Temperature-Dependent Reactions of Phthalic Acid on Ag(100)

Autores
Franke, Matthias; Marchini, Florencia; Zhang, Liang; Tariq, Quratulain; Tsud, Nataliya; Vorokhta, Mykhailo; Vondraćek, Martin; Prince, Kevin; Röckert, Michael; Williams, Federico José; Steinrück, Hans-Peter; Lytken, Ole
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We have investigated the adsorption and temperature-dependent reactions of phthalic acid on Ag(100), in the temperature range 110-700 K, by synchrotron radiation X-ray photoelectron spectrocopy (SR-XPS), temperature-programmed desorption (TPD) and near-edge X-ray absorption fine structure (NEXAFS). Phthalic acid adsorbs intact at 110 K, but decomposes to phthalic anhydride and polyanhdride at 150 K. When heated further, phthalic anhydride desorbs at 250 K, leaving only polyanhydride on the surface, which at 350 K decomposes into a carboxylate, through desorption of phthalic anhydride and water. The carboxylate is stable until 500 K, after which it decomposes, through desorption of CO2 and benzene, into carbon; the latter diffuses into the bulk, leaving only a little carbon on the Ag(100) surface at 600 K.
Fil: Franke, Matthias. Universitat Erlangen-Nuremberg; Alemania
Fil: Marchini, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Zhang, Liang. Universitat Erlangen-Nuremberg; Alemania
Fil: Tariq, Quratulain. Universitat Erlangen-Nuremberg; Alemania
Fil: Tsud, Nataliya. Charles University; República Checa
Fil: Vorokhta, Mykhailo. Charles University; República Checa
Fil: Vondraćek, Martin. Academy of Sciences of the Czech Republic; República Checa
Fil: Prince, Kevin. Elettra - Synchrotron Ligght Laboratory; Italia
Fil: Röckert, Michael. Universitat Erlangen-Nuremberg; Alemania
Fil: Williams, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Steinrück, Hans-Peter. Universitat Erlangen-Nuremberg; Alemania
Fil: Lytken, Ole. Universitat Erlangen-Nuremberg; Alemania
Materia
Phtalic Acid
Surface Reactions
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/38544
Acceder
id CONICETDig_3609de3066eb7ba453557c191d747055
oai_identifier_str oai:ri.conicet.gov.ar:11336/38544
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Temperature-Dependent Reactions of Phthalic Acid on Ag(100)Franke, MatthiasMarchini, FlorenciaZhang, LiangTariq, QuratulainTsud, NataliyaVorokhta, MykhailoVondraćek, MartinPrince, KevinRöckert, MichaelWilliams, Federico JoséSteinrück, Hans-PeterLytken, OlePhtalic AcidSurface Reactionshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We have investigated the adsorption and temperature-dependent reactions of phthalic acid on Ag(100), in the temperature range 110-700 K, by synchrotron radiation X-ray photoelectron spectrocopy (SR-XPS), temperature-programmed desorption (TPD) and near-edge X-ray absorption fine structure (NEXAFS). Phthalic acid adsorbs intact at 110 K, but decomposes to phthalic anhydride and polyanhdride at 150 K. When heated further, phthalic anhydride desorbs at 250 K, leaving only polyanhydride on the surface, which at 350 K decomposes into a carboxylate, through desorption of phthalic anhydride and water. The carboxylate is stable until 500 K, after which it decomposes, through desorption of CO2 and benzene, into carbon; the latter diffuses into the bulk, leaving only a little carbon on the Ag(100) surface at 600 K.Fil: Franke, Matthias. Universitat Erlangen-Nuremberg; AlemaniaFil: Marchini, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Zhang, Liang. Universitat Erlangen-Nuremberg; AlemaniaFil: Tariq, Quratulain. Universitat Erlangen-Nuremberg; AlemaniaFil: Tsud, Nataliya. Charles University; República ChecaFil: Vorokhta, Mykhailo. Charles University; República ChecaFil: Vondraćek, Martin. Academy of Sciences of the Czech Republic; República ChecaFil: Prince, Kevin. Elettra - Synchrotron Ligght Laboratory; ItaliaFil: Röckert, Michael. Universitat Erlangen-Nuremberg; AlemaniaFil: Williams, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Steinrück, Hans-Peter. Universitat Erlangen-Nuremberg; AlemaniaFil: Lytken, Ole. Universitat Erlangen-Nuremberg; AlemaniaAmerican Chemical Society2015-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/38544Franke, Matthias; Marchini, Florencia; Zhang, Liang; Tariq, Quratulain; Tsud, Nataliya; et al.; Temperature-Dependent Reactions of Phthalic Acid on Ag(100); American Chemical Society; Journal of Physical Chemistry C; 119; 41; 10-2015; 23580-235851932-7447CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.5b07858info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.jpcc.5b07858info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-02-26T10:05:14Zoai:ri.conicet.gov.ar:11336/38544instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-02-26 10:05:15.288CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Temperature-Dependent Reactions of Phthalic Acid on Ag(100)
