Nitrate uptake from water by means of tailored adsorbents

Autores
Nunell, Gisel Vanesa; Fernandez, Maria Emilia; Bonelli, Pablo Ricardo; Cukierman, Ana Lea
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Two different adsorbents directed to nitrate removal from water were developed from Parkinsonia aculeata wood. An activated carbon was obtained by chemical activation with K2CO3 at 800 °C, whereas another adsorbent was prepared using a dilute solution of NH4Cl at 450 °C. Elemental compositions, surface functional groups, and textural parameters of both adsorbents were determined and compared with those of a commercial activated carbon used as a reference. Nitrate adsorption assays were carried out to examine the effects of solution pH, adsorbent dosage, contact time, and equilibrium adsorption isotherms. The adsorbent obtained with K2CO3 showed a well-developed pore structure (S BET∈=∈777 m2/g; V T∈=∈0.35 cm3/g) and neutral character, while the one prepared with NH4Cl exhibited a low porous development (S BET∈=∈58 m2/g; V T∈=∈0.03 cm3/g), acidic nature, and a noticeably high N content. The latter attained the highest nitrate removal efficiency, with a maximum adsorption capacity (X mL∈=∈0.40 mmol/g) higher than those estimated for the former (X mL∈=∈0.34 mmol/g) and the commercial sample (X mL∈=∈0.23 mmol/g), pointing to a predominant role of the chemical surface characteristics, mainly of N-containing groups and basic functionalities. Accordingly, the adsorbent obtained with NH4Cl represents a friendly novel material especially suited for nitrate removal.
Fil: Nunell, Gisel Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina
Fil: Fernandez, Maria Emilia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina
Fil: Bonelli, Pablo Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina
Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Activated Carbons
Ammonium Chloride
Nitrate Removal
Potassium Carbonate
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/59533
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/59533
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Nitrate uptake from water by means of tailored adsorbentsNunell, Gisel VanesaFernandez, Maria EmiliaBonelli, Pablo RicardoCukierman, Ana LeaActivated CarbonsAmmonium ChlorideNitrate RemovalPotassium Carbonatehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Two different adsorbents directed to nitrate removal from water were developed from Parkinsonia aculeata wood. An activated carbon was obtained by chemical activation with K2CO3 at 800 °C, whereas another adsorbent was prepared using a dilute solution of NH4Cl at 450 °C. Elemental compositions, surface functional groups, and textural parameters of both adsorbents were determined and compared with those of a commercial activated carbon used as a reference. Nitrate adsorption assays were carried out to examine the effects of solution pH, adsorbent dosage, contact time, and equilibrium adsorption isotherms. The adsorbent obtained with K2CO3 showed a well-developed pore structure (S BET∈=∈777 m2/g; V T∈=∈0.35 cm3/g) and neutral character, while the one prepared with NH4Cl exhibited a low porous development (S BET∈=∈58 m2/g; V T∈=∈0.03 cm3/g), acidic nature, and a noticeably high N content. The latter attained the highest nitrate removal efficiency, with a maximum adsorption capacity (X mL∈=∈0.40 mmol/g) higher than those estimated for the former (X mL∈=∈0.34 mmol/g) and the commercial sample (X mL∈=∈0.23 mmol/g), pointing to a predominant role of the chemical surface characteristics, mainly of N-containing groups and basic functionalities. Accordingly, the adsorbent obtained with NH4Cl represents a friendly novel material especially suited for nitrate removal.Fil: Nunell, Gisel Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; ArgentinaFil: Fernandez, Maria Emilia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; ArgentinaFil: Bonelli, Pablo Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; ArgentinaFil: Cukierman, Ana Lea. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaSpringer2015-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/59533Nunell, Gisel Vanesa; Fernandez, Maria Emilia; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Nitrate uptake from water by means of tailored adsorbents; Springer; Water, Air and Soil Pollution; 226; 8; 7-2015; 1-130049-69791573-2932CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s11270-015-2546-8info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11270-015-2546-8info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:10:48Zoai:ri.conicet.gov.ar:11336/59533instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:10:48.602CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Nitrate uptake from water by means of tailored adsorbents
title Nitrate uptake from water by means of tailored adsorbents
spellingShingle Nitrate uptake from water by means of tailored adsorbents
Nunell, Gisel Vanesa
