Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions

Autores
Ciolino, Andrés Eduardo; Pieroni, Olga Inés; Vuano, Bruno Mario; Villar, Marcelo Armando; Valles, Enrique Marcelo
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report preliminary results for the synthesis of poly(ethylene)-graft-poly(dimethylsiloxane) copolymers (PE-g-PDMS) obtained by catalytic hydrogenation of poly(butadiene)-graft-poly(dimethylsiloxane) copolymers (PB-g-PDMS). These last copolymers were synthesized by hydrosilylation reactions between commercial poly(butadiene) (PB) and w-silane poly(dimethylsiloxane). The reaction was carried in solution catalyzed by cis-dichloro bis(diethylsufide) platinum (II) salt (Cl2[S(CH2CH3)2]Pt). The PB-g-PDMS copolymers were analyzed by 1H- and 13C-NMR spectroscopy and the relative weight percentages (wt%) of the grafted poly(dimethylsiloxane) macromonomer were determined from the integrated peak areas of the spectra.
Fil: Ciolino, Andrés Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pieroni, Olga Inés. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Vuano, Bruno Mario. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
poly(ethylene)-graft-poly(dimethylsiloxane)
hydrogenation
hydrosilylation reactions
1H- and 13C-NMR
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/99619
Acceder
id CONICETDig_35924774fa531975f3390ccadb44f722
oai_identifier_str oai:ri.conicet.gov.ar:11336/99619
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactionsCiolino, Andrés EduardoPieroni, Olga InésVuano, Bruno MarioVillar, Marcelo ArmandoValles, Enrique Marcelopoly(ethylene)-graft-poly(dimethylsiloxane)hydrogenationhydrosilylation reactions1H- and 13C-NMRhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2We report preliminary results for the synthesis of poly(ethylene)-graft-poly(dimethylsiloxane) copolymers (PE-g-PDMS) obtained by catalytic hydrogenation of poly(butadiene)-graft-poly(dimethylsiloxane) copolymers (PB-g-PDMS). These last copolymers were synthesized by hydrosilylation reactions between commercial poly(butadiene) (PB) and w-silane poly(dimethylsiloxane). The reaction was carried in solution catalyzed by cis-dichloro bis(diethylsufide) platinum (II) salt (Cl2[S(CH2CH3)2]Pt). The PB-g-PDMS copolymers were analyzed by 1H- and 13C-NMR spectroscopy and the relative weight percentages (wt%) of the grafted poly(dimethylsiloxane) macromonomer were determined from the integrated peak areas of the spectra.Fil: Ciolino, Andrés Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Pieroni, Olga Inés. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Vuano, Bruno Mario. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaJohn Wiley & Sons Inc2004-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/99619Ciolino, Andrés Eduardo; Pieroni, Olga Inés; Vuano, Bruno Mario; Villar, Marcelo Armando; Valles, Enrique Marcelo; Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions; John Wiley & Sons Inc; Journal of Polymer Science Part A: Polymer Chemistry; 42; 12; 6-2004; 2920-29300887-624XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/pola.20032info:eu-repo/semantics/altIdentifier/doi/10.1002/pola.20032info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:40:33Zoai:ri.conicet.gov.ar:11336/99619instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:40:33.393CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions
title Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions
spellingShingle Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions
Ciolino, Andrés Eduardo
poly(ethylene)-graft-poly(dimethylsiloxane)
hydrogenation
hydrosilylation reactions
1H- and 13C-NMR
title_short Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions
title_full Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions
title_fullStr Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions
title_full_unstemmed Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions
title_sort Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions
dc.creator.none.fl_str_mv Ciolino, Andrés Eduardo
Pieroni, Olga Inés
Vuano, Bruno Mario
Villar, Marcelo Armando
Valles, Enrique Marcelo
author Ciolino, Andrés Eduardo
author_facet Ciolino, Andrés Eduardo
Pieroni, Olga Inés
Vuano, Bruno Mario
Villar, Marcelo Armando
Valles, Enrique Marcelo
author_role author
author2 Pieroni, Olga Inés
Vuano, Bruno Mario
Villar, Marcelo Armando
Valles, Enrique Marcelo
author2_role author
author
author
author
dc.subject.none.fl_str_mv poly(ethylene)-graft-poly(dimethylsiloxane)
hydrogenation
hydrosilylation reactions
1H- and 13C-NMR
topic poly(ethylene)-graft-poly(dimethylsiloxane)
hydrogenation
hydrosilylation reactions
1H- and 13C-NMR
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv We report preliminary results for the synthesis of poly(ethylene)-graft-poly(dimethylsiloxane) copolymers (PE-g-PDMS) obtained by catalytic hydrogenation of poly(butadiene)-graft-poly(dimethylsiloxane) copolymers (PB-g-PDMS). These last copolymers were synthesized by hydrosilylation reactions between commercial poly(butadiene) (PB) and w-silane poly(dimethylsiloxane). The reaction was carried in solution catalyzed by cis-dichloro bis(diethylsufide) platinum (II) salt (Cl2[S(CH2CH3)2]Pt). The PB-g-PDMS copolymers were analyzed by 1H- and 13C-NMR spectroscopy and the relative weight percentages (wt%) of the grafted poly(dimethylsiloxane) macromonomer were determined from the integrated peak areas of the spectra.
Fil: Ciolino, Andrés Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pieroni, Olga Inés. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Vuano, Bruno Mario. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description We report preliminary results for the synthesis of poly(ethylene)-graft-poly(dimethylsiloxane) copolymers (PE-g-PDMS) obtained by catalytic hydrogenation of poly(butadiene)-graft-poly(dimethylsiloxane) copolymers (PB-g-PDMS). These last copolymers were synthesized by hydrosilylation reactions between commercial poly(butadiene) (PB) and w-silane poly(dimethylsiloxane). The reaction was carried in solution catalyzed by cis-dichloro bis(diethylsufide) platinum (II) salt (Cl2[S(CH2CH3)2]Pt). The PB-g-PDMS copolymers were analyzed by 1H- and 13C-NMR spectroscopy and the relative weight percentages (wt%) of the grafted poly(dimethylsiloxane) macromonomer were determined from the integrated peak areas of the spectra.
publishDate 2004
dc.date.none.fl_str_mv 2004-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/99619
Ciolino, Andrés Eduardo; Pieroni, Olga Inés; Vuano, Bruno Mario; Villar, Marcelo Armando; Valles, Enrique Marcelo; Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions; John Wiley & Sons Inc; Journal of Polymer Science Part A: Polymer Chemistry; 42; 12; 6-2004; 2920-2930
0887-624X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/99619
identifier_str_mv Ciolino, Andrés Eduardo; Pieroni, Olga Inés; Vuano, Bruno Mario; Villar, Marcelo Armando; Valles, Enrique Marcelo; Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions; John Wiley & Sons Inc; Journal of Polymer Science Part A: Polymer Chemistry; 42; 12; 6-2004; 2920-2930
0887-624X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/pola.20032
info:eu-repo/semantics/altIdentifier/doi/10.1002/pola.20032
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613283244408832
score 13.070432

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