Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene

Autores
Ledesma, Gabriela Nanci; Signorella, Sandra Rosanna; Back, Davi; Schulz Lang, Ernesto
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound, C 26 H 23 BN 2 O 2, was obtained as by product during synthetic attempts of a complexation reaction between the tripodal ligand H 2 L [N,N-bis(2-hydroxybenzyl)(pyridin-2-yl)methylamine] and manganese(III) acetate in the presence of NaBPh 4. The isolated B-phenyl dioxazaborocine contains an N→B dative bond with a cis conformation. In the crystal, C-HO hydrogen bonds define chains parallel to the b-axis direction. A comparative analysis with other structurally related derivatives is also included, together with a rationalization of the unexpected production of this zwitterionic heterocycle.
Fil: Ledesma, Gabriela Nanci. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Signorella, Sandra Rosanna. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Back, Davi. Universidade Federal de Santa Maria; Brasil
Fil: Schulz Lang, Ernesto. Universidade Federal de Santa Maria; Brasil
Materia
B-Phenyldioxazaborocine
C-Ho Interactions
Crystal Structure
N-B Dative Bond
Zwitterionic Heterocycle
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/50589
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/50589
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-dieneLedesma, Gabriela NanciSignorella, Sandra RosannaBack, DaviSchulz Lang, ErnestoB-PhenyldioxazaborocineC-Ho InteractionsCrystal StructureN-B Dative BondZwitterionic Heterocyclehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The title compound, C 26 H 23 BN 2 O 2, was obtained as by product during synthetic attempts of a complexation reaction between the tripodal ligand H 2 L [N,N-bis(2-hydroxybenzyl)(pyridin-2-yl)methylamine] and manganese(III) acetate in the presence of NaBPh 4. The isolated B-phenyl dioxazaborocine contains an N→B dative bond with a cis conformation. In the crystal, C-HO hydrogen bonds define chains parallel to the b-axis direction. A comparative analysis with other structurally related derivatives is also included, together with a rationalization of the unexpected production of this zwitterionic heterocycle.Fil: Ledesma, Gabriela Nanci. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; ArgentinaFil: Signorella, Sandra Rosanna. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; ArgentinaFil: Back, Davi. Universidade Federal de Santa Maria; BrasilFil: Schulz Lang, Ernesto. Universidade Federal de Santa Maria; BrasilInternational Union of Crystallography2017-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/50589Ledesma, Gabriela Nanci; Signorella, Sandra Rosanna; Back, Davi; Schulz Lang, Ernesto; Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene; International Union of Crystallography; Acta Crystallographica Section E: Crystallographic Communications; 73; 11-2017; 1917-19202056-9890CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1107/S2056989017016553info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2056989017016553info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-26T08:58:36Zoai:ri.conicet.gov.ar:11336/50589instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-26 08:58:36.34CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene
title Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene
spellingShingle Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene
Ledesma, Gabriela Nanci
B-Phenyldioxazaborocine
C-Ho Interactions
Crystal Structure
N-B Dative Bond
Zwitterionic Heterocycle
title_short Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene
title_full Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene
title_fullStr Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene
title_full_unstemmed Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene
title_sort Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene
dc.creator.none.fl_str_mv Ledesma, Gabriela Nanci
Signorella, Sandra Rosanna
Back, Davi
Schulz Lang, Ernesto
author Ledesma, Gabriela Nanci
author_facet Ledesma, Gabriela Nanci
Signorella, Sandra Rosanna
Back, Davi
Schulz Lang, Ernesto
author_role author
author2 Signorella, Sandra Rosanna
Back, Davi
Schulz Lang, Ernesto
author2_role author
author
author
dc.subject.none.fl_str_mv B-Phenyldioxazaborocine
C-Ho Interactions
Crystal Structure
N-B Dative Bond
Zwitterionic Heterocycle
topic B-Phenyldioxazaborocine
C-Ho Interactions
Crystal Structure
N-B Dative Bond
Zwitterionic Heterocycle
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The title compound, C 26 H 23 BN 2 O 2, was obtained as by product during synthetic attempts of a complexation reaction between the tripodal ligand H 2 L [N,N-bis(2-hydroxybenzyl)(pyridin-2-yl)methylamine] and manganese(III) acetate in the presence of NaBPh 4. The isolated B-phenyl dioxazaborocine contains an N→B dative bond with a cis conformation. In the crystal, C-HO hydrogen bonds define chains parallel to the b-axis direction. A comparative analysis with other structurally related derivatives is also included, together with a rationalization of the unexpected production of this zwitterionic heterocycle.
Fil: Ledesma, Gabriela Nanci. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Signorella, Sandra Rosanna. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Back, Davi. Universidade Federal de Santa Maria; Brasil
Fil: Schulz Lang, Ernesto. Universidade Federal de Santa Maria; Brasil
description The title compound, C 26 H 23 BN 2 O 2, was obtained as by product during synthetic attempts of a complexation reaction between the tripodal ligand H 2 L [N,N-bis(2-hydroxybenzyl)(pyridin-2-yl)methylamine] and manganese(III) acetate in the presence of NaBPh 4. The isolated B-phenyl dioxazaborocine contains an N→B dative bond with a cis conformation. In the crystal, C-HO hydrogen bonds define chains parallel to the b-axis direction. A comparative analysis with other structurally related derivatives is also included, together with a rationalization of the unexpected production of this zwitterionic heterocycle.
publishDate 2017
dc.date.none.fl_str_mv 2017-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/50589
Ledesma, Gabriela Nanci; Signorella, Sandra Rosanna; Back, Davi; Schulz Lang, Ernesto; Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene; International Union of Crystallography; Acta Crystallographica Section E: Crystallographic Communications; 73; 11-2017; 1917-1920
2056-9890
CONICET Digital
CONICET
url http://hdl.handle.net/11336/50589
identifier_str_mv Ledesma, Gabriela Nanci; Signorella, Sandra Rosanna; Back, Davi; Schulz Lang, Ernesto; Crystal structure of cis-1-phenyl-8-(pyridin-2-ylmethyl)dibenzo[1,2-c:2,1-h ]-2,14-dioxa-8-aza-1-borabicyclo[4.4.0]deca-3,8-diene; International Union of Crystallography; Acta Crystallographica Section E: Crystallographic Communications; 73; 11-2017; 1917-1920
2056-9890
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1107/S2056989017016553
info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2056989017016553
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.011256

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