Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior

Autores
Bengoa, Leandro Nicolás; Tuckart, Walter Roberto; Zabala, Nicolás Ariel; Prieto, Germán; Egli, Walter Alfredo
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A high efficiency methane sulfonic acid electrolyte used for tin electrodeposition was studied, and the properties of the resulting deposits were compared to those of tin coatings obtained from an industrial phenol sulfonic acid electrolyte. Cyclic voltammetry was used to study the effect of organic additives on the reduction process to define the composition of the electrolytic bath. Thick tin electrodeposits were obtained on rotating cylinder steel electrodes and their surface morphology, preferred crystal orientation, surface roughness, micro hardness and tribological behaviour were measured. Smooth, adherent and bright tin coatings were obtained from the methane sulfonic acid electrolyte, which differed in morphology and texture from tin electrodeposited from the industrial bath. Influence of organic additives on preferred crystal orientation of the coatings was found to be stronger than changing the supporting sulfonic acid type. Tribological tests showed that the two types of deposits have a similar coefficient of friction. However, tin coatings obtained from methane sulfonic electrolytes presented a lower wear resistance and underwent galling at lower loads.
Fil: Bengoa, Leandro Nicolás. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina. Universidad Nacional de La Plata. Facultad de Ingeniería; Argentina
Fil: Tuckart, Walter Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería; Argentina
Fil: Zabala, Nicolás Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería; Argentina
Fil: Prieto, Germán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería; Argentina
Fil: Egli, Walter Alfredo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Materia
Tin
Phenol Sulfonic Acid
Methane Sulfonic Acid
Coatings
Tribology
Wear Resistance
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/45077
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/45077
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological BehaviorBengoa, Leandro NicolásTuckart, Walter RobertoZabala, Nicolás ArielPrieto, GermánEgli, Walter AlfredoTinPhenol Sulfonic AcidMethane Sulfonic AcidCoatingsTribologyWear Resistancehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2A high efficiency methane sulfonic acid electrolyte used for tin electrodeposition was studied, and the properties of the resulting deposits were compared to those of tin coatings obtained from an industrial phenol sulfonic acid electrolyte. Cyclic voltammetry was used to study the effect of organic additives on the reduction process to define the composition of the electrolytic bath. Thick tin electrodeposits were obtained on rotating cylinder steel electrodes and their surface morphology, preferred crystal orientation, surface roughness, micro hardness and tribological behaviour were measured. Smooth, adherent and bright tin coatings were obtained from the methane sulfonic acid electrolyte, which differed in morphology and texture from tin electrodeposited from the industrial bath. Influence of organic additives on preferred crystal orientation of the coatings was found to be stronger than changing the supporting sulfonic acid type. Tribological tests showed that the two types of deposits have a similar coefficient of friction. However, tin coatings obtained from methane sulfonic electrolytes presented a lower wear resistance and underwent galling at lower loads.Fil: Bengoa, Leandro Nicolás. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina. Universidad Nacional de La Plata. Facultad de Ingeniería; ArgentinaFil: Tuckart, Walter Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería; ArgentinaFil: Zabala, Nicolás Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería; ArgentinaFil: Prieto, Germán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería; ArgentinaFil: Egli, Walter Alfredo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaSpringer2015-06-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/45077Bengoa, Leandro Nicolás; Tuckart, Walter Roberto; Zabala, Nicolás Ariel; Prieto, Germán; Egli, Walter Alfredo; Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior; Springer; Journal of Materials Engineering and Performance; 24; 6; 9-6-2015; 2274-22811059-94951544-1024CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007%2Fs11665-015-1503-4info:eu-repo/semantics/altIdentifier/doi/10.1007/s11665-015-1503-4info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:54:07Zoai:ri.conicet.gov.ar:11336/45077instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:54:07.361CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior
title Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior
spellingShingle Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior
Bengoa, Leandro Nicolás
Tin
Phenol Sulfonic Acid
