.none.fl_str_mv 2005-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/94362
Mosiewicki, Mirna Alejandra; Aranguren, Mirta Ines; Borrajo Fernandez, Julio; Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers; John Wiley & Sons Inc; Journal of Applied Polymer Science; 97; 3; 8-2005; 825-836
0021-8995
CONICET Digital
CONICET
url http://hdl.handle.net/11336/94362
identifier_str_mv Mosiewicki, Mirna Alejandra; Aranguren, Mirta Ines; Borrajo Fernandez, Julio; Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers; John Wiley & Sons Inc; Journal of Applied Polymer Science; 97; 3; 8-2005; 825-836
0021-8995
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/app.21790
info:eu-repo/semantics/altIdentifier/doi/10.1002/app.21790
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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