Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers

Autores
Herrera Gonzalez, Ana María; D'accorso, Norma Beatriz; García Serrano, Jesús; Cuevas Saurez, Carlos Enrique; Fascio, Mirta Liliana; Martins Alho, Miriam; Zamarripa Calderón, Juan Eliezer
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Three new bisglycidyl monomers; 1,4-bis((2-hydroxy-3-methacryloxypropoxy) methyl)benzene (MB-Phe-OH), 1,4-bis(2-hydroxy-3-methacryloxypropoxy)2-cis-butene (MB-Cis-OH), and 1,7-bis(2-hydroxy-3-methacryloxypropoxy)heptane (MB-1,7-OH); were synthesized and used as Bis-GMA/TEGDMA (bisphenolglycidyl methacrylate/triethylene glycol dimethacrylate) composite resin additives. Flexural properties and double bond conversion of the dental resins composed of silanizated inorganic filler and organic matrices containing new monomers were evaluated. The composite resins formulated, using the monomers MB-Cis-OH and MB-1,7-OH, have mechanical properties and double bond conversion comparable with those of Bis-GMA/TEGDMA composite resin used as control. The composite containing the new monomer MB-Phe-OH has better flexural properties (flexural strength 65.01 MPa and flexural modulus 5675.91 MPa) than the control composite resin (flexural strength 52.85 MPa and flexural modulus 4879.72 MPa); this could be attributed to the molecular structure of the monomer and its high double bond conversion level of 74.19%. The new bisglycidyl methacrylate monomer MB-Phe-OH could be potentially useful in the development of new organic matrices for dental composite resins with high double bond conversion and enhanced mechanical properties.
Fil: Herrera Gonzalez, Ana María. Universidad Autonoma del Estado de Hidalgo; México
Fil: D'accorso, Norma Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina. Universidad Autonoma del Estado de Hidalgo; México
Fil: García Serrano, Jesús. Universidad Autonoma del Estado de Hidalgo; México
Fil: Cuevas Saurez, Carlos Enrique. Universidad Autonoma del Estado de Hidalgo; México
Fil: Fascio, Mirta Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina. Universidad Autonoma del Estado de Hidalgo; México
Fil: Martins Alho, Miriam. Universidad Autonoma del Estado de Hidalgo; México
Fil: Zamarripa Calderón, Juan Eliezer. Universidad Autonoma del Estado de Hidalgo; México
Materia
Biomaterials
Composites
Crosslinking
Photopolymerization
Resins
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/8176
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/8176
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Composite resins based on novel and highly reactive bisglycidyl methacrylate monomersHerrera Gonzalez, Ana MaríaD'accorso, Norma BeatrizGarcía Serrano, JesúsCuevas Saurez, Carlos EnriqueFascio, Mirta LilianaMartins Alho, Miriam Zamarripa Calderón, Juan EliezerBiomaterialsCompositesCrosslinkingPhotopolymerizationResinshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Three new bisglycidyl monomers; 1,4-bis((2-hydroxy-3-methacryloxypropoxy) methyl)benzene (MB-Phe-OH), 1,4-bis(2-hydroxy-3-methacryloxypropoxy)2-cis-butene (MB-Cis-OH), and 1,7-bis(2-hydroxy-3-methacryloxypropoxy)heptane (MB-1,7-OH); were synthesized and used as Bis-GMA/TEGDMA (bisphenolglycidyl methacrylate/triethylene glycol dimethacrylate) composite resin additives. Flexural properties and double bond conversion of the dental resins composed of silanizated inorganic filler and organic matrices containing new monomers were evaluated. The composite resins formulated, using the monomers MB-Cis-OH and MB-1,7-OH, have mechanical properties and double bond conversion comparable with those of Bis-GMA/TEGDMA composite resin used as control. The composite containing the new monomer MB-Phe-OH has better flexural properties (flexural strength 65.01 MPa and flexural modulus 5675.91 MPa) than the control composite resin (flexural strength 52.85 MPa and flexural modulus 4879.72 MPa); this could be attributed to the molecular structure of the monomer and its high double bond conversion level of 74.19%. The new bisglycidyl methacrylate monomer MB-Phe-OH could be potentially useful in the development of new organic matrices for dental composite resins with high double bond conversion and enhanced mechanical properties.Fil: Herrera Gonzalez, Ana María. Universidad Autonoma del Estado de Hidalgo; MéxicoFil: D'accorso, Norma Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina. Universidad Autonoma del Estado de Hidalgo; MéxicoFil: García Serrano, Jesús. Universidad Autonoma del Estado de Hidalgo; MéxicoFil: Cuevas Saurez, Carlos Enrique. Universidad Autonoma del Estado de Hidalgo; MéxicoFil: Fascio, Mirta Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina. Universidad Autonoma del Estado de Hidalgo; MéxicoFil: Martins Alho, Miriam. Universidad Autonoma del Estado de Hidalgo; MéxicoFil: Zamarripa Calderón, Juan Eliezer. Universidad Autonoma del Estado de Hidalgo; MéxicoWiley2014-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/8176Herrera Gonzalez, Ana María; D'accorso, Norma Beatriz; García Serrano, Jesús; Cuevas Saurez, Carlos Enrique; Fascio, Mirta Liliana; et al.; Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers; Wiley; Journal of Applied Polymer Science; 131; 21; 11-2014; 40971-409801097-4628enginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/app.40971/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/app.40971info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:53Zoai:ri.conicet.gov.ar:11336/8176instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:53.444CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
title Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
