6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms
- Autores
- Carro, Pilar; Müller, Kathrin; Lobo Maza, Flavia Emilia; Vericat, Carolina; Starke, Ulrich; Kern, Klaus; Salvarezza, Roberto Carlos; Grumelli, Doris Elda
- Año de publicación
- 2017
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Thiol molecules adsorbed on gold became a model system for molecular self-assembly on metal substrates long ago. In most cases the strong molecule-gold interaction is able to restructure the substrate, resulting in vacancy islands and steps. Today it is widely accepted that gold adatoms produced by this process form stable thiol-adatom complexes, usually termed "staples" (RS-Auad-SR or RS-Auad-SR-Auad-SR), which are the basic units of the self-assembled monolayers. Here we report on a different scenario for 6-mercaptopurine (6MP), a heterocyclic aromatic thiol, namely its adsorption on the Au(001)-(5 × 20) reconstructed surface. Our results show that 6MP lifts the reconstruction upon adsorption, thus ejecting a large excess of gold adatoms. Surprisingly, 6MP molecules prefer to arrange in highly ordered adatom-free domains in the bridging configuration, while the ejected adatoms form gold islands. Our investigation reveals that the formation of thiol-gold adatom complexes is not always a thermodynamically favored process but rather depends on the nature of the thiol molecule.
Fil: Carro, Pilar. Universidad de La Laguna; España
Fil: Müller, Kathrin. Max Planck Institute For Solid State Research; Alemania
Fil: Lobo Maza, Flavia Emilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Vericat, Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Starke, Ulrich. Max Planck Institute For Solid State Research; Alemania
Fil: Kern, Klaus. Max Planck Institute For Solid State Research; Alemania. Ecole Polytechnique Federale de Lausanne; Francia
Fil: Salvarezza, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Grumelli, Doris Elda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina - Materia
-
self assembled monolayers
6 mercaptopurine
Au 100 5x20
STM_LEED - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/63302
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6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold AdatomsCarro, PilarMüller, KathrinLobo Maza, Flavia EmiliaVericat, CarolinaStarke, UlrichKern, KlausSalvarezza, Roberto CarlosGrumelli, Doris Eldaself assembled monolayers6 mercaptopurineAu 100 5x20STM_LEEDhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Thiol molecules adsorbed on gold became a model system for molecular self-assembly on metal substrates long ago. In most cases the strong molecule-gold interaction is able to restructure the substrate, resulting in vacancy islands and steps. Today it is widely accepted that gold adatoms produced by this process form stable thiol-adatom complexes, usually termed "staples" (RS-Auad-SR or RS-Auad-SR-Auad-SR), which are the basic units of the self-assembled monolayers. Here we report on a different scenario for 6-mercaptopurine (6MP), a heterocyclic aromatic thiol, namely its adsorption on the Au(001)-(5 × 20) reconstructed surface. Our results show that 6MP lifts the reconstruction upon adsorption, thus ejecting a large excess of gold adatoms. Surprisingly, 6MP molecules prefer to arrange in highly ordered adatom-free domains in the bridging configuration, while the ejected adatoms form gold islands. Our investigation reveals that the formation of thiol-gold adatom complexes is not always a thermodynamically favored process but rather depends on the nature of the thiol molecule.Fil: Carro, Pilar. Universidad de La Laguna; EspañaFil: Müller, Kathrin. Max Planck Institute For Solid State Research; AlemaniaFil: Lobo Maza, Flavia Emilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Vericat, Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Starke, Ulrich. Max Planck Institute For Solid State Research; AlemaniaFil: Kern, Klaus. Max Planck Institute For Solid State Research; Alemania. Ecole Polytechnique Federale de Lausanne; FranciaFil: Salvarezza, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Grumelli, Doris Elda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaAmerican Chemical Society2017-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/63302Carro, Pilar; Müller, Kathrin; Lobo Maza, Flavia Emilia; Vericat, Carolina; Starke, Ulrich; et al.; 6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms; American Chemical Society; Journal of Physical Chemistry C; 121; 16; 4-2017; 8938-89431932-7447CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.7b02732info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.7b02732info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:39Zoai:ri.conicet.gov.ar:11336/63302instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:39.598CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms |
title |
6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms |
spellingShingle |
