Inversion of the rectifying effect in diblock molecular diodes by protonation

Autores
Morales, Gustavo Marcelo; Jiang, Ping; Yuan, Shenwen; Lee, Youngu; Sanchez, Arturo; You, Wei; Yu, Luping
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A new molecular diode based on biphenyl-co-bispyrimidine was synthesized and showed a pronounced rectifying effect. Further studies indicate that protonation on the nitrogen atoms of the diode molecule by strong acids can reversibly alter the rectifying direction. This phenomenon can be envisioned as a starting point for single molecule detection devices.
Fil: Morales, Gustavo Marcelo. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; Argentina
Fil: Jiang, Ping. University of Chicago; Estados Unidos
Fil: Yuan, Shenwen. University of Chicago; Estados Unidos
Fil: Lee, Youngu. University of Chicago; Estados Unidos
Fil: Sanchez, Arturo. University of Chicago; Estados Unidos
Fil: You, Wei. University of Chicago; Estados Unidos
Fil: Yu, Luping. University of Chicago; Estados Unidos
Materia
PROTONATION
DIBLOK MOLECULAR DIODES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/115195
Acceder
id CONICETDig_3015be6ec5c0150def054a74abc8e84f
oai_identifier_str oai:ri.conicet.gov.ar:11336/115195
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Inversion of the rectifying effect in diblock molecular diodes by protonationMorales, Gustavo MarceloJiang, PingYuan, ShenwenLee, YounguSanchez, ArturoYou, WeiYu, LupingPROTONATIONDIBLOK MOLECULAR DIODEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A new molecular diode based on biphenyl-co-bispyrimidine was synthesized and showed a pronounced rectifying effect. Further studies indicate that protonation on the nitrogen atoms of the diode molecule by strong acids can reversibly alter the rectifying direction. This phenomenon can be envisioned as a starting point for single molecule detection devices.Fil: Morales, Gustavo Marcelo. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; ArgentinaFil: Jiang, Ping. University of Chicago; Estados UnidosFil: Yuan, Shenwen. University of Chicago; Estados UnidosFil: Lee, Youngu. University of Chicago; Estados UnidosFil: Sanchez, Arturo. University of Chicago; Estados UnidosFil: You, Wei. University of Chicago; Estados UnidosFil: Yu, Luping. University of Chicago; Estados UnidosAmerican Chemical Society2005-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/115195Morales, Gustavo Marcelo; Jiang, Ping; Yuan, Shenwen; Lee, Youngu; Sanchez, Arturo; et al.; Inversion of the rectifying effect in diblock molecular diodes by protonation; American Chemical Society; Journal of the American Chemical Society; 127; 30; 12-2005; 10456-104570002-7863CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ja051332cinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ja051332cinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:16:46Zoai:ri.conicet.gov.ar:11336/115195instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:16:46.321CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Inversion of the rectifying effect in diblock molecular diodes by protonation
title Inversion of the rectifying effect in diblock molecular diodes by protonation
spellingShingle Inversion of the rectifying effect in diblock molecular diodes by protonation
Morales, Gustavo Marcelo
PROTONATION
DIBLOK MOLECULAR DIODES
title_short Inversion of the rectifying effect in diblock molecular diodes by protonation
title_full Inversion of the rectifying effect in diblock molecular diodes by protonation
title_fullStr Inversion of the rectifying effect in diblock molecular diodes by protonation
title_full_unstemmed Inversion of the rectifying effect in diblock molecular diodes by protonation
title_sort Inversion of the rectifying effect in diblock molecular diodes by protonation
dc.creator.none.fl_str_mv Morales, Gustavo Marcelo
Jiang, Ping
Yuan, Shenwen
Lee, Youngu
Sanchez, Arturo
You, Wei
Yu, Luping
author Morales, Gustavo Marcelo
author_facet Morales, Gustavo Marcelo
Jiang, Ping
Yuan, Shenwen
Lee, Youngu
Sanchez, Arturo
You, Wei
Yu, Luping
author_role author
author2 Jiang, Ping
Yuan, Shenwen
Lee, Youngu
Sanchez, Arturo
You, Wei
Yu, Luping
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv PROTONATION
DIBLOK MOLECULAR DIODES
topic PROTONATION
DIBLOK MOLECULAR DIODES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A new molecular diode based on biphenyl-co-bispyrimidine was synthesized and showed a pronounced rectifying effect. Further studies indicate that protonation on the nitrogen atoms of the diode molecule by strong acids can reversibly alter the rectifying direction. This phenomenon can be envisioned as a starting point for single molecule detection devices.
Fil: Morales, Gustavo Marcelo. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados; Argentina
Fil: Jiang, Ping. University of Chicago; Estados Unidos
Fil: Yuan, Shenwen. University of Chicago; Estados Unidos
Fil: Lee, Youngu. University of Chicago; Estados Unidos
Fil: Sanchez, Arturo. University of Chicago; Estados Unidos
Fil: You, Wei. University of Chicago; Estados Unidos
Fil: Yu, Luping. University of Chicago; Estados Unidos
description A new molecular diode based on biphenyl-co-bispyrimidine was synthesized and showed a pronounced rectifying effect. Further studies indicate that protonation on the nitrogen atoms of the diode molecule by strong acids can reversibly alter the rectifying direction. This phenomenon can be envisioned as a starting point for single molecule detection devices.
publishDate 2005
dc.date.none.fl_str_mv 2005-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/115195
Morales, Gustavo Marcelo; Jiang, Ping; Yuan, Shenwen; Lee, Youngu; Sanchez, Arturo; et al.; Inversion of the rectifying effect in diblock molecular diodes by protonation; American Chemical Society; Journal of the American Chemical Society; 127; 30; 12-2005; 10456-10457
0002-7863
CONICET Digital
CONICET
url http://hdl.handle.net/11336/115195
identifier_str_mv Morales, Gustavo Marcelo; Jiang, Ping; Yuan, Shenwen; Lee, Youngu; Sanchez, Arturo; et al.; Inversion of the rectifying effect in diblock molecular diodes by protonation; American Chemical Society; Journal of the American Chemical Society; 127; 30; 12-2005; 10456-10457
0002-7863
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ja051332c
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ja051332c
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781621888352256
score 12.982451

Publicaciones similares