Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer

Autores
Perez Calderon, John Freddy; Santos, Maria Victoria; Zaritzky, Noemi Elisabet
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The presence of emulsified oils in wastewater from the petroleum and petrochemical industry causes a significant environmental concern. The effect of chitosan (CH) and sodium dodecyl sulfate (SDS) doses on the destabilization of emulsified wastewater was analyzed based on key parameters such as: residual turbidity (% RT), relative length of the clarified zone (CL), chemical oxygen demand (% COD) and zeta potential (ZP). A response surface methodology and central composite design were applied for optimizating the influence of CH and SDS doses, on the performance of the demulsification process. A desirability test allowed to calculate the optimal doses of CH and SDS to produce: i) minimum values of%RT and ZP and ii) maximum values of CL and % COD removal. A novel kinetic model based on first order equations for both stages: coagulation/flocculation and settling of the flocs was proposed to describe clarification using measurements of static dispersion of light and back scattering profiles (BS). The proposed model is a useful tool for predicting clarification times and to analyze the governing mechanisms of the process. Coagulation/flocculation occurs in less than 3 h reaching very low turbidity values in the clarified zone (<11% RT). Additionally, the BS profiles after 3 h showed that at the optimal dosage of CH and SDS 70% of the total volume was clarified with a total hydrocarbon removal of 98.61%. This study demonstrates that CH constitutes a potent flocculating/coagulating agent in waste-water emulsified systems from petroleum industry.
Fil: Perez Calderon, John Freddy. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
Fil: Santos, Maria Victoria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
Fil: Zaritzky, Noemi Elisabet. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina. Universidad Nacional de La Plata. Facultad de Ingeniería; Argentina
Materia
CHITOSAN
COAGULATION/FLOCCULATION
EMULSIFIED WASTEWATER
KINETICS MODELING
PROCESS OPTIMIZATION
SURFACTANT
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/86389
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/86389
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymerPerez Calderon, John FreddySantos, Maria VictoriaZaritzky, Noemi ElisabetCHITOSANCOAGULATION/FLOCCULATIONEMULSIFIED WASTEWATERKINETICS MODELINGPROCESS OPTIMIZATIONSURFACTANThttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The presence of emulsified oils in wastewater from the petroleum and petrochemical industry causes a significant environmental concern. The effect of chitosan (CH) and sodium dodecyl sulfate (SDS) doses on the destabilization of emulsified wastewater was analyzed based on key parameters such as: residual turbidity (% RT), relative length of the clarified zone (CL), chemical oxygen demand (% COD) and zeta potential (ZP). A response surface methodology and central composite design were applied for optimizating the influence of CH and SDS doses, on the performance of the demulsification process. A desirability test allowed to calculate the optimal doses of CH and SDS to produce: i) minimum values of%RT and ZP and ii) maximum values of CL and % COD removal. A novel kinetic model based on first order equations for both stages: coagulation/flocculation and settling of the flocs was proposed to describe clarification using measurements of static dispersion of light and back scattering profiles (BS). The proposed model is a useful tool for predicting clarification times and to analyze the governing mechanisms of the process. Coagulation/flocculation occurs in less than 3 h reaching very low turbidity values in the clarified zone (<11% RT). Additionally, the BS profiles after 3 h showed that at the optimal dosage of CH and SDS 70% of the total volume was clarified with a total hydrocarbon removal of 98.61%. This study demonstrates that CH constitutes a potent flocculating/coagulating agent in waste-water emulsified systems from petroleum industry.Fil: Perez Calderon, John Freddy. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaFil: Santos, Maria Victoria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaFil: Zaritzky, Noemi Elisabet. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina. Universidad Nacional de La Plata. Facultad de Ingeniería; ArgentinaElsevier Ltd2018-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/86389Perez Calderon, John Freddy; Santos, Maria Victoria; Zaritzky, Noemi Elisabet; Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer; Elsevier Ltd; Journal of Environmental Chemical Engineering; 6; 4; 8-2018; 3808-38182213-3437CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2018.06.004info:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S2213343718303105info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:49:12Zoai:ri.conicet.gov.ar:11336/86389instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:49:12.775CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer
title Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer
spellingShingle Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer
Perez Calderon, John Freddy
CHITOSAN
COAGULATION/FLOCCULATION
EMULSIFIED WASTEWATER
KINETICS MODELING
PROCESS OPTIMIZATION
SURFACTANT
