Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study
- Autores
- Silva, Alexander Martins; Rojas, Mariana Isabel
- Año de publicación
- 2016
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Graphite carbon nitride (g-C3N4) is a new class of N-doped material that exists in 2D and 3D structures. They are nanoporous materials with multiple technological applications. That is why we present here a complete Density Functional Theory study about the properties of (2D) sheets: triazine and tri-s-triazine and the (3D) crystals. The layers can be stacked in different forms on the crystals. Thus, we consider different stacking types and calculate the adhesion energy between the layers. We also simulate the X-ray diffraction pattern (XRD) and Transmission Electron Microscopy (TEM) pattern using the optimized geometries, because all these data are useful for experimentalists. As g-C3N4 is an organic semiconductor, we inform the electrical properties for sheets and crystals. We perform band diagrams using symmetry paths in the Brillouin zone (BZ) and Density of States (DOS) calculations. We compare graphene and graphite materials with 2D and 3D g-C3N4 structures, because they are a good reference as they are well known.
Fil: Silva, Alexander Martins. Instituto Nacional de Metrologia; Brasil
Fil: Rojas, Mariana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina - Materia
-
Density Functional Theory Calculation
Graphite Carbon Nitride
Properties - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/62138
Ver los metadatos del registro completo
id |
CONICETDig_3b6b0bc764c53e486b601e39d05fb3db |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/62138 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory studySilva, Alexander MartinsRojas, Mariana IsabelDensity Functional Theory CalculationGraphite Carbon NitridePropertieshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Graphite carbon nitride (g-C3N4) is a new class of N-doped material that exists in 2D and 3D structures. They are nanoporous materials with multiple technological applications. That is why we present here a complete Density Functional Theory study about the properties of (2D) sheets: triazine and tri-s-triazine and the (3D) crystals. The layers can be stacked in different forms on the crystals. Thus, we consider different stacking types and calculate the adhesion energy between the layers. We also simulate the X-ray diffraction pattern (XRD) and Transmission Electron Microscopy (TEM) pattern using the optimized geometries, because all these data are useful for experimentalists. As g-C3N4 is an organic semiconductor, we inform the electrical properties for sheets and crystals. We perform band diagrams using symmetry paths in the Brillouin zone (BZ) and Density of States (DOS) calculations. We compare graphene and graphite materials with 2D and 3D g-C3N4 structures, because they are a good reference as they are well known.Fil: Silva, Alexander Martins. Instituto Nacional de Metrologia; BrasilFil: Rojas, Mariana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaElsevier Science2016-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/62138Silva, Alexander Martins; Rojas, Mariana Isabel; Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study; Elsevier Science; Computational and Theoretical Chemistry; 1098; 12-2016; 41-492210-271XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2210271X16304431info:eu-repo/semantics/altIdentifier/doi/10.1016/j.comptc.2016.11.004info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:03Zoai:ri.conicet.gov.ar:11336/62138instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:03.766CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study |
title |
Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study |
spellingShingle |
Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study Silva, Alexander Martins Density Functional Theory Calculation Graphite Carbon Nitride Properties |
title_short |
Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study |
title_full |
Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study |
title_fullStr |
Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study |
title_full_unstemmed |
Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study |
title_sort |
Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study |
dc.creator.none.fl_str_mv |
Silva, Alexander Martins Rojas, Mariana Isabel |
author |
Silva, Alexander Martins |
author_facet |
Silva, Alexander Martins Rojas, Mariana Isabel |
author_role |
author |
author2 |
Rojas, Mariana Isabel |
author2_role |
author |
dc.subject.none.fl_str_mv |
Density Functional Theory Calculation Graphite Carbon Nitride Properties |
topic |
Density Functional Theory Calculation Graphite Carbon Nitride Properties |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Graphite carbon nitride (g-C3N4) is a new class of N-doped material that exists in 2D and 3D structures. They are nanoporous materials with multiple technological applications. That is why we present here a complete Density Functional Theory study about the properties of (2D) sheets: triazine and tri-s-triazine and the (3D) crystals. The layers can be stacked in different forms on the crystals. Thus, we consider different stacking types and calculate the adhesion energy between the layers. We also simulate the X-ray diffraction pattern (XRD) and Transmission Electron Microscopy (TEM) pattern using the optimized geometries, because all these data are useful for experimentalists. As g-C3N4 is an organic semiconductor, we inform the electrical properties for sheets and crystals. We perform band diagrams using symmetry paths in the Brillouin zone (BZ) and Density of States (DOS) calculations. We compare graphene and graphite materials with 2D and 3D g-C3N4 structures, because they are a good reference as they are well known. Fil: Silva, Alexander Martins. Instituto Nacional de Metrologia; Brasil Fil: Rojas, Mariana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina |
description |
Graphite carbon nitride (g-C3N4) is a new class of N-doped material that exists in 2D and 3D structures. They are nanoporous materials with multiple technological applications. That is why we present here a complete Density Functional Theory study about the properties of (2D) sheets: triazine and tri-s-triazine and the (3D) crystals. The layers can be stacked in different forms on the crystals. Thus, we consider different stacking types and calculate the adhesion energy between the layers. We also simulate the X-ray diffraction pattern (XRD) and Transmission Electron Microscopy (TEM) pattern using the optimized geometries, because all these data are useful for experimentalists. As g-C3N4 is an organic semiconductor, we inform the electrical properties for sheets and crystals. We perform band diagrams using symmetry paths in the Brillouin zone (BZ) and Density of States (DOS) calculations. We compare graphene and graphite materials with 2D and 3D g-C3N4 structures, because they are a good reference as they are well known. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/62138 Silva, Alexander Martins; Rojas, Mariana Isabel; Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study; Elsevier Science; Computational and Theoretical Chemistry; 1098; 12-2016; 41-49 2210-271X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/62138 |
identifier_str_mv |
Silva, Alexander Martins; Rojas, Mariana Isabel; Electric and structural properties of polymeric graphite carbon nitride (g-C3N4): A Density Functional Theory study; Elsevier Science; Computational and Theoretical Chemistry; 1098; 12-2016; 41-49 2210-271X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2210271X16304431 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.comptc.2016.11.004 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613235432488960 |
score |
13.070432 |