Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum

Autores
Quaino, Paola Monica; Gennero, Maria Rosa; Chialvo, Abel Cesar
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The present work deals with a kinetic study of the hydrogen electrode reaction (HER) on a platinum electrode modified by bismuth adatoms in both cathodic and anodic range of overpotentials. Kinetic expressions previously derived for the Volmer-Heyrovsky-Tafel mechanism were modified in order to take into account the influence of bismuth. Thus, a modification of the adsorption energy of the reaction intermediate, described through the variation of the Frumkin interaction parameter, and a possible effect of inhibition on the active sites were included in the kinetic expressions. On this basis, the experimental results obtained in the overpotentials range -0.20 < h / V < 0.40 were successfully correlated through the variation of only four adjustable parameters, which dependence on the bismuth surface coverage were evaluated and discussed.
Fil: Quaino, Paola Monica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Materia
HYDROGEN ELECTRODE REACTION
UNDERPOTENTIAL DEPOSITION
BI-MODIFIED PLATINUM ELECTRODE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/101895
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/101895
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Kinetic Study of the hydrogen electrode reaction on Bi-modified PlatinumQuaino, Paola MonicaGennero, Maria RosaChialvo, Abel CesarHYDROGEN ELECTRODE REACTIONUNDERPOTENTIAL DEPOSITIONBI-MODIFIED PLATINUM ELECTRODEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The present work deals with a kinetic study of the hydrogen electrode reaction (HER) on a platinum electrode modified by bismuth adatoms in both cathodic and anodic range of overpotentials. Kinetic expressions previously derived for the Volmer-Heyrovsky-Tafel mechanism were modified in order to take into account the influence of bismuth. Thus, a modification of the adsorption energy of the reaction intermediate, described through the variation of the Frumkin interaction parameter, and a possible effect of inhibition on the active sites were included in the kinetic expressions. On this basis, the experimental results obtained in the overpotentials range -0.20 < h / V < 0.40 were successfully correlated through the variation of only four adjustable parameters, which dependence on the bismuth surface coverage were evaluated and discussed.Fil: Quaino, Paola Monica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; ArgentinaFil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; ArgentinaFil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; ArgentinaElectrochemical Society2009-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/101895Quaino, Paola Monica; Gennero, Maria Rosa; Chialvo, Abel Cesar; Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum; Electrochemical Society; Journal of the Electrochemical Society; 156; 1-2009; 167-1730013-4651CONICET DigitalCONICETenginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T10:40:01Zoai:ri.conicet.gov.ar:11336/101895instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 10:40:02.238CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum
title Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum
spellingShingle Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum
Quaino, Paola Monica
HYDROGEN ELECTRODE REACTION
UNDERPOTENTIAL DEPOSITION
BI-MODIFIED PLATINUM ELECTRODE
title_short Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum
title_full Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum
title_fullStr Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum
title_full_unstemmed Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum
title_sort Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum
dc.creator.none.fl_str_mv Quaino, Paola Monica
Gennero, Maria Rosa
Chialvo, Abel Cesar
author Quaino, Paola Monica
author_facet Quaino, Paola Monica
Gennero, Maria Rosa
Chialvo, Abel Cesar
author_role author
author2 Gennero, Maria Rosa
Chialvo, Abel Cesar
author2_role author
author
dc.subject.none.fl_str_mv HYDROGEN ELECTRODE REACTION
UNDERPOTENTIAL DEPOSITION
BI-MODIFIED PLATINUM ELECTRODE
topic HYDROGEN ELECTRODE REACTION
UNDERPOTENTIAL DEPOSITION
BI-MODIFIED PLATINUM ELECTRODE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The present work deals with a kinetic study of the hydrogen electrode reaction (HER) on a platinum electrode modified by bismuth adatoms in both cathodic and anodic range of overpotentials. Kinetic expressions previously derived for the Volmer-Heyrovsky-Tafel mechanism were modified in order to take into account the influence of bismuth. Thus, a modification of the adsorption energy of the reaction intermediate, described through the variation of the Frumkin interaction parameter, and a possible effect of inhibition on the active sites were included in the kinetic expressions. On this basis, the experimental results obtained in the overpotentials range -0.20 < h / V < 0.40 were successfully correlated through the variation of only four adjustable parameters, which dependence on the bismuth surface coverage were evaluated and discussed.
Fil: Quaino, Paola Monica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
description The present work deals with a kinetic study of the hydrogen electrode reaction (HER) on a platinum electrode modified by bismuth adatoms in both cathodic and anodic range of overpotentials. Kinetic expressions previously derived for the Volmer-Heyrovsky-Tafel mechanism were modified in order to take into account the influence of bismuth. Thus, a modification of the adsorption energy of the reaction intermediate, described through the variation of the Frumkin interaction parameter, and a possible effect of inhibition on the active sites were included in the kinetic expressions. On this basis, the experimental results obtained in the overpotentials range -0.20 < h / V < 0.40 were successfully correlated through the variation of only four adjustable parameters, which dependence on the bismuth surface coverage were evaluated and discussed.
publishDate 2009
dc.date.none.fl_str_mv 2009-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/101895
Quaino, Paola Monica; Gennero, Maria Rosa; Chialvo, Abel Cesar; Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum; Electrochemical Society; Journal of the Electrochemical Society; 156; 1-2009; 167-173
0013-4651
CONICET Digital
CONICET
url http://hdl.handle.net/11336/101895
identifier_str_mv Quaino, Paola Monica; Gennero, Maria Rosa; Chialvo, Abel Cesar; Kinetic Study of the hydrogen electrode reaction on Bi-modified Platinum; Electrochemical Society; Journal of the Electrochemical Society; 156; 1-2009; 167-173
0013-4651
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Electrochemical Society
publisher.none.fl_str_mv Electrochemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.087074

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