Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups

Autores
Cuentas Gallegos, Ana Karina; López Cortina, S.; Brousse, T.; Pacheco Catalán, D.; Fuentes Quezada, Eduardo; Mosqueda, H.; Orozco Gamboa, G.
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, we show a comparative study based on the effects of specific chemical functional groups (–OH, –NH2), grafted on Vulcan carbon (VC) with the incorporation of a specific polyoxometalate (POM), PMo12 (H3PMo12O40), to improve electrochemical performance. We observed a decrease in the specific surface area of the grafted matrices (VC-OH and VC-NH2) [1], and the same trend was observed for PMo12 (POM) incorporation. Our electrochemical studies showed low concentrations of POM in unmodified VCs and higher POM concentrations for grafted matrices (VC-OH and VC-NH2) after 500 voltammetric cycles, especially for the VC grafted with –OH groups (VC-OH-POM). Mechanisms have been proposed for POM interaction with the grafted groups in carbon, emphasizing the role of aqueous medium and redox activity of POM. Cyclic voltammograms suggested the POM anchoring through –OH groups with a strong interaction as a covalent bond, resulting in a surface coverage of 1.66 × 10−11 mol cm−2. Surface modifications could be extrapolated to other carbons, and the materials could be employed for different potential applications such as photocatalysis, amperometric sensors, fuel cells, and supercapacitors.
Fil: Cuentas Gallegos, Ana Karina. Universidad Nacional Autónoma de México; México. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: López Cortina, S.. Universidad Autonoma de Nuevo Leon; México
Fil: Brousse, T.. Université de Nantes. Institut Des Materiaux Jean Rouxel; Francia
Fil: Pacheco Catalán, D.. Centro de Investigación Científica de Yucatán; México
Fil: Fuentes Quezada, Eduardo. Centro de Investigación y Desarrollo Tecnológico en Electroquímica; México. Universidad Nacional Autónoma de México; México. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mosqueda, H.. Universidad Autonoma de Nuevo Leon; México
Fil: Orozco Gamboa, G.. Centro de Investigación y Desarrollo Tecnológico en Electroquímica; México
Materia
Carbon
Grafting
Hybrid
Nanocomposites
Polyoxometalates
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/17505
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/17505
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groupsCuentas Gallegos, Ana KarinaLópez Cortina, S.Brousse, T.Pacheco Catalán, D.Fuentes Quezada, EduardoMosqueda, H.Orozco Gamboa, G.CarbonGraftingHybridNanocompositesPolyoxometalateshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In this work, we show a comparative study based on the effects of specific chemical functional groups (–OH, –NH2), grafted on Vulcan carbon (VC) with the incorporation of a specific polyoxometalate (POM), PMo12 (H3PMo12O40), to improve electrochemical performance. We observed a decrease in the specific surface area of the grafted matrices (VC-OH and VC-NH2) [1], and the same trend was observed for PMo12 (POM) incorporation. Our electrochemical studies showed low concentrations of POM in unmodified VCs and higher POM concentrations for grafted matrices (VC-OH and VC-NH2) after 500 voltammetric cycles, especially for the VC grafted with –OH groups (VC-OH-POM). Mechanisms have been proposed for POM interaction with the grafted groups in carbon, emphasizing the role of aqueous medium and redox activity of POM. Cyclic voltammograms suggested the POM anchoring through –OH groups with a strong interaction as a covalent bond, resulting in a surface coverage of 1.66 × 10−11 mol cm−2. Surface modifications could be extrapolated to other carbons, and the materials could be employed for different potential applications such as photocatalysis, amperometric sensors, fuel cells, and supercapacitors.Fil: Cuentas Gallegos, Ana Karina. Universidad Nacional Autónoma de México; México. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: López Cortina, S.. Universidad Autonoma de Nuevo Leon; MéxicoFil: Brousse, T.. Université de Nantes. Institut Des Materiaux Jean Rouxel; FranciaFil: Pacheco Catalán, D.. Centro de Investigación Científica de Yucatán; MéxicoFil: Fuentes Quezada, Eduardo. Centro de Investigación y Desarrollo Tecnológico en Electroquímica; México. Universidad Nacional Autónoma de México; México. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Mosqueda, H.. Universidad Autonoma de Nuevo Leon; MéxicoFil: Orozco Gamboa, G.. Centro de Investigación y Desarrollo Tecnológico en Electroquímica; MéxicoSpringer2016-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/17505Cuentas Gallegos, Ana Karina; López Cortina, S.; Brousse, T.; Pacheco Catalán, D.; Fuentes Quezada, Eduardo; et al.; Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups; Springer; Journal Of Solid State Electrochemistry (print); 20; 1; 1-2016; 67-791432-8488enginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10008-015-2994-5info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10008-015-2994-5info:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)https://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:10:01Zoai:ri.conicet.gov.ar:11336/17505instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:10:01.407CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups
title Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups
spellingShingle Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups
Cuentas Gallegos, Ana Karina
Carbon
Grafting
Hybrid
Nanocomposites
Polyoxometalates
title_short Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups
title_full Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups
title_fullStr Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups
title_full_unstemmed Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups
title_sort Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups
dc.creator.none.fl_str_mv Cuentas Gallegos, Ana Karina
López Cortina, S.