Activated Carbons
Ammonium Chloride
Nitrate Removal
Potassium Carbonate
title_short Nitrate uptake from water by means of tailored adsorbents
title_full Nitrate uptake from water by means of tailored adsorbents
title_fullStr Nitrate uptake from water by means of tailored adsorbents
title_full_unstemmed Nitrate uptake from water by means of tailored adsorbents
title_sort Nitrate uptake from water by means of tailored adsorbents
dc.creator.none.fl_str_mv Nunell, Gisel Vanesa
Fernandez, Maria Emilia
Bonelli, Pablo Ricardo
Cukierman, Ana Lea
author Nunell, Gisel Vanesa
author_facet Nunell, Gisel Vanesa
Fernandez, Maria Emilia
Bonelli, Pablo Ricardo
Cukierman, Ana Lea
author_role author
author2 Fernandez, Maria Emilia
Bonelli, Pablo Ricardo
Cukierman, Ana Lea
author2_role author
author
author
dc.subject.none.fl_str_mv Activated Carbons
Ammonium Chloride
Nitrate Removal
Potassium Carbonate
topic Activated Carbons
Ammonium Chloride
Nitrate Removal
Potassium Carbonate
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Two different adsorbents directed to nitrate removal from water were developed from Parkinsonia aculeata wood. An activated carbon was obtained by chemical activation with K2CO3 at 800 °C, whereas another adsorbent was prepared using a dilute solution of NH4Cl at 450 °C. Elemental compositions, surface functional groups, and textural parameters of both adsorbents were determined and compared with those of a commercial activated carbon used as a reference. Nitrate adsorption assays were carried out to examine the effects of solution pH, adsorbent dosage, contact time, and equilibrium adsorption isotherms. The adsorbent obtained with K2CO3 showed a well-developed pore structure (S BET∈=∈777 m2/g; V T∈=∈0.35 cm3/g) and neutral character, while the one prepared with NH4Cl exhibited a low porous development (S BET∈=∈58 m2/g; V T∈=∈0.03 cm3/g), acidic nature, and a noticeably high N content. The latter attained the highest nitrate removal efficiency, with a maximum adsorption capacity (X mL∈=∈0.40 mmol/g) higher than those estimated for the former (X mL∈=∈0.34 mmol/g) and the commercial sample (X mL∈=∈0.23 mmol/g), pointing to a predominant role of the chemical surface characteristics, mainly of N-containing groups and basic functionalities. Accordingly, the adsorbent obtained with NH4Cl represents a friendly novel material especially suited for nitrate removal.
Fil: Nunell, Gisel Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina
Fil: Fernandez, Maria Emilia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina
Fil: Bonelli, Pablo Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina
Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Two different adsorbents directed to nitrate removal from water were developed from Parkinsonia aculeata wood. An activated carbon was obtained by chemical activation with K2CO3 at 800 °C, whereas another adsorbent was prepared using a dilute solution of NH4Cl at 450 °C. Elemental compositions, surface functional groups, and textural parameters of both adsorbents were determined and compared with those of a commercial activated carbon used as a reference. Nitrate adsorption assays were carried out to examine the effects of solution pH, adsorbent dosage, contact time, and equilibrium adsorption isotherms. The adsorbent obtained with K2CO3 showed a well-developed pore structure (S BET∈=∈777 m2/g; V T∈=∈0.35 cm3/g) and neutral character, while the one prepared with NH4Cl exhibited a low porous development (S BET∈=∈58 m2/g; V T∈=∈0.03 cm3/g), acidic nature, and a noticeably high N content. The latter attained the highest nitrate removal efficiency, with a maximum adsorption capacity (X mL∈=∈0.40 mmol/g) higher than those estimated for the former (X mL∈=∈0.34 mmol/g) and the commercial sample (X mL∈=∈0.23 mmol/g), pointing to a predominant role of the chemical surface characteristics, mainly of N-containing groups and basic functionalities. Accordingly, the adsorbent obtained with NH4Cl represents a friendly novel material especially suited for nitrate removal.
publishDate 2015
dc.date.none.fl_str_mv 2015-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/59533
Nunell, Gisel Vanesa; Fernandez, Maria Emilia; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Nitrate uptake from water by means of tailored adsorbents; Springer; Water, Air and Soil Pollution; 226; 8; 7-2015; 1-13
0049-6979
1573-2932
CONICET Digital
CONICET
url http://hdl.handle.net/11336/59533
identifier_str_mv Nunell, Gisel Vanesa; Fernandez, Maria Emilia; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Nitrate uptake from water by means of tailored adsorbents; Springer; Water, Air and Soil Pollution; 226; 8; 7-2015; 1-13
0049-6979
1573-2932
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s11270-015-2546-8
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11270-015-2546-8
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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