Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application
- Autores
- Thomas, Yohann; Bruno, Mariano Martín; Corti, Horacio Roberto
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The preparation and characterization of a monolithic mesoporous carbon structure, which could be used as diffusion layer in PEM and DMPEM micro fuel cells, is described. Several characteristics of the monolithic carbon were studied, such as specific surface area, pore size distribution, bulk electrical resistivity, contact resistance with graphite plates, along with the wettability, imbibition and permeability of methanol aqueous solution. These properties were compared to those reported for commercial carbon paper and carbon cloth materials commonly used as diffusion layers in PEM fuel cells. The electrical properties of the mesoporous carbon meet the requirements to be employed as diffusion layers in PEM stacks assembled at pressures above 15 bar. The rapid spreading and imbibition of concentrated methanol solutions in the mesoporous carbon, as well as the permeability of the aqueous methanol through it, also make this mesostructured carbon a possible candidate for diffusion layer and catalyst support in passive direct methanol micro fuel cells.
Fil: Thomas, Yohann. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones No Nucleares. Gerencia Física (CAC). Departamento de Física de la Materia Condensada; Argentina
Fil: Bruno, Mariano Martín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones No Nucleares. Gerencia Física (CAC). Departamento de Física de la Materia Condensada; Argentina
Fil: Corti, Horacio Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones No Nucleares. Gerencia Física (CAC). Departamento de Física de la Materia Condensada; Argentina - Materia
-
CONTACT RESISTANCE
DIFFUSION LAYER
MESOPOROUS CARBON
MICRO FUEL CELLS
PERMEABILITY - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/194865
Ver los metadatos del registro completo
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Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells applicationThomas, YohannBruno, Mariano MartínCorti, Horacio RobertoCONTACT RESISTANCEDIFFUSION LAYERMESOPOROUS CARBONMICRO FUEL CELLSPERMEABILITYhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The preparation and characterization of a monolithic mesoporous carbon structure, which could be used as diffusion layer in PEM and DMPEM micro fuel cells, is described. Several characteristics of the monolithic carbon were studied, such as specific surface area, pore size distribution, bulk electrical resistivity, contact resistance with graphite plates, along with the wettability, imbibition and permeability of methanol aqueous solution. These properties were compared to those reported for commercial carbon paper and carbon cloth materials commonly used as diffusion layers in PEM fuel cells. The electrical properties of the mesoporous carbon meet the requirements to be employed as diffusion layers in PEM stacks assembled at pressures above 15 bar. The rapid spreading and imbibition of concentrated methanol solutions in the mesoporous carbon, as well as the permeability of the aqueous methanol through it, also make this mesostructured carbon a possible candidate for diffusion layer and catalyst support in passive direct methanol micro fuel cells.Fil: Thomas, Yohann. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones No Nucleares. Gerencia Física (CAC). Departamento de Física de la Materia Condensada; ArgentinaFil: Bruno, Mariano Martín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones No Nucleares. Gerencia Física (CAC). Departamento de Física de la Materia Condensada; ArgentinaFil: Corti, Horacio Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones No Nucleares. Gerencia Física (CAC). Departamento de Física de la Materia Condensada; ArgentinaElsevier Science2012-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/194865Thomas, Yohann; Bruno, Mariano Martín; Corti, Horacio Roberto; Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application; Elsevier Science; Microporous and Mesoporous Materials; 155; 6-2012; 47-551387-18111873-3093CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1387181112000224info:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2012.01.012info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:27:56Zoai:ri.conicet.gov.ar:11336/194865instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:27:57.153CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application |
title |
Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application |
spellingShingle |
Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application Thomas, Yohann CONTACT RESISTANCE DIFFUSION LAYER MESOPOROUS CARBON MICRO FUEL CELLS PERMEABILITY |
title_short |
Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application |
title_full |
Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application |
title_fullStr |
Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application |
title_full_unstemmed |
Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application |
title_sort |
Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application |
dc.creator.none.fl_str_mv |
Thomas, Yohann Bruno, Mariano Martín Corti, Horacio Roberto |
author |
Thomas, Yohann |
author_facet |
Thomas, Yohann Bruno, Mariano Martín Corti, Horacio Roberto |
author_role |
author |
author2 |
Bruno, Mariano Martín Corti, Horacio Roberto |
author2_role |
author author |
dc.subject.none.fl_str_mv |
CONTACT RESISTANCE DIFFUSION LAYER MESOPOROUS CARBON MICRO FUEL CELLS PERMEABILITY |
topic |
CONTACT RESISTANCE DIFFUSION LAYER MESOPOROUS CARBON MICRO FUEL CELLS PERMEABILITY |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The preparation and characterization of a monolithic mesoporous carbon structure, which could be used as diffusion layer in PEM and DMPEM micro fuel cells, is described. Several characteristics of the monolithic carbon were studied, such as specific surface area, pore size distribution, bulk electrical resistivity, contact resistance with graphite plates, along with the wettability, imbibition and permeability of methanol aqueous solution. These properties were compared to those reported for commercial carbon paper and carbon cloth materials commonly used as diffusion layers in PEM fuel cells. The electrical properties of the mesoporous carbon meet the requirements to be employed as diffusion layers in PEM stacks assembled at pressures above 15 bar. The rapid spreading and imbibition of concentrated methanol solutions in the mesoporous carbon, as well as the permeability of the aqueous methanol through it, also make this mesostructured carbon a possible candidate for diffusion layer and catalyst support in passive direct methanol micro fuel cells. Fil: Thomas