Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions

Autores
Bonetto, Fernando Jose; Romero, Marcelo Ariel; Iglesias Garcia, Adalberto de Jesus; Vidal, Ricardo Alberto; Goldberg, Edith Catalina
Año de publicación
2015
Idioma
español castellano
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The formation of negative ions in the scattering of protons by a highly oriented pyrolytic graphite (HOPG) surface is theoretically and experimentally analyzed for a large scattering angle and compared with previous results obtained in the same system but for a forward scattering geometry. These experiments were motivated by the fact that the interaction of a hydrogen atom with a surface is the prototype system for studying the intra-atomic Coulomb repulsion in an s-like valence orbital localized in the atom. We tried to answer the open questions related to the electronic correlation effects and the influence of the detailed surface band structure by using appropriate theoretical models. The comparison with the experiment of theoretical results obtained by using different limit approximations of the electronic repulsion in the atomic state shows the expected validity ranges according to the ion velocity. However, the most remarkable conclusion obtained from this comparison is the nonvalidity of an adiabatic picture of the energy levels shifted by the interactions with the surface atoms, when the energy uncertainty introduced by the ion velocity becomes of the order of the electronic repulsion in the hydrogen ground state.
Fil: Bonetto, Fernando Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Departamento de Materiales; Argentina
Fil: Romero, Marcelo Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina
Fil: Iglesias Garcia, Adalberto de Jesus. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina
Fil: Vidal, Ricardo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Departamento de Fisica; Argentina
Fil: Goldberg, Edith Catalina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Departamento de Materiales; Argentina
Materia
Charge Transfer
Graphite
Atom-Solid Interaction
Low Energy Ion Scattering
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/4414
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite CollisionsBonetto, Fernando JoseRomero, Marcelo ArielIglesias Garcia, Adalberto de JesusVidal, Ricardo AlbertoGoldberg, Edith CatalinaCharge TransferGraphiteAtom-Solid InteractionLow Energy Ion Scatteringhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The formation of negative ions in the scattering of protons by a highly oriented pyrolytic graphite (HOPG) surface is theoretically and experimentally analyzed for a large scattering angle and compared with previous results obtained in the same system but for a forward scattering geometry. These experiments were motivated by the fact that the interaction of a hydrogen atom with a surface is the prototype system for studying the intra-atomic Coulomb repulsion in an s-like valence orbital localized in the atom. We tried to answer the open questions related to the electronic correlation effects and the influence of the detailed surface band structure by using appropriate theoretical models. The comparison with the experiment of theoretical results obtained by using different limit approximations of the electronic repulsion in the atomic state shows the expected validity ranges according to the ion velocity. However, the most remarkable conclusion obtained from this comparison is the nonvalidity of an adiabatic picture of the energy levels shifted by the interactions with the surface atoms, when the energy uncertainty introduced by the ion velocity becomes of the order of the electronic repulsion in the hydrogen ground state.Fil: Bonetto, Fernando Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Departamento de Materiales; ArgentinaFil: Romero, Marcelo Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; ArgentinaFil: Iglesias Garcia, Adalberto de Jesus. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; ArgentinaFil: Vidal, Ricardo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Departamento de Fisica; ArgentinaFil: Goldberg, Edith Catalina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Departamento de Materiales; ArgentinaAmerican Chemical Society2015-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/4414Bonetto, Fernando Jose; Romero, Marcelo Ariel; Iglesias Garcia, Adalberto de Jesus; Vidal, Ricardo Alberto; Goldberg, Edith Catalina; Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions; American Chemical Society; Journal of Physical Chemistry C; 119; 6; 1-2015; 3124-31311932-7447spainfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jp511339vinfo:eu-repo/semantics/altIdentifier/doi/DOI:10.1021/jp511339vinfo:eu-repo/semantics/altIdentifier/issn/1932-7447info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:07Zoai:ri.conicet.gov.ar:11336/4414instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:08.042CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions
title Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions
spellingShingle Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions
Bonetto, Fernando Jose
Charge Transfer
Graphite
