Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites

Autores
Bolletta, Juan Pablo; Cuello, Gabriel Julio; Nassif, Vivian; Suard, Emmanuelle; Kurbakov, Alexander I.; Maignan, Antoine; Martin, Christine; Carbonio, Raul Ernesto
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Rare-earth orthoferrites (RFeO3) provide a flexible playground for magnetic materials design, combining the magnetic properties arising from complex interactions between R3+ and Fe3+ cations within the robust framework of the perovskite structure. The most important magnetic property common to most orthoferrites is a spin reorientation transition in which the magnetic moments of Fe3+ cations rotate with respect to a crystallographic axis. SmFeO3 is unique among orthoferrites due to its high-temperature spin reorientation. It is possible to tune the spin reorientation transition to occur at room temperature by replacing Sm with Tm in the Sm0.70Tm0.30FeO3 perovskite. In this study, we show how small changes in composition in the Sm1-xTmxFeO3 (x=0.30-0.50) series provide a high degree of control over the magnetic properties. This work also offers a rather unusual look into the magnetic structure of a samarium-based perovskite by means of neutron powder diffraction, which was made possible by using Sm152. The combination of these results and magnetization measurements allowed the construction of the magnetic phase diagram of the series.
Fil: Bolletta, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Cuello, Gabriel Julio. Institut Laue Langevin; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Nassif, Vivian. Universite Grenoble Alpes; Francia
Fil: Suard, Emmanuelle. Institut Laue Langevin; Francia
Fil: Kurbakov, Alexander I.. No especifíca;
Fil: Maignan, Antoine. No especifíca;
Fil: Martin, Christine. No especifíca;
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
ORTHOFERRITE
PEROVSKITE
MAGNETIC
ANISOTROPY
NEUTRON
DIFFRACTION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/216016
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/216016
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferritesBolletta, Juan PabloCuello, Gabriel JulioNassif, VivianSuard, EmmanuelleKurbakov, Alexander I.Maignan, AntoineMartin, ChristineCarbonio, Raul ErnestoORTHOFERRITEPEROVSKITEMAGNETICANISOTROPYNEUTRONDIFFRACTIONhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Rare-earth orthoferrites (RFeO3) provide a flexible playground for magnetic materials design, combining the magnetic properties arising from complex interactions between R3+ and Fe3+ cations within the robust framework of the perovskite structure. The most important magnetic property common to most orthoferrites is a spin reorientation transition in which the magnetic moments of Fe3+ cations rotate with respect to a crystallographic axis. SmFeO3 is unique among orthoferrites due to its high-temperature spin reorientation. It is possible to tune the spin reorientation transition to occur at room temperature by replacing Sm with Tm in the Sm0.70Tm0.30FeO3 perovskite. In this study, we show how small changes in composition in the Sm1-xTmxFeO3 (x=0.30-0.50) series provide a high degree of control over the magnetic properties. This work also offers a rather unusual look into the magnetic structure of a samarium-based perovskite by means of neutron powder diffraction, which was made possible by using Sm152. The combination of these results and magnetization measurements allowed the construction of the magnetic phase diagram of the series.Fil: Bolletta, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Cuello, Gabriel Julio. Institut Laue Langevin; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Nassif, Vivian. Universite Grenoble Alpes; FranciaFil: Suard, Emmanuelle. Institut Laue Langevin; FranciaFil: Kurbakov, Alexander I.. No especifíca;Fil: Maignan, Antoine. No especifíca;Fil: Martin, Christine. No especifíca;Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaAmerican Physical Society2022-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/216016Bolletta, Juan Pablo; Cuello, Gabriel Julio; Nassif, Vivian; Suard, Emmanuelle; Kurbakov, Alexander I.; et al.; Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites; American Physical Society; Physical Review B; 105; 5; 2-2022; 54407-544242469-99502469-9969CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1103/PhysRevB.105.054407info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:45:47Zoai:ri.conicet.gov.ar:11336/216016instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:45:47.975CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites
title Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites
spellingShingle Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites
Bolletta, Juan Pablo
ORTHOFERRITE
PEROVSKITE
MAGNETIC
ANISOTROPY
NEUTRON
DIFFRACTION
title_short Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites
title_full Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites
title_fullStr Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites
title_full_unstemmed Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites
title_sort Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites
dc.creator.none.fl_str_mv Bolletta, Juan Pablo
Cuello, Gabriel Julio
Nassif, Vivian
Suard, Emmanuelle
Kurbakov, Alexander I.