title_short Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer
title_full Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer
title_fullStr Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer
title_full_unstemmed Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer
title_sort Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer
dc.creator.none.fl_str_mv Perez Calderon, John Freddy
Santos, Maria Victoria
Zaritzky, Noemi Elisabet
author Perez Calderon, John Freddy
author_facet Perez Calderon, John Freddy
Santos, Maria Victoria
Zaritzky, Noemi Elisabet
author_role author
author2 Santos, Maria Victoria
Zaritzky, Noemi Elisabet
author2_role author
author
dc.subject.none.fl_str_mv CHITOSAN
COAGULATION/FLOCCULATION
EMULSIFIED WASTEWATER
KINETICS MODELING
PROCESS OPTIMIZATION
SURFACTANT
topic CHITOSAN
COAGULATION/FLOCCULATION
EMULSIFIED WASTEWATER
KINETICS MODELING
PROCESS OPTIMIZATION
SURFACTANT
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The presence of emulsified oils in wastewater from the petroleum and petrochemical industry causes a significant environmental concern. The effect of chitosan (CH) and sodium dodecyl sulfate (SDS) doses on the destabilization of emulsified wastewater was analyzed based on key parameters such as: residual turbidity (% RT), relative length of the clarified zone (CL), chemical oxygen demand (% COD) and zeta potential (ZP). A response surface methodology and central composite design were applied for optimizating the influence of CH and SDS doses, on the performance of the demulsification process. A desirability test allowed to calculate the optimal doses of CH and SDS to produce: i) minimum values of%RT and ZP and ii) maximum values of CL and % COD removal. A novel kinetic model based on first order equations for both stages: coagulation/flocculation and settling of the flocs was proposed to describe clarification using measurements of static dispersion of light and back scattering profiles (BS). The proposed model is a useful tool for predicting clarification times and to analyze the governing mechanisms of the process. Coagulation/flocculation occurs in less than 3 h reaching very low turbidity values in the clarified zone (<11% RT). Additionally, the BS profiles after 3 h showed that at the optimal dosage of CH and SDS 70% of the total volume was clarified with a total hydrocarbon removal of 98.61%. This study demonstrates that CH constitutes a potent flocculating/coagulating agent in waste-water emulsified systems from petroleum industry.
Fil: Perez Calderon, John Freddy. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
Fil: Santos, Maria Victoria. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
Fil: Zaritzky, Noemi Elisabet. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina. Universidad Nacional de La Plata. Facultad de Ingeniería; Argentina
description The presence of emulsified oils in wastewater from the petroleum and petrochemical industry causes a significant environmental concern. The effect of chitosan (CH) and sodium dodecyl sulfate (SDS) doses on the destabilization of emulsified wastewater was analyzed based on key parameters such as: residual turbidity (% RT), relative length of the clarified zone (CL), chemical oxygen demand (% COD) and zeta potential (ZP). A response surface methodology and central composite design were applied for optimizating the influence of CH and SDS doses, on the performance of the demulsification process. A desirability test allowed to calculate the optimal doses of CH and SDS to produce: i) minimum values of%RT and ZP and ii) maximum values of CL and % COD removal. A novel kinetic model based on first order equations for both stages: coagulation/flocculation and settling of the flocs was proposed to describe clarification using measurements of static dispersion of light and back scattering profiles (BS). The proposed model is a useful tool for predicting clarification times and to analyze the governing mechanisms of the process. Coagulation/flocculation occurs in less than 3 h reaching very low turbidity values in the clarified zone (<11% RT). Additionally, the BS profiles after 3 h showed that at the optimal dosage of CH and SDS 70% of the total volume was clarified with a total hydrocarbon removal of 98.61%. This study demonstrates that CH constitutes a potent flocculating/coagulating agent in waste-water emulsified systems from petroleum industry.
publishDate 2018
dc.date.none.fl_str_mv 2018-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/86389
Perez Calderon, John Freddy; Santos, Maria Victoria; Zaritzky, Noemi Elisabet; Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer; Elsevier Ltd; Journal of Environmental Chemical Engineering; 6; 4; 8-2018; 3808-3818
2213-3437
CONICET Digital
CONICET
url http://hdl.handle.net/11336/86389
identifier_str_mv Perez Calderon, John Freddy; Santos, Maria Victoria; Zaritzky, Noemi Elisabet; Optimal clarification of emulsified oily wastewater using a surfactant/chitosan biopolymer; Elsevier Ltd; Journal of Environmental Chemical Engineering; 6; 4; 8-2018; 3808-3818
2213-3437
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2018.06.004
info:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S2213343718303105
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Ltd
publisher.none.fl_str_mv Elsevier Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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