title Temperature-Dependent Reactions of Phthalic Acid on Ag(100)
spellingShingle Temperature-Dependent Reactions of Phthalic Acid on Ag(100)
Franke, Matthias
Phtalic Acid
Surface Reactions
title_short Temperature-Dependent Reactions of Phthalic Acid on Ag(100)
title_full Temperature-Dependent Reactions of Phthalic Acid on Ag(100)
title_fullStr Temperature-Dependent Reactions of Phthalic Acid on Ag(100)
title_full_unstemmed Temperature-Dependent Reactions of Phthalic Acid on Ag(100)
title_sort Temperature-Dependent Reactions of Phthalic Acid on Ag(100)
dc.creator.none.fl_str_mv Franke, Matthias
Marchini, Florencia
Zhang, Liang
Tariq, Quratulain
Tsud, Nataliya
Vorokhta, Mykhailo
Vondraćek, Martin
Prince, Kevin
Röckert, Michael
Williams, Federico José
Steinrück, Hans-Peter
Lytken, Ole
author Franke, Matthias
author_facet Franke, Matthias
Marchini, Florencia
Zhang, Liang
Tariq, Quratulain
Tsud, Nataliya
Vorokhta, Mykhailo
Vondraćek, Martin
Prince, Kevin
Röckert, Michael
Williams, Federico José
Steinrück, Hans-Peter
Lytken, Ole
author_role author
author2 Marchini, Florencia
Zhang, Liang
Tariq, Quratulain
Tsud, Nataliya
Vorokhta, Mykhailo
Vondraćek, Martin
Prince, Kevin
Röckert, Michael
Williams, Federico José
Steinrück, Hans-Peter
Lytken, Ole
author2_role author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Phtalic Acid
Surface Reactions
topic Phtalic Acid
Surface Reactions
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We have investigated the adsorption and temperature-dependent reactions of phthalic acid on Ag(100), in the temperature range 110-700 K, by synchrotron radiation X-ray photoelectron spectrocopy (SR-XPS), temperature-programmed desorption (TPD) and near-edge X-ray absorption fine structure (NEXAFS). Phthalic acid adsorbs intact at 110 K, but decomposes to phthalic anhydride and polyanhdride at 150 K. When heated further, phthalic anhydride desorbs at 250 K, leaving only polyanhydride on the surface, which at 350 K decomposes into a carboxylate, through desorption of phthalic anhydride and water. The carboxylate is stable until 500 K, after which it decomposes, through desorption of CO2 and benzene, into carbon; the latter diffuses into the bulk, leaving only a little carbon on the Ag(100) surface at 600 K.
Fil: Franke, Matthias. Universitat Erlangen-Nuremberg; Alemania
Fil: Marchini, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Zhang, Liang. Universitat Erlangen-Nuremberg; Alemania
Fil: Tariq, Quratulain. Universitat Erlangen-Nuremberg; Alemania
Fil: Tsud, Nataliya. Charles University; República Checa
Fil: Vorokhta, Mykhailo. Charles University; República Checa
Fil: Vondraćek, Martin. Academy of Sciences of the Czech Republic; República Checa
Fil: Prince, Kevin. Elettra - Synchrotron Ligght Laboratory; Italia
Fil: Röckert, Michael. Universitat Erlangen-Nuremberg; Alemania
Fil: Williams, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Steinrück, Hans-Peter. Universitat Erlangen-Nuremberg; Alemania
Fil: Lytken, Ole. Universitat Erlangen-Nuremberg; Alemania
description We have investigated the adsorption and temperature-dependent reactions of phthalic acid on Ag(100), in the temperature range 110-700 K, by synchrotron radiation X-ray photoelectron spectrocopy (SR-XPS), temperature-programmed desorption (TPD) and near-edge X-ray absorption fine structure (NEXAFS). Phthalic acid adsorbs intact at 110 K, but decomposes to phthalic anhydride and polyanhdride at 150 K. When heated further, phthalic anhydride desorbs at 250 K, leaving only polyanhydride on the surface, which at 350 K decomposes into a carboxylate, through desorption of phthalic anhydride and water. The carboxylate is stable until 500 K, after which it decomposes, through desorption of CO2 and benzene, into carbon; the latter diffuses into the bulk, leaving only a little carbon on the Ag(100) surface at 600 K.
publishDate 2015
dc.date.none.fl_str_mv 2015-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/38544
Franke, Matthias; Marchini, Florencia; Zhang, Liang; Tariq, Quratulain; Tsud, Nataliya; et al.; Temperature-Dependent Reactions of Phthalic Acid on Ag(100); American Chemical Society; Journal of Physical Chemistry C; 119; 41; 10-2015; 23580-23585
1932-7447
CONICET Digital
CONICET
url http://hdl.handle.net/11336/38544
identifier_str_mv Franke, Matthias; Marchini, Florencia; Zhang, Liang; Tariq, Quratulain; Tsud, Nataliya; et al.; Temperature-Dependent Reactions of Phthalic Acid on Ag(100); American Chemical Society; Journal of Physical Chemistry C; 119; 41; 10-2015; 23580-23585
1932-7447
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.5b07858
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.jpcc.5b07858
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1858305156649582592
score 13.176822

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