Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy

Autores
Torres, Alberto Sabier; Martinez, Luis Dante; Pacheco, Pablo Hugo
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Arsenic species were determined in extra virgin olive oils (EVOOs) by two dimension chromatography and atomic spectroscopy: inductively coupled plasma mass spectrometry (ICP MS) and electrothermal atomic absorption spectrometry (ETAAS). A first approach determined total As concentration in EVOOs samples by microwave assisted digestion and ICP MS from 2.01 to 152 μg kg−1. EVOOs with elevated As concentration were selected for protein extraction. In a first dimension, by size exclusion chromatography (SEC) coupled to ICP MS, a fraction of 66 kDa was identified and collected for analysis. Free and proteic As were separated by molecular weight cut off filters. Proteic and free arsenic concentrations determined by ETAAS range from 0.56–4.44 and 0.67-3.89 μg kg−1 of As respectively. Finally in a second dimension, by anion exchange chromatography (AEC) coupled to ICP MS, dimethylarsenate and arsenite were determined in proteic fraction of EVOOs in concentrations of 1.68–2.86 and 0.53–0.55 μg kg−1 respectively.
Fil: Torres, Sabier. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química de San Luis; Argentina
Fil: Martínez, Luis D.. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química de San Luis; Argentina
Fil: Pacheco, Pablo Hugo. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química de San Luis; Argentina
Materia
ARSENIC SPECIES
ATOMIC SPECTROSCOPY
FOOD ANALYSIS
FOOD COMPOSITION
LIQUID CHROMATOGRAPHY
OLIVE OIL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/92862
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/92862
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopyTorres, Alberto SabierMartinez, Luis DantePacheco, Pablo HugoARSENIC SPECIESATOMIC SPECTROSCOPYFOOD ANALYSISFOOD COMPOSITIONLIQUID CHROMATOGRAPHYOLIVE OILhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Arsenic species were determined in extra virgin olive oils (EVOOs) by two dimension chromatography and atomic spectroscopy: inductively coupled plasma mass spectrometry (ICP MS) and electrothermal atomic absorption spectrometry (ETAAS). A first approach determined total As concentration in EVOOs samples by microwave assisted digestion and ICP MS from 2.01 to 152 μg kg−1. EVOOs with elevated As concentration were selected for protein extraction. In a first dimension, by size exclusion chromatography (SEC) coupled to ICP MS, a fraction of 66 kDa was identified and collected for analysis. Free and proteic As were separated by molecular weight cut off filters. Proteic and free arsenic concentrations determined by ETAAS range from 0.56–4.44 and 0.67-3.89 μg kg−1 of As respectively. Finally in a second dimension, by anion exchange chromatography (AEC) coupled to ICP MS, dimethylarsenate and arsenite were determined in proteic fraction of EVOOs in concentrations of 1.68–2.86 and 0.53–0.55 μg kg−1 respectively.Fil: Torres, Sabier. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química de San Luis; ArgentinaFil: Martínez, Luis D.. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química de San Luis; ArgentinaFil: Pacheco, Pablo Hugo. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química de San Luis; ArgentinaAcademic Press Inc Elsevier Science2018-03-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/92862Torres, Alberto Sabier; Martinez, Luis Dante; Pacheco, Pablo Hugo; Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy; Academic Press Inc Elsevier Science; Journal of Food Composition and Analysis; 66; 9-3-2018; 121-1260889-15750889-1575CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jfca.2017.12.011info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0889157517302892info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:21Zoai:ri.conicet.gov.ar:11336/92862instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:21.309CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy
title Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy
spellingShingle Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy
Torres, Alberto Sabier
ARSENIC SPECIES
ATOMIC SPECTROSCOPY
FOOD ANALYSIS
FOOD COMPOSITION
LIQUID CHROMATOGRAPHY
OLIVE OIL
title_short Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy
