Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions

Autores
Yohai del Cerro, Lucía; Schreiner, W. H.; Vazquez, Marcela Vivian; Valcarce, María Beatriz
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The composition of the surface layers has been investigated on copper, zinc and brass in contact with moderately hard, highly carbonated and chloride rich artificial tap water (ATW). Cyclic voltammetry, reflectance spectroscopy, X-ray diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy have been used to identify the changes in composition that result from the incorporation of sodium orthophosphate to ATW. The results showed that when PO43− is added, the film changes its composition and it also becomes thinner, denser and more compact. On copper, the presence of CuO in the passive film can be correlated to the improvement in the corrosion behavior in the presence of phosphate ions. In the case of brass, the development of a thinner, compact and less porous Zn3(PO4)2 layer hinders Cu(I) dissolution. A mechanism explaining the effect of this inhibitor is proposed, which accounts for the experimental results.
Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina
Fil: Schreiner, W. H.. Universidade Federal Do Parana; Brasil
Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina
Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina
Materia
Passive Film
Copper
Zinc
Brass
Tap Water
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/16015
Acceder
id CONICETDig_37d2864be657c539e4083146ee58bef6
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ionsYohai del Cerro, LucíaSchreiner, W. H.Vazquez, Marcela VivianValcarce, María BeatrizPassive FilmCopperZincBrassTap Waterhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The composition of the surface layers has been investigated on copper, zinc and brass in contact with moderately hard, highly carbonated and chloride rich artificial tap water (ATW). Cyclic voltammetry, reflectance spectroscopy, X-ray diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy have been used to identify the changes in composition that result from the incorporation of sodium orthophosphate to ATW. The results showed that when PO43− is added, the film changes its composition and it also becomes thinner, denser and more compact. On copper, the presence of CuO in the passive film can be correlated to the improvement in the corrosion behavior in the presence of phosphate ions. In the case of brass, the development of a thinner, compact and less porous Zn3(PO4)2 layer hinders Cu(I) dissolution. A mechanism explaining the effect of this inhibitor is proposed, which accounts for the experimental results.Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; ArgentinaFil: Schreiner, W. H.. Universidade Federal Do Parana; BrasilFil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; ArgentinaFil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; ArgentinaElsevier Science2011-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/16015Yohai del Cerro, Lucía; Schreiner, W. H.; Vazquez, Marcela Vivian; Valcarce, María Beatriz; Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions; Elsevier Science; Applied Surface Science; 257; 23; 9-2011; 10089-100950169-4332enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2011.07.002info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S016943321101035Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:23Zoai:ri.conicet.gov.ar:11336/16015instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:23.37CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions
title Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions
spellingShingle Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions
Yohai del Cerro, Lucía
Passive Film
Copper
Zinc
Brass
Tap Water
title_short Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions
title_full Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions
title_fullStr Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions
title_full_unstemmed Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions
title_sort Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions
dc.creator.none.fl_str_mv Yohai del Cerro, Lucía
Schreiner, W. H.
Vazquez, Marcela Vivian
Valcarce, María Beatriz
author Yohai del Cerro, Lucía
author_facet Yohai del Cerro, Lucía
Schreiner, W. H.
Vazquez, Marcela Vivian
Valcarce, María Beatriz
author_role author
author2 Schreiner, W. H.
Vazquez, Marcela Vivian
Valcarce, María Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv Passive Film
Copper
Zinc
Brass
Tap Water
topic Passive Film
Copper
Zinc
Brass
Tap Water
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The composition of the surface layers has been investigated on copper, zinc and brass in contact with moderately hard, highly carbonated and chloride rich artificial tap water (ATW). Cyclic voltammetry, reflectance spectroscopy, X-ray diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy have been used to identify the changes in composition that result from the incorporation of sodium orthophosphate to ATW. The results showed that when PO43− is added, the film changes its composition and it also becomes thinner, denser and more compact. On copper, the presence of CuO in the passive film can be correlated to the improvement in the corrosion behavior in the presence of phosphate ions. In the case of brass, the development of a thinner, compact and less porous Zn3(PO4)2 layer hinders Cu(I) dissolution. A mechanism explaining the effect of this inhibitor is proposed, which accounts for the experimental results.
Fil: Yohai del Cerro, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina
Fil: Schreiner, W. H.. Universidade Federal Do Parana; Brasil
Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina
Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina
description The composition of the surface layers has been investigated on copper, zinc and brass in contact with moderately hard, highly carbonated and chloride rich artificial tap water (ATW). Cyclic voltammetry, reflectance spectroscopy, X-ray diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy have been used to identify the changes in composition that result from the incorporation of sodium orthophosphate to ATW. The results showed that when PO43− is added, the film changes its composition and it also becomes thinner, denser and more compact. On copper, the presence of CuO in the passive film can be correlated to the improvement in the corrosion behavior in the presence of phosphate ions. In the case of brass, the development of a thinner, compact and less porous Zn3(PO4)2 layer hinders Cu(I) dissolution. A mechanism explaining the effect of this inhibitor is proposed, which accounts for the experimental results.
publishDate 2011
dc.date.none.fl_str_mv 2011-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/16015
Yohai del Cerro, Lucía; Schreiner, W. H.; Vazquez, Marcela Vivian; Valcarce, María Beatriz; Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions; Elsevier Science; Applied Surface Science; 257; 23; 9-2011; 10089-10095
0169-4332
url http://hdl.handle.net/11336/16015
identifier_str_mv Yohai del Cerro, Lucía; Schreiner, W. H.; Vazquez, Marcela Vivian; Valcarce, María Beatriz; Surface characterization of copper, zinc and brass in contact with tap water inhibited with phosphate ions; Elsevier Science; Applied Surface Science; 257; 23; 9-2011; 10089-10095
0169-4332
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2011.07.002
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S016943321101035X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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