Atom-Solid Interaction
Low Energy Ion Scattering
title_short Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions
title_full Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions
title_fullStr Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions
title_full_unstemmed Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions
title_sort Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions
dc.creator.none.fl_str_mv Bonetto, Fernando Jose
Romero, Marcelo Ariel
Iglesias Garcia, Adalberto de Jesus
Vidal, Ricardo Alberto
Goldberg, Edith Catalina
author Bonetto, Fernando Jose
author_facet Bonetto, Fernando Jose
Romero, Marcelo Ariel
Iglesias Garcia, Adalberto de Jesus
Vidal, Ricardo Alberto
Goldberg, Edith Catalina
author_role author
author2 Romero, Marcelo Ariel
Iglesias Garcia, Adalberto de Jesus
Vidal, Ricardo Alberto
Goldberg, Edith Catalina
author2_role author
author
author
author
dc.subject.none.fl_str_mv Charge Transfer
Graphite
Atom-Solid Interaction
Low Energy Ion Scattering
topic Charge Transfer
Graphite
Atom-Solid Interaction
Low Energy Ion Scattering
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The formation of negative ions in the scattering of protons by a highly oriented pyrolytic graphite (HOPG) surface is theoretically and experimentally analyzed for a large scattering angle and compared with previous results obtained in the same system but for a forward scattering geometry. These experiments were motivated by the fact that the interaction of a hydrogen atom with a surface is the prototype system for studying the intra-atomic Coulomb repulsion in an s-like valence orbital localized in the atom. We tried to answer the open questions related to the electronic correlation effects and the influence of the detailed surface band structure by using appropriate theoretical models. The comparison with the experiment of theoretical results obtained by using different limit approximations of the electronic repulsion in the atomic state shows the expected validity ranges according to the ion velocity. However, the most remarkable conclusion obtained from this comparison is the nonvalidity of an adiabatic picture of the energy levels shifted by the interactions with the surface atoms, when the energy uncertainty introduced by the ion velocity becomes of the order of the electronic repulsion in the hydrogen ground state.
Fil: Bonetto, Fernando Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Departamento de Materiales; Argentina
Fil: Romero, Marcelo Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina
Fil: Iglesias Garcia, Adalberto de Jesus. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina
Fil: Vidal, Ricardo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Departamento de Fisica; Argentina
Fil: Goldberg, Edith Catalina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Departamento de Materiales; Argentina
description The formation of negative ions in the scattering of protons by a highly oriented pyrolytic graphite (HOPG) surface is theoretically and experimentally analyzed for a large scattering angle and compared with previous results obtained in the same system but for a forward scattering geometry. These experiments were motivated by the fact that the interaction of a hydrogen atom with a surface is the prototype system for studying the intra-atomic Coulomb repulsion in an s-like valence orbital localized in the atom. We tried to answer the open questions related to the electronic correlation effects and the influence of the detailed surface band structure by using appropriate theoretical models. The comparison with the experiment of theoretical results obtained by using different limit approximations of the electronic repulsion in the atomic state shows the expected validity ranges according to the ion velocity. However, the most remarkable conclusion obtained from this comparison is the nonvalidity of an adiabatic picture of the energy levels shifted by the interactions with the surface atoms, when the energy uncertainty introduced by the ion velocity becomes of the order of the electronic repulsion in the hydrogen ground state.
publishDate 2015
dc.date.none.fl_str_mv 2015-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/4414
Bonetto, Fernando Jose; Romero, Marcelo Ariel; Iglesias Garcia, Adalberto de Jesus; Vidal, Ricardo Alberto; Goldberg, Edith Catalina; Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions; American Chemical Society; Journal of Physical Chemistry C; 119; 6; 1-2015; 3124-3131
1932-7447
url http://hdl.handle.net/11336/4414
identifier_str_mv Bonetto, Fernando Jose; Romero, Marcelo Ariel; Iglesias Garcia, Adalberto de Jesus; Vidal, Ricardo Alberto; Goldberg, Edith Catalina; Time - Energy Uncertainty and Electronic Correlation in H+ - Graphite Collisions; American Chemical Society; Journal of Physical Chemistry C; 119; 6; 1-2015; 3124-3131
1932-7447
dc.language.none.fl_str_mv spa
language spa
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jp511339v
info:eu-repo/semantics/altIdentifier/doi/DOI:10.1021/jp511339v
info:eu-repo/semantics/altIdentifier/issn/1932-7447
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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