A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction

Autores
Montero, María de Los Angeles; Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A simple and rigorous methodology to establish the relationship between the faradaic equilibrium polarization resistance of an electrocatalytic reaction with the elementary kinetic parameters involved in the reaction mechanism is proposed. It was derived through an alternative method, which avoided the differentiation of the corresponding current-overpotential dependence. This formalism includes the cases where both, reactants and products, exhibit diffusion contributions. It is demonstrated that the equilibrium polarization resistance is the sum of both, faradaic and diffusion, contributions. Each diffusion term has a linear variation with the inverse of the limiting diffusion current density of the species involved. This behavior was exemplified with two different experimental data sets for the hydrogen electrode reaction, obtained on a rotating disc and microelectrodes, respectively. [Figure not available: see fulltext.].
Fil: Montero, María de Los Angeles. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Marozzi, Carlos Alberto. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Materia
Equilibrium Polarization Resistance
Equilibrium Reaction Rate of Elementary Steps
Exchange Current Density
Faradaic And Diffusion Contributions
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/56085
Acceder
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network_name_str CONICET Digital (CONICET)
spelling A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed ReactionMontero, María de Los AngelesMarozzi, Carlos AlbertoGennero, Maria RosaChialvo, Abel CesarEquilibrium Polarization ResistanceEquilibrium Reaction Rate of Elementary StepsExchange Current DensityFaradaic And Diffusion Contributionshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A simple and rigorous methodology to establish the relationship between the faradaic equilibrium polarization resistance of an electrocatalytic reaction with the elementary kinetic parameters involved in the reaction mechanism is proposed. It was derived through an alternative method, which avoided the differentiation of the corresponding current-overpotential dependence. This formalism includes the cases where both, reactants and products, exhibit diffusion contributions. It is demonstrated that the equilibrium polarization resistance is the sum of both, faradaic and diffusion, contributions. Each diffusion term has a linear variation with the inverse of the limiting diffusion current density of the species involved. This behavior was exemplified with two different experimental data sets for the hydrogen electrode reaction, obtained on a rotating disc and microelectrodes, respectively. [Figure not available: see fulltext.].Fil: Montero, María de Los Angeles. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; ArgentinaFil: Marozzi, Carlos Alberto. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; ArgentinaFil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; ArgentinaFil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; ArgentinaSpringer New York LLC2018-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/56085Montero, María de Los Angeles; Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction; Springer New York LLC; Electrocatalysis; 9; 3; 5-2018; 409-4151868-5994CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s12678-017-0443-1info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs12678-017-0443-1info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:45:55Zoai:ri.conicet.gov.ar:11336/56085instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:45:55.655CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction
title A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction
spellingShingle A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction
Montero, María de Los Angeles
Equilibrium Polarization Resistance
Equilibrium Reaction Rate of Elementary Steps
Exchange Current Density
Faradaic And Diffusion Contributions
title_short A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction
title_full A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction
title_fullStr A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction
title_full_unstemmed A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction
title_sort A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction
dc.creator.none.fl_str_mv Montero, María de Los Angeles
Marozzi, Carlos Alberto
Gennero, Maria Rosa
Chialvo, Abel Cesar
author Montero, María de Los Angeles
author_facet Montero, María de Los Angeles
Marozzi, Carlos Alberto
Gennero, Maria Rosa
Chialvo, Abel Cesar
author_role author
author2 Marozzi, Carlos Alberto
Gennero, Maria Rosa
Chialvo, Abel Cesar
author2_role author
author
author
dc.subject.none.fl_str_mv Equilibrium Polarization Resistance
Equilibrium Reaction Rate of Elementary Steps
Exchange Current Density
Faradaic And Diffusion Contributions
topic Equilibrium Polarization Resistance
Equilibrium Reaction Rate of Elementary Steps
Exchange Current Density
Faradaic And Diffusion Contributions
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A simple and rigorous methodology to establish the relationship between the faradaic equilibrium polarization resistance of an electrocatalytic reaction with the elementary kinetic parameters involved in the reaction mechanism is proposed. It was derived through an alternative method, which avoided the differentiation of the corresponding current-overpotential dependence. This formalism includes the cases where both, reactants and products, exhibit diffusion contributions. It is demonstrated that the equilibrium polarization resistance is the sum of both, faradaic and diffusion, contributions. Each diffusion term has a linear variation with the inverse of the limiting diffusion current density of the species involved. This behavior was exemplified with two different experimental data sets for the hydrogen electrode reaction, obtained on a rotating disc and microelectrodes, respectively. [Figure not available: see fulltext.].
Fil: Montero, María de Los Angeles. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Marozzi, Carlos Alberto. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
description A simple and rigorous methodology to establish the relationship between the faradaic equilibrium polarization resistance of an electrocatalytic reaction with the elementary kinetic parameters involved in the reaction mechanism is proposed. It was derived through an alternative method, which avoided the differentiation of the corresponding current-overpotential dependence. This formalism includes the cases where both, reactants and products, exhibit diffusion contributions. It is demonstrated that the equilibrium polarization resistance is the sum of both, faradaic and diffusion, contributions. Each diffusion term has a linear variation with the inverse of the limiting diffusion current density of the species involved. This behavior was exemplified with two different experimental data sets for the hydrogen electrode reaction, obtained on a rotating disc and microelectrodes, respectively. [Figure not available: see fulltext.].
publishDate 2018
dc.date.none.fl_str_mv 2018-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/56085
Montero, María de Los Angeles; Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction; Springer New York LLC; Electrocatalysis; 9; 3; 5-2018; 409-415
1868-5994
CONICET Digital
CONICET
url http://hdl.handle.net/11336/56085
identifier_str_mv Montero, María de Los Angeles; Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; A Simple Method to Establish the Relationship Between the Equilibrium Polarization Resistance and the Elementary Kinetic Parameters of an Electrocatalysed Reaction; Springer New York LLC; Electrocatalysis; 9; 3; 5-2018; 409-415
1868-5994
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s12678-017-0443-1
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs12678-017-0443-1
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer New York LLC
publisher.none.fl_str_mv Springer New York LLC
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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