title_full Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy
title_fullStr Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy
title_full_unstemmed Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy
title_sort Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy
dc.creator.none.fl_str_mv Torres, Alberto Sabier
Martinez, Luis Dante
Pacheco, Pablo Hugo
author Torres, Alberto Sabier
author_facet Torres, Alberto Sabier
Martinez, Luis Dante
Pacheco, Pablo Hugo
author_role author
author2 Martinez, Luis Dante
Pacheco, Pablo Hugo
author2_role author
author
dc.subject.none.fl_str_mv ARSENIC SPECIES
ATOMIC SPECTROSCOPY
FOOD ANALYSIS
FOOD COMPOSITION
LIQUID CHROMATOGRAPHY
OLIVE OIL
topic ARSENIC SPECIES
ATOMIC SPECTROSCOPY
FOOD ANALYSIS
FOOD COMPOSITION
LIQUID CHROMATOGRAPHY
OLIVE OIL
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Arsenic species were determined in extra virgin olive oils (EVOOs) by two dimension chromatography and atomic spectroscopy: inductively coupled plasma mass spectrometry (ICP MS) and electrothermal atomic absorption spectrometry (ETAAS). A first approach determined total As concentration in EVOOs samples by microwave assisted digestion and ICP MS from 2.01 to 152 μg kg−1. EVOOs with elevated As concentration were selected for protein extraction. In a first dimension, by size exclusion chromatography (SEC) coupled to ICP MS, a fraction of 66 kDa was identified and collected for analysis. Free and proteic As were separated by molecular weight cut off filters. Proteic and free arsenic concentrations determined by ETAAS range from 0.56–4.44 and 0.67-3.89 μg kg−1 of As respectively. Finally in a second dimension, by anion exchange chromatography (AEC) coupled to ICP MS, dimethylarsenate and arsenite were determined in proteic fraction of EVOOs in concentrations of 1.68–2.86 and 0.53–0.55 μg kg−1 respectively.
Fil: Torres, Sabier. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química de San Luis; Argentina
Fil: Martínez, Luis D.. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química de San Luis; Argentina
Fil: Pacheco, Pablo Hugo. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Química de San Luis; Argentina
description Arsenic species were determined in extra virgin olive oils (EVOOs) by two dimension chromatography and atomic spectroscopy: inductively coupled plasma mass spectrometry (ICP MS) and electrothermal atomic absorption spectrometry (ETAAS). A first approach determined total As concentration in EVOOs samples by microwave assisted digestion and ICP MS from 2.01 to 152 μg kg−1. EVOOs with elevated As concentration were selected for protein extraction. In a first dimension, by size exclusion chromatography (SEC) coupled to ICP MS, a fraction of 66 kDa was identified and collected for analysis. Free and proteic As were separated by molecular weight cut off filters. Proteic and free arsenic concentrations determined by ETAAS range from 0.56–4.44 and 0.67-3.89 μg kg−1 of As respectively. Finally in a second dimension, by anion exchange chromatography (AEC) coupled to ICP MS, dimethylarsenate and arsenite were determined in proteic fraction of EVOOs in concentrations of 1.68–2.86 and 0.53–0.55 μg kg−1 respectively.
publishDate 2018
dc.date.none.fl_str_mv 2018-03-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/92862
Torres, Alberto Sabier; Martinez, Luis Dante; Pacheco, Pablo Hugo; Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy; Academic Press Inc Elsevier Science; Journal of Food Composition and Analysis; 66; 9-3-2018; 121-126
0889-1575
0889-1575
CONICET Digital
CONICET
url http://hdl.handle.net/11336/92862
identifier_str_mv Torres, Alberto Sabier; Martinez, Luis Dante; Pacheco, Pablo Hugo; Determination of arsenic species distribution in extra virgin olive oils from arsenic-endemic areas by dimensional chromatography and atomic spectroscopy; Academic Press Inc Elsevier Science; Journal of Food Composition and Analysis; 66; 9-3-2018; 121-126
0889-1575
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jfca.2017.12.011
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0889157517302892
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Academic Press Inc Elsevier Science
publisher.none.fl_str_mv Academic Press Inc Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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