Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends

Autores
Agazzi, Federico Martin; Falcone, Ruben Dario; Silber, Juana J.; Correa, Nestor Mariano
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We present results on a new system that forms non-aqueous reverse micelles (RMs) created with a cationic surfactant, benzyl-n-hexadecyldimethylammonium chloride (BHDC), encapsulating ethylene glycol (EG), in different nonpolar solvents blends of n-heptane:benzene. It is shown that a cationic surfactant forms RMs using EG as polar solvent without the addition of a co-surfactant. In particular, we analyzed the EG solubilization capacity, the droplet size values and the interface composition of EG/BHDC/n-heptane:benzene RMs, using dynamic light scattering (DLS) and the solvatochromic behavior of 1-methyl-8-oxyquinolinium betaine (QB) as molecular dye. The EG solubilization capacity depends on the external phase composition decreasing when the n-heptane content increases. Using DLS technique, we demonstrate the formation of RMs, and observe that for the same [EG]/[BHDC] ratio, the micellar size increases when n-heptane content increases. Using QB it was found that EG penetrates into the micellar interface changing dramatically the composition and the droplet-droplet interaction, in comparison when water is encapsulated.
Fil: Agazzi, Federico Martin. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Falcone, Ruben Dario. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Silber, Juana J.. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina
Fil: Correa, Nestor Mariano. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Bhdc
Dls
Non-Aqueous Reverse Micelles
Qb
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/72264
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blendsAgazzi, Federico MartinFalcone, Ruben DarioSilber, Juana J.Correa, Nestor MarianoBhdcDlsNon-Aqueous Reverse MicellesQbhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We present results on a new system that forms non-aqueous reverse micelles (RMs) created with a cationic surfactant, benzyl-n-hexadecyldimethylammonium chloride (BHDC), encapsulating ethylene glycol (EG), in different nonpolar solvents blends of n-heptane:benzene. It is shown that a cationic surfactant forms RMs using EG as polar solvent without the addition of a co-surfactant. In particular, we analyzed the EG solubilization capacity, the droplet size values and the interface composition of EG/BHDC/n-heptane:benzene RMs, using dynamic light scattering (DLS) and the solvatochromic behavior of 1-methyl-8-oxyquinolinium betaine (QB) as molecular dye. The EG solubilization capacity depends on the external phase composition decreasing when the n-heptane content increases. Using DLS technique, we demonstrate the formation of RMs, and observe that for the same [EG]/[BHDC] ratio, the micellar size increases when n-heptane content increases. Using QB it was found that EG penetrates into the micellar interface changing dramatically the composition and the droplet-droplet interaction, in comparison when water is encapsulated.Fil: Agazzi, Federico Martin. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Falcone, Ruben Dario. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Silber, Juana J.. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; ArgentinaFil: Correa, Nestor Mariano. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier Science2016-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/72264Agazzi, Federico Martin; Falcone, Ruben Dario; Silber, Juana J.; Correa, Nestor Mariano; Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 509; 11-2016; 467-4730927-7757CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2016.09.070info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0927775716308202info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:50:26Zoai:ri.conicet.gov.ar:11336/72264instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:50:26.301CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends
title Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends
spellingShingle Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends
Agazzi, Federico Martin
Bhdc
Dls
Non-Aqueous Reverse Micelles
Qb
title_short Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends
title_full Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends
title_fullStr Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends
title_full_unstemmed Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends
title_sort Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends
dc.creator.none.fl_str_mv Agazzi, Federico Martin
Falcone, Ruben Dario
Silber, Juana J.
Correa, Nestor Mariano
author Agazzi, Federico Martin
author_facet Agazzi, Federico Martin
Falcone, Ruben Dario
Silber, Juana J.
Correa, Nestor Mariano
author_role author
author2 Falcone, Ruben Dario
Silber, Juana J.
Correa, Nestor Mariano
author2_role author
author
author
dc.subject.none.fl_str_mv Bhdc
Dls
Non-Aqueous Reverse Micelles
Qb
topic Bhdc
Dls
Non-Aqueous Reverse Micelles
Qb
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We present results on a new system that forms non-aqueous reverse micelles (RMs) created with a cationic surfactant, benzyl-n-hexadecyldimethylammonium chloride (BHDC), encapsulating ethylene glycol (EG), in different nonpolar solvents blends of n-heptane:benzene. It is shown that a cationic surfactant forms RMs using EG as polar solvent without the addition of a co-surfactant. In particular, we analyzed the EG solubilization capacity, the droplet size values and the interface composition of EG/BHDC/n-heptane:benzene RMs, using dynamic light scattering (DLS) and the solvatochromic behavior of 1-methyl-8-oxyquinolinium betaine (QB) as molecular dye. The EG solubilization capacity depends on the external phase composition decreasing when the n-heptane content increases. Using DLS technique, we demonstrate the formation of RMs, and observe that for the same [EG]/[BHDC] ratio, the micellar size increases when n-heptane content increases. Using QB it was found that EG penetrates into the micellar interface changing dramatically the composition and the droplet-droplet interaction, in comparison when water is encapsulated.
Fil: Agazzi, Federico Martin. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Falcone, Ruben Dario. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Silber, Juana J.. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina
Fil: Correa, Nestor Mariano. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description We present results on a new system that forms non-aqueous reverse micelles (RMs) created with a cationic surfactant, benzyl-n-hexadecyldimethylammonium chloride (BHDC), encapsulating ethylene glycol (EG), in different nonpolar solvents blends of n-heptane:benzene. It is shown that a cationic surfactant forms RMs using EG as polar solvent without the addition of a co-surfactant. In particular, we analyzed the EG solubilization capacity, the droplet size values and the interface composition of EG/BHDC/n-heptane:benzene RMs, using dynamic light scattering (DLS) and the solvatochromic behavior of 1-methyl-8-oxyquinolinium betaine (QB) as molecular dye. The EG solubilization capacity depends on the external phase composition decreasing when the n-heptane content increases. Using DLS technique, we demonstrate the formation of RMs, and observe that for the same [EG]/[BHDC] ratio, the micellar size increases when n-heptane content increases. Using QB it was found that EG penetrates into the micellar interface changing dramatically the composition and the droplet-droplet interaction, in comparison when water is encapsulated.
publishDate 2016
dc.date.none.fl_str_mv 2016-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/72264
Agazzi, Federico Martin; Falcone, Ruben Dario; Silber, Juana J.; Correa, Nestor Mariano; Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 509; 11-2016; 467-473
0927-7757
CONICET Digital
CONICET
url http://hdl.handle.net/11336/72264
identifier_str_mv Agazzi, Federico Martin; Falcone, Ruben Dario; Silber, Juana J.; Correa, Nestor Mariano; Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 509; 11-2016; 467-473
0927-7757
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2016.09.070
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0927775716308202
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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