Methane Sulfonic Acid
Coatings
Tribology
Wear Resistance
title_short Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior
title_full Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior
title_fullStr Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior
title_full_unstemmed Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior
title_sort Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior
dc.creator.none.fl_str_mv Bengoa, Leandro Nicolás
Tuckart, Walter Roberto
Zabala, Nicolás Ariel
Prieto, Germán
Egli, Walter Alfredo
author Bengoa, Leandro Nicolás
author_facet Bengoa, Leandro Nicolás
Tuckart, Walter Roberto
Zabala, Nicolás Ariel
Prieto, Germán
Egli, Walter Alfredo
author_role author
author2 Tuckart, Walter Roberto
Zabala, Nicolás Ariel
Prieto, Germán
Egli, Walter Alfredo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Tin
Phenol Sulfonic Acid
Methane Sulfonic Acid
Coatings
Tribology
Wear Resistance
topic Tin
Phenol Sulfonic Acid
Methane Sulfonic Acid
Coatings
Tribology
Wear Resistance
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A high efficiency methane sulfonic acid electrolyte used for tin electrodeposition was studied, and the properties of the resulting deposits were compared to those of tin coatings obtained from an industrial phenol sulfonic acid electrolyte. Cyclic voltammetry was used to study the effect of organic additives on the reduction process to define the composition of the electrolytic bath. Thick tin electrodeposits were obtained on rotating cylinder steel electrodes and their surface morphology, preferred crystal orientation, surface roughness, micro hardness and tribological behaviour were measured. Smooth, adherent and bright tin coatings were obtained from the methane sulfonic acid electrolyte, which differed in morphology and texture from tin electrodeposited from the industrial bath. Influence of organic additives on preferred crystal orientation of the coatings was found to be stronger than changing the supporting sulfonic acid type. Tribological tests showed that the two types of deposits have a similar coefficient of friction. However, tin coatings obtained from methane sulfonic electrolytes presented a lower wear resistance and underwent galling at lower loads.
Fil: Bengoa, Leandro Nicolás. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina. Universidad Nacional de La Plata. Facultad de Ingeniería; Argentina
Fil: Tuckart, Walter Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería; Argentina
Fil: Zabala, Nicolás Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería; Argentina
Fil: Prieto, Germán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería; Argentina
Fil: Egli, Walter Alfredo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
description A high efficiency methane sulfonic acid electrolyte used for tin electrodeposition was studied, and the properties of the resulting deposits were compared to those of tin coatings obtained from an industrial phenol sulfonic acid electrolyte. Cyclic voltammetry was used to study the effect of organic additives on the reduction process to define the composition of the electrolytic bath. Thick tin electrodeposits were obtained on rotating cylinder steel electrodes and their surface morphology, preferred crystal orientation, surface roughness, micro hardness and tribological behaviour were measured. Smooth, adherent and bright tin coatings were obtained from the methane sulfonic acid electrolyte, which differed in morphology and texture from tin electrodeposited from the industrial bath. Influence of organic additives on preferred crystal orientation of the coatings was found to be stronger than changing the supporting sulfonic acid type. Tribological tests showed that the two types of deposits have a similar coefficient of friction. However, tin coatings obtained from methane sulfonic electrolytes presented a lower wear resistance and underwent galling at lower loads.
publishDate 2015
dc.date.none.fl_str_mv 2015-06-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/45077
Bengoa, Leandro Nicolás; Tuckart, Walter Roberto; Zabala, Nicolás Ariel; Prieto, Germán; Egli, Walter Alfredo; Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior; Springer; Journal of Materials Engineering and Performance; 24; 6; 9-6-2015; 2274-2281
1059-9495
1544-1024
CONICET Digital
CONICET
url http://hdl.handle.net/11336/45077
identifier_str_mv Bengoa, Leandro Nicolás; Tuckart, Walter Roberto; Zabala, Nicolás Ariel; Prieto, Germán; Egli, Walter Alfredo; Tin Coatings Electrodeposited from Sulfonic Acid-Based Electrolytes: Tribological Behavior; Springer; Journal of Materials Engineering and Performance; 24; 6; 9-6-2015; 2274-2281
1059-9495
1544-1024
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007%2Fs11665-015-1503-4
info:eu-repo/semantics/altIdentifier/doi/10.1007/s11665-015-1503-4
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083072938737664
score 13.22299

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