6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms Carro, Pilar self assembled monolayers 6 mercaptopurine Au 100 5x20 STM_LEED |
title_short |
6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms |
title_full |
6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms |
title_fullStr |
6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms |
title_full_unstemmed |
6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms |
title_sort |
6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms |
dc.creator.none.fl_str_mv |
Carro, Pilar Müller, Kathrin Lobo Maza, Flavia Emilia Vericat, Carolina Starke, Ulrich Kern, Klaus Salvarezza, Roberto Carlos Grumelli, Doris Elda |
author |
Carro, Pilar |
author_facet |
Carro, Pilar Müller, Kathrin Lobo Maza, Flavia Emilia Vericat, Carolina Starke, Ulrich Kern, Klaus Salvarezza, Roberto Carlos Grumelli, Doris Elda |
author_role |
author |
author2 |
Müller, Kathrin Lobo Maza, Flavia Emilia Vericat, Carolina Starke, Ulrich Kern, Klaus Salvarezza, Roberto Carlos Grumelli, Doris Elda |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
self assembled monolayers 6 mercaptopurine Au 100 5x20 STM_LEED |
topic |
self assembled monolayers 6 mercaptopurine Au 100 5x20 STM_LEED |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Thiol molecules adsorbed on gold became a model system for molecular self-assembly on metal substrates long ago. In most cases the strong molecule-gold interaction is able to restructure the substrate, resulting in vacancy islands and steps. Today it is widely accepted that gold adatoms produced by this process form stable thiol-adatom complexes, usually termed "staples" (RS-Auad-SR or RS-Auad-SR-Auad-SR), which are the basic units of the self-assembled monolayers. Here we report on a different scenario for 6-mercaptopurine (6MP), a heterocyclic aromatic thiol, namely its adsorption on the Au(001)-(5 × 20) reconstructed surface. Our results show that 6MP lifts the reconstruction upon adsorption, thus ejecting a large excess of gold adatoms. Surprisingly, 6MP molecules prefer to arrange in highly ordered adatom-free domains in the bridging configuration, while the ejected adatoms form gold islands. Our investigation reveals that the formation of thiol-gold adatom complexes is not always a thermodynamically favored process but rather depends on the nature of the thiol molecule. Fil: Carro, Pilar. Universidad de La Laguna; España Fil: Müller, Kathrin. Max Planck Institute For Solid State Research; Alemania Fil: Lobo Maza, Flavia Emilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: Vericat, Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: Starke, Ulrich. Max Planck Institute For Solid State Research; Alemania Fil: Kern, Klaus. Max Planck Institute For Solid State Research; Alemania. Ecole Polytechnique Federale de Lausanne; Francia Fil: Salvarezza, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: Grumelli, Doris Elda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina |
description |
Thiol molecules adsorbed on gold became a model system for molecular self-assembly on metal substrates long ago. In most cases the strong molecule-gold interaction is able to restructure the substrate, resulting in vacancy islands and steps. Today it is widely accepted that gold adatoms produced by this process form stable thiol-adatom complexes, usually termed "staples" (RS-Auad-SR or RS-Auad-SR-Auad-SR), which are the basic units of the self-assembled monolayers. Here we report on a different scenario for 6-mercaptopurine (6MP), a heterocyclic aromatic thiol, namely its adsorption on the Au(001)-(5 × 20) reconstructed surface. Our results show that 6MP lifts the reconstruction upon adsorption, thus ejecting a large excess of gold adatoms. Surprisingly, 6MP molecules prefer to arrange in highly ordered adatom-free domains in the bridging configuration, while the ejected adatoms form gold islands. Our investigation reveals that the formation of thiol-gold adatom complexes is not always a thermodynamically favored process but rather depends on the nature of the thiol molecule. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/63302 Carro, Pilar; Müller, Kathrin; Lobo Maza, Flavia Emilia; Vericat, Carolina; Starke, Ulrich; et al.; 6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms; American Chemical Society; Journal of Physical Chemistry C; 121; 16; 4-2017; 8938-8943 1932-7447 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/63302 |
identifier_str_mv |
Carro, Pilar; Müller, Kathrin; Lobo Maza, Flavia Emilia; Vericat, Carolina; Starke, Ulrich; et al.; 6-Mercaptopurine Self-Assembled Monolayers on Gold (001)-Hex: Revealing the Fate of Gold Adatoms; American Chemical Society; Journal of Physical Chemistry C; 121; 16; 4-2017; 8938-8943 1932-7447 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.7b02732 info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.7b02732 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613373651582976 |
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13.070432 |