Maignan, Antoine
Martin, Christine
Carbonio, Raul Ernesto
author Bolletta, Juan Pablo
author_facet Bolletta, Juan Pablo
Cuello, Gabriel Julio
Nassif, Vivian
Suard, Emmanuelle
Kurbakov, Alexander I.
Maignan, Antoine
Martin, Christine
Carbonio, Raul Ernesto
author_role author
author2 Cuello, Gabriel Julio
Nassif, Vivian
Suard, Emmanuelle
Kurbakov, Alexander I.
Maignan, Antoine
Martin, Christine
Carbonio, Raul Ernesto
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv ORTHOFERRITE
PEROVSKITE
MAGNETIC
ANISOTROPY
NEUTRON
DIFFRACTION
topic ORTHOFERRITE
PEROVSKITE
MAGNETIC
ANISOTROPY
NEUTRON
DIFFRACTION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Rare-earth orthoferrites (RFeO3) provide a flexible playground for magnetic materials design, combining the magnetic properties arising from complex interactions between R3+ and Fe3+ cations within the robust framework of the perovskite structure. The most important magnetic property common to most orthoferrites is a spin reorientation transition in which the magnetic moments of Fe3+ cations rotate with respect to a crystallographic axis. SmFeO3 is unique among orthoferrites due to its high-temperature spin reorientation. It is possible to tune the spin reorientation transition to occur at room temperature by replacing Sm with Tm in the Sm0.70Tm0.30FeO3 perovskite. In this study, we show how small changes in composition in the Sm1-xTmxFeO3 (x=0.30-0.50) series provide a high degree of control over the magnetic properties. This work also offers a rather unusual look into the magnetic structure of a samarium-based perovskite by means of neutron powder diffraction, which was made possible by using Sm152. The combination of these results and magnetization measurements allowed the construction of the magnetic phase diagram of the series.
Fil: Bolletta, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Cuello, Gabriel Julio. Institut Laue Langevin; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Nassif, Vivian. Universite Grenoble Alpes; Francia
Fil: Suard, Emmanuelle. Institut Laue Langevin; Francia
Fil: Kurbakov, Alexander I.. No especifíca;
Fil: Maignan, Antoine. No especifíca;
Fil: Martin, Christine. No especifíca;
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description Rare-earth orthoferrites (RFeO3) provide a flexible playground for magnetic materials design, combining the magnetic properties arising from complex interactions between R3+ and Fe3+ cations within the robust framework of the perovskite structure. The most important magnetic property common to most orthoferrites is a spin reorientation transition in which the magnetic moments of Fe3+ cations rotate with respect to a crystallographic axis. SmFeO3 is unique among orthoferrites due to its high-temperature spin reorientation. It is possible to tune the spin reorientation transition to occur at room temperature by replacing Sm with Tm in the Sm0.70Tm0.30FeO3 perovskite. In this study, we show how small changes in composition in the Sm1-xTmxFeO3 (x=0.30-0.50) series provide a high degree of control over the magnetic properties. This work also offers a rather unusual look into the magnetic structure of a samarium-based perovskite by means of neutron powder diffraction, which was made possible by using Sm152. The combination of these results and magnetization measurements allowed the construction of the magnetic phase diagram of the series.
publishDate 2022
dc.date.none.fl_str_mv 2022-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/216016
Bolletta, Juan Pablo; Cuello, Gabriel Julio; Nassif, Vivian; Suard, Emmanuelle; Kurbakov, Alexander I.; et al.; Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites; American Physical Society; Physical Review B; 105; 5; 2-2022; 54407-54424
2469-9950
2469-9969
CONICET Digital
CONICET
url http://hdl.handle.net/11336/216016
identifier_str_mv Bolletta, Juan Pablo; Cuello, Gabriel Julio; Nassif, Vivian; Suard, Emmanuelle; Kurbakov, Alexander I.; et al.; Room-temperature tuning of magnetic anisotropy in samarium-thulium orthoferrites; American Physical Society; Physical Review B; 105; 5; 2-2022; 54407-54424
2469-9950
2469-9969
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1103/PhysRevB.105.054407
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Physical Society
publisher.none.fl_str_mv American Physical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842268753755111424
score 13.13397

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