Brousse, T.
Pacheco Catalán, D.
Fuentes Quezada, Eduardo
Mosqueda, H.
Orozco Gamboa, G.
author Cuentas Gallegos, Ana Karina
author_facet Cuentas Gallegos, Ana Karina
López Cortina, S.
Brousse, T.
Pacheco Catalán, D.
Fuentes Quezada, Eduardo
Mosqueda, H.
Orozco Gamboa, G.
author_role author
author2 López Cortina, S.
Brousse, T.
Pacheco Catalán, D.
Fuentes Quezada, Eduardo
Mosqueda, H.
Orozco Gamboa, G.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Carbon
Grafting
Hybrid
Nanocomposites
Polyoxometalates
topic Carbon
Grafting
Hybrid
Nanocomposites
Polyoxometalates
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work, we show a comparative study based on the effects of specific chemical functional groups (–OH, –NH2), grafted on Vulcan carbon (VC) with the incorporation of a specific polyoxometalate (POM), PMo12 (H3PMo12O40), to improve electrochemical performance. We observed a decrease in the specific surface area of the grafted matrices (VC-OH and VC-NH2) [1], and the same trend was observed for PMo12 (POM) incorporation. Our electrochemical studies showed low concentrations of POM in unmodified VCs and higher POM concentrations for grafted matrices (VC-OH and VC-NH2) after 500 voltammetric cycles, especially for the VC grafted with –OH groups (VC-OH-POM). Mechanisms have been proposed for POM interaction with the grafted groups in carbon, emphasizing the role of aqueous medium and redox activity of POM. Cyclic voltammograms suggested the POM anchoring through –OH groups with a strong interaction as a covalent bond, resulting in a surface coverage of 1.66 × 10−11 mol cm−2. Surface modifications could be extrapolated to other carbons, and the materials could be employed for different potential applications such as photocatalysis, amperometric sensors, fuel cells, and supercapacitors.
Fil: Cuentas Gallegos, Ana Karina. Universidad Nacional Autónoma de México; México. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: López Cortina, S.. Universidad Autonoma de Nuevo Leon; México
Fil: Brousse, T.. Université de Nantes. Institut Des Materiaux Jean Rouxel; Francia
Fil: Pacheco Catalán, D.. Centro de Investigación Científica de Yucatán; México
Fil: Fuentes Quezada, Eduardo. Centro de Investigación y Desarrollo Tecnológico en Electroquímica; México. Universidad Nacional Autónoma de México; México. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mosqueda, H.. Universidad Autonoma de Nuevo Leon; México
Fil: Orozco Gamboa, G.. Centro de Investigación y Desarrollo Tecnológico en Electroquímica; México
description In this work, we show a comparative study based on the effects of specific chemical functional groups (–OH, –NH2), grafted on Vulcan carbon (VC) with the incorporation of a specific polyoxometalate (POM), PMo12 (H3PMo12O40), to improve electrochemical performance. We observed a decrease in the specific surface area of the grafted matrices (VC-OH and VC-NH2) [1], and the same trend was observed for PMo12 (POM) incorporation. Our electrochemical studies showed low concentrations of POM in unmodified VCs and higher POM concentrations for grafted matrices (VC-OH and VC-NH2) after 500 voltammetric cycles, especially for the VC grafted with –OH groups (VC-OH-POM). Mechanisms have been proposed for POM interaction with the grafted groups in carbon, emphasizing the role of aqueous medium and redox activity of POM. Cyclic voltammograms suggested the POM anchoring through –OH groups with a strong interaction as a covalent bond, resulting in a surface coverage of 1.66 × 10−11 mol cm−2. Surface modifications could be extrapolated to other carbons, and the materials could be employed for different potential applications such as photocatalysis, amperometric sensors, fuel cells, and supercapacitors.
publishDate 2016
dc.date.none.fl_str_mv 2016-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/17505
Cuentas Gallegos, Ana Karina; López Cortina, S.; Brousse, T.; Pacheco Catalán, D.; Fuentes Quezada, Eduardo; et al.; Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups; Springer; Journal Of Solid State Electrochemistry (print); 20; 1; 1-2016; 67-79
1432-8488
url http://hdl.handle.net/11336/17505
identifier_str_mv Cuentas Gallegos, Ana Karina; López Cortina, S.; Brousse, T.; Pacheco Catalán, D.; Fuentes Quezada, Eduardo; et al.; Electrochemical study of H3PMo12 retention on Vulcan carbon grafted with NH2 and OH groups; Springer; Journal Of Solid State Electrochemistry (print); 20; 1; 1-2016; 67-79
1432-8488
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s10008-015-2994-5
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10008-015-2994-5
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv Atribución-NoComercial-CompartirIgual 2.5 Argentina (CC BY-NC-SA 2.5 AR)
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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