Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays

Autores
Zanelli, Chiara; Iglesias, Claudio; Dominguez, Eduardo Alejandro; Gardini, Davide; Raimondo, Mariarosa; Guarini, Guia; Dondi, Michele
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The ball clays from the Donetzk basin, Ukraine are widely utilized in the production of ceramic tiles. Their commercial success stems from unrivaled technological properties, whose link to mineralogical composition and particle size is not well understood yet. This work is an in-depth investigation of the mineralogical, chemical, and physical properties with the aim to disclose the reasons of the peculiar technological behavior of these clays. Five clay samples were studied by XRF, XRD (bulk and fractions <. 2. μm and <. 0.2. μm), SEM, TEM, rheological characterization, particle size distribution, BET, MBI, Pfefferkorn index, Atterberg plasticity limits, and laboratory simulation of the tilemaking process. The Ukrainian clays are very fine-grained and characterized by poorly ordered kaolinite (Kaol), interstratified illite/smectite (I-Sm) and a low quartz content. The Kaol-to-I-Sm ratio is lower than in conventional ball clays and two different I-Sm types are found to be predominant in the colloidal fraction. Morphologically, clay minerals appear to be mostly subhedral lamellae that curl and fold under pressure. These characteristics explain the outstanding technological properties of Ukrainian clays and particularly their high plasticity and suitable rheological behavior. These properties depend on the peculiar conjunction of mineralogical and grain size factors that are difficult to be reproduced by clay blending or mixing design.
Fil: Zanelli, Chiara. National Research Institute. Institute Of Science And Technology For Ceramic Materials; Italia
Fil: Iglesias, Claudio. Piedra Grande Sa; Argentina
Fil: Dominguez, Eduardo Alejandro. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Gardini, Davide. National Research Institute. Institute Of Science And Technology For Ceramic Materials; Italia
Fil: Raimondo, Mariarosa. National Research Institute. Institute Of Science And Technology For Ceramic Materials; Italia
Fil: Guarini, Guia. National Research Institute. Institute Of Science And Technology For Ceramic Materials; Italia
Fil: Dondi, Michele. National Research Institute. Institute Of Science And Technology For Ceramic Materials; Italia
Materia
Ball Clay
Ceramic Tiles
Clay Mineralogy
Particle Size Distribution
Technological Properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/37820
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/37820
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball claysZanelli, ChiaraIglesias, ClaudioDominguez, Eduardo AlejandroGardini, DavideRaimondo, MariarosaGuarini, GuiaDondi, MicheleBall ClayCeramic TilesClay MineralogyParticle Size DistributionTechnological Propertieshttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1The ball clays from the Donetzk basin, Ukraine are widely utilized in the production of ceramic tiles. Their commercial success stems from unrivaled technological properties, whose link to mineralogical composition and particle size is not well understood yet. This work is an in-depth investigation of the mineralogical, chemical, and physical properties with the aim to disclose the reasons of the peculiar technological behavior of these clays. Five clay samples were studied by XRF, XRD (bulk and fractions <. 2. μm and <. 0.2. μm), SEM, TEM, rheological characterization, particle size distribution, BET, MBI, Pfefferkorn index, Atterberg plasticity limits, and laboratory simulation of the tilemaking process. The Ukrainian clays are very fine-grained and characterized by poorly ordered kaolinite (Kaol), interstratified illite/smectite (I-Sm) and a low quartz content. The Kaol-to-I-Sm ratio is lower than in conventional ball clays and two different I-Sm types are found to be predominant in the colloidal fraction. Morphologically, clay minerals appear to be mostly subhedral lamellae that curl and fold under pressure. These characteristics explain the outstanding technological properties of Ukrainian clays and particularly their high plasticity and suitable rheological behavior. These properties depend on the peculiar conjunction of mineralogical and grain size factors that are difficult to be reproduced by clay blending or mixing design.Fil: Zanelli, Chiara. National Research Institute. Institute Of Science And Technology For Ceramic Materials; ItaliaFil: Iglesias, Claudio. Piedra Grande Sa; ArgentinaFil: Dominguez, Eduardo Alejandro. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Gardini, Davide. National Research Institute. Institute Of Science And Technology For Ceramic Materials; ItaliaFil: Raimondo, Mariarosa. National Research Institute. Institute Of Science And Technology For Ceramic Materials; ItaliaFil: Guarini, Guia. National Research Institute. Institute Of Science And Technology For Ceramic Materials; ItaliaFil: Dondi, Michele. National Research Institute. Institute Of Science And Technology For Ceramic Materials; ItaliaElsevier Science2015-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37820Zanelli, Chiara; Iglesias, Claudio; Dominguez, Eduardo Alejandro; Gardini, Davide; Raimondo, Mariarosa; et al.; Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays; Elsevier Science; Applied Clay Science; 108; 5-2015; 102-1100169-1317CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0169131715000551info:eu-repo/semantics/altIdentifier/doi/10.1016/j.clay.2015.02.005info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:10:47Zoai:ri.conicet.gov.ar:11336/37820instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:10:47.991CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays
title Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays
spellingShingle Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays
Zanelli, Chiara
Ball Clay
Ceramic Tiles
Clay Mineralogy
Particle Size Distribution
Technological Properties
title_short Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays
title_full Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays
title_fullStr Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays
title_full_unstemmed Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays
title_sort Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays
dc.creator.none.fl_str_mv Zanelli, Chiara
Iglesias, Claudio
Dominguez, Eduardo Alejandro
Gardini, Davide
Raimondo, Mariarosa
Guarini, Guia
Dondi, Michele
author Zanelli, Chiara
author_facet Zanelli, Chiara
Iglesias, Claudio
Dominguez, Eduardo Alejandro
Gardini, Davide
Raimondo, Mariarosa
Guarini, Guia
Dondi, Michele
author_role author
author2 Iglesias, Claudio
Dominguez, Eduardo Alejandro
Gardini, Davide
Raimondo, Mariarosa
Guarini, Guia
Dondi, Michele
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Ball Clay
Ceramic Tiles
Clay Mineralogy
Particle Size Distribution
Technological Properties
topic Ball Clay
Ceramic Tiles
Clay Mineralogy
Particle Size Distribution
Technological Properties
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The ball clays from the Donetzk basin, Ukraine are widely utilized in the production of ceramic tiles. Their commercial success stems from unrivaled technological properties, whose link to mineralogical composition and particle size is not well understood yet. This work is an in-depth investigation of the mineralogical, chemical, and physical properties with the aim to disclose the reasons of the peculiar technological behavior of these clays. Five clay samples were studied by XRF, XRD (bulk and fractions <. 2. μm and <. 0.2. μm), SEM, TEM, rheological characterization, particle size distribution, BET, MBI, Pfefferkorn index, Atterberg plasticity limits, and laboratory simulation of the tilemaking process. The Ukrainian clays are very fine-grained and characterized by poorly ordered kaolinite (Kaol), interstratified illite/smectite (I-Sm) and a low quartz content. The Kaol-to-I-Sm ratio is lower than in conventional ball clays and two different I-Sm types are found to be predominant in the colloidal fraction. Morphologically, clay minerals appear to be mostly subhedral lamellae that curl and fold under pressure. These characteristics explain the outstanding technological properties of Ukrainian clays and particularly their high plasticity and suitable rheological behavior. These properties depend on the peculiar conjunction of mineralogical and grain size factors that are difficult to be reproduced by clay blending or mixing design.
Fil: Zanelli, Chiara. National Research Institute. Institute Of Science And Technology For Ceramic Materials; Italia
Fil: Iglesias, Claudio. Piedra Grande Sa; Argentina
Fil: Dominguez, Eduardo Alejandro. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Gardini, Davide. National Research Institute. Institute Of Science And Technology For Ceramic Materials; Italia
Fil: Raimondo, Mariarosa. National Research Institute. Institute Of Science And Technology For Ceramic Materials; Italia
Fil: Guarini, Guia. National Research Institute. Institute Of Science And Technology For Ceramic Materials; Italia
Fil: Dondi, Michele. National Research Institute. Institute Of Science And Technology For Ceramic Materials; Italia
description The ball clays from the Donetzk basin, Ukraine are widely utilized in the production of ceramic tiles. Their commercial success stems from unrivaled technological properties, whose link to mineralogical composition and particle size is not well understood yet. This work is an in-depth investigation of the mineralogical, chemical, and physical properties with the aim to disclose the reasons of the peculiar technological behavior of these clays. Five clay samples were studied by XRF, XRD (bulk and fractions <. 2. μm and <. 0.2. μm), SEM, TEM, rheological characterization, particle size distribution, BET, MBI, Pfefferkorn index, Atterberg plasticity limits, and laboratory simulation of the tilemaking process. The Ukrainian clays are very fine-grained and characterized by poorly ordered kaolinite (Kaol), interstratified illite/smectite (I-Sm) and a low quartz content. The Kaol-to-I-Sm ratio is lower than in conventional ball clays and two different I-Sm types are found to be predominant in the colloidal fraction. Morphologically, clay minerals appear to be mostly subhedral lamellae that curl and fold under pressure. These characteristics explain the outstanding technological properties of Ukrainian clays and particularly their high plasticity and suitable rheological behavior. These properties depend on the peculiar conjunction of mineralogical and grain size factors that are difficult to be reproduced by clay blending or mixing design.
publishDate 2015
dc.date.none.fl_str_mv 2015-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/37820
Zanelli, Chiara; Iglesias, Claudio; Dominguez, Eduardo Alejandro; Gardini, Davide; Raimondo, Mariarosa; et al.; Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays; Elsevier Science; Applied Clay Science; 108; 5-2015; 102-110
0169-1317
CONICET Digital
CONICET
url http://hdl.handle.net/11336/37820
identifier_str_mv Zanelli, Chiara; Iglesias, Claudio; Dominguez, Eduardo Alejandro; Gardini, Davide; Raimondo, Mariarosa; et al.; Mineralogical composition and particle size distribution as a key to understand the technological properties of Ukrainian ball clays; Elsevier Science; Applied Clay Science; 108; 5-2015; 102-110
0169-1317
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0169131715000551
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.clay.2015.02.005
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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