spellingShingle Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
Herrera Gonzalez, Ana María
Biomaterials
Composites
Crosslinking
Photopolymerization
Resins
title_short Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
title_full Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
title_fullStr Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
title_full_unstemmed Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
title_sort Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
dc.creator.none.fl_str_mv Herrera Gonzalez, Ana María
D'accorso, Norma Beatriz
García Serrano, Jesús
Cuevas Saurez, Carlos Enrique
Fascio, Mirta Liliana
Martins Alho, Miriam
Zamarripa Calderón, Juan Eliezer
author Herrera Gonzalez, Ana María
author_facet Herrera Gonzalez, Ana María
D'accorso, Norma Beatriz
García Serrano, Jesús
Cuevas Saurez, Carlos Enrique
Fascio, Mirta Liliana
Martins Alho, Miriam
Zamarripa Calderón, Juan Eliezer
author_role author
author2 D'accorso, Norma Beatriz
García Serrano, Jesús
Cuevas Saurez, Carlos Enrique
Fascio, Mirta Liliana
Martins Alho, Miriam
Zamarripa Calderón, Juan Eliezer
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Biomaterials
Composites
Crosslinking
Photopolymerization
Resins
topic Biomaterials
Composites
Crosslinking
Photopolymerization
Resins
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Three new bisglycidyl monomers; 1,4-bis((2-hydroxy-3-methacryloxypropoxy) methyl)benzene (MB-Phe-OH), 1,4-bis(2-hydroxy-3-methacryloxypropoxy)2-cis-butene (MB-Cis-OH), and 1,7-bis(2-hydroxy-3-methacryloxypropoxy)heptane (MB-1,7-OH); were synthesized and used as Bis-GMA/TEGDMA (bisphenolglycidyl methacrylate/triethylene glycol dimethacrylate) composite resin additives. Flexural properties and double bond conversion of the dental resins composed of silanizated inorganic filler and organic matrices containing new monomers were evaluated. The composite resins formulated, using the monomers MB-Cis-OH and MB-1,7-OH, have mechanical properties and double bond conversion comparable with those of Bis-GMA/TEGDMA composite resin used as control. The composite containing the new monomer MB-Phe-OH has better flexural properties (flexural strength 65.01 MPa and flexural modulus 5675.91 MPa) than the control composite resin (flexural strength 52.85 MPa and flexural modulus 4879.72 MPa); this could be attributed to the molecular structure of the monomer and its high double bond conversion level of 74.19%. The new bisglycidyl methacrylate monomer MB-Phe-OH could be potentially useful in the development of new organic matrices for dental composite resins with high double bond conversion and enhanced mechanical properties.
Fil: Herrera Gonzalez, Ana María. Universidad Autonoma del Estado de Hidalgo; México
Fil: D'accorso, Norma Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina. Universidad Autonoma del Estado de Hidalgo; México
Fil: García Serrano, Jesús. Universidad Autonoma del Estado de Hidalgo; México
Fil: Cuevas Saurez, Carlos Enrique. Universidad Autonoma del Estado de Hidalgo; México
Fil: Fascio, Mirta Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina. Universidad Autonoma del Estado de Hidalgo; México
Fil: Martins Alho, Miriam. Universidad Autonoma del Estado de Hidalgo; México
Fil: Zamarripa Calderón, Juan Eliezer. Universidad Autonoma del Estado de Hidalgo; México
description Three new bisglycidyl monomers; 1,4-bis((2-hydroxy-3-methacryloxypropoxy) methyl)benzene (MB-Phe-OH), 1,4-bis(2-hydroxy-3-methacryloxypropoxy)2-cis-butene (MB-Cis-OH), and 1,7-bis(2-hydroxy-3-methacryloxypropoxy)heptane (MB-1,7-OH); were synthesized and used as Bis-GMA/TEGDMA (bisphenolglycidyl methacrylate/triethylene glycol dimethacrylate) composite resin additives. Flexural properties and double bond conversion of the dental resins composed of silanizated inorganic filler and organic matrices containing new monomers were evaluated. The composite resins formulated, using the monomers MB-Cis-OH and MB-1,7-OH, have mechanical properties and double bond conversion comparable with those of Bis-GMA/TEGDMA composite resin used as control. The composite containing the new monomer MB-Phe-OH has better flexural properties (flexural strength 65.01 MPa and flexural modulus 5675.91 MPa) than the control composite resin (flexural strength 52.85 MPa and flexural modulus 4879.72 MPa); this could be attributed to the molecular structure of the monomer and its high double bond conversion level of 74.19%. The new bisglycidyl methacrylate monomer MB-Phe-OH could be potentially useful in the development of new organic matrices for dental composite resins with high double bond conversion and enhanced mechanical properties.
publishDate 2014
dc.date.none.fl_str_mv 2014-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/8176
Herrera Gonzalez, Ana María; D'accorso, Norma Beatriz; García Serrano, Jesús; Cuevas Saurez, Carlos Enrique; Fascio, Mirta Liliana; et al.; Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers; Wiley; Journal of Applied Polymer Science; 131; 21; 11-2014; 40971-40980
1097-4628
url http://hdl.handle.net/11336/8176
identifier_str_mv Herrera Gonzalez, Ana María; D'accorso, Norma Beatriz; García Serrano, Jesús; Cuevas Saurez, Carlos Enrique; Fascio, Mirta Liliana; et al.; Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers; Wiley; Journal of Applied Polymer Science; 131; 21; 11-2014; 40971-40980
1097-4628
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/app.40971/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/app.40971
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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