Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity

Autores
Segobia, Dario Jobino; Trasarti, Andres Fernando; Apesteguia, Carlos Rodolfo
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The liquid-phase hydrogenation of butyronitrile to butylamines was studied on Pt(0.27%)/SiO2, Pd(0.33%)/SiO2 and Ru(1.80%)/SiO2 using n-butanol, toluene and cyclohexane as solvents. In n-butanol, Pt and Pd catalysts formed preponderantly dibutylamine and minor amounts of tributylamine while Ru/SiO2 yielded mainly butylamine. Replacing n-butanol by toluene or cyclohexane caused significant changes in catalyst activity and selectivity. These changes were interpreted by relating the catalyst performance with the solvent-catalyst interaction strength that was investigated by temperature-programmed desorption of solvents and mass spectrometry. Pd/SiO2 strongly deactivated with the progress of the reaction in all the solvents.
Fil: Segobia, Dario Jobino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Trasarti, Andres Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Butyronitrile
Butylamine
Hydrogenation
Noble Metals
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31058
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivitySegobia, Dario JobinoTrasarti, Andres FernandoApesteguia, Carlos RodolfoButyronitrileButylamineHydrogenationNoble Metalshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The liquid-phase hydrogenation of butyronitrile to butylamines was studied on Pt(0.27%)/SiO2, Pd(0.33%)/SiO2 and Ru(1.80%)/SiO2 using n-butanol, toluene and cyclohexane as solvents. In n-butanol, Pt and Pd catalysts formed preponderantly dibutylamine and minor amounts of tributylamine while Ru/SiO2 yielded mainly butylamine. Replacing n-butanol by toluene or cyclohexane caused significant changes in catalyst activity and selectivity. These changes were interpreted by relating the catalyst performance with the solvent-catalyst interaction strength that was investigated by temperature-programmed desorption of solvents and mass spectrometry. Pd/SiO2 strongly deactivated with the progress of the reaction in all the solvents.Fil: Segobia, Dario Jobino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Trasarti, Andres Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaRoyal Society of Chemistry2014-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31058Segobia, Dario Jobino; Trasarti, Andres Fernando; Apesteguia, Carlos Rodolfo; Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity; Royal Society of Chemistry; Catalysis Science & Technology; 4; 11; 7-2014; 4075-40832044-4753CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2014/cy/c4cy00741g/unauth#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C4CY00741Ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:57:10Zoai:ri.conicet.gov.ar:11336/31058instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:57:10.7CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity
title Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity
spellingShingle Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity
Segobia, Dario Jobino
Butyronitrile
Butylamine
Hydrogenation
Noble Metals
title_short Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity
title_full Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity
title_fullStr Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity
title_full_unstemmed Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity
title_sort Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity
dc.creator.none.fl_str_mv Segobia, Dario Jobino
Trasarti, Andres Fernando
Apesteguia, Carlos Rodolfo
author Segobia, Dario Jobino
author_facet Segobia, Dario Jobino
Trasarti, Andres Fernando
Apesteguia, Carlos Rodolfo
author_role author
author2 Trasarti, Andres Fernando
Apesteguia, Carlos Rodolfo
author2_role author
author
dc.subject.none.fl_str_mv Butyronitrile
Butylamine
Hydrogenation
Noble Metals
topic Butyronitrile
Butylamine
Hydrogenation
Noble Metals
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The liquid-phase hydrogenation of butyronitrile to butylamines was studied on Pt(0.27%)/SiO2, Pd(0.33%)/SiO2 and Ru(1.80%)/SiO2 using n-butanol, toluene and cyclohexane as solvents. In n-butanol, Pt and Pd catalysts formed preponderantly dibutylamine and minor amounts of tributylamine while Ru/SiO2 yielded mainly butylamine. Replacing n-butanol by toluene or cyclohexane caused significant changes in catalyst activity and selectivity. These changes were interpreted by relating the catalyst performance with the solvent-catalyst interaction strength that was investigated by temperature-programmed desorption of solvents and mass spectrometry. Pd/SiO2 strongly deactivated with the progress of the reaction in all the solvents.
Fil: Segobia, Dario Jobino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Trasarti, Andres Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The liquid-phase hydrogenation of butyronitrile to butylamines was studied on Pt(0.27%)/SiO2, Pd(0.33%)/SiO2 and Ru(1.80%)/SiO2 using n-butanol, toluene and cyclohexane as solvents. In n-butanol, Pt and Pd catalysts formed preponderantly dibutylamine and minor amounts of tributylamine while Ru/SiO2 yielded mainly butylamine. Replacing n-butanol by toluene or cyclohexane caused significant changes in catalyst activity and selectivity. These changes were interpreted by relating the catalyst performance with the solvent-catalyst interaction strength that was investigated by temperature-programmed desorption of solvents and mass spectrometry. Pd/SiO2 strongly deactivated with the progress of the reaction in all the solvents.
publishDate 2014
dc.date.none.fl_str_mv 2014-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31058
Segobia, Dario Jobino; Trasarti, Andres Fernando; Apesteguia, Carlos Rodolfo; Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity; Royal Society of Chemistry; Catalysis Science & Technology; 4; 11; 7-2014; 4075-4083
2044-4753
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31058
identifier_str_mv Segobia, Dario Jobino; Trasarti, Andres Fernando; Apesteguia, Carlos Rodolfo; Conversion of butyronitrile to butylamines on noble metals: Effect of solvent on catalyst activity and selectivity; Royal Society of Chemistry; Catalysis Science & Technology; 4; 11; 7-2014; 4075-4083
2044-4753
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2014/cy/c4cy00741g/unauth#!divAbstract
info:eu-repo/semantics/altIdentifier/doi/10.1039/C4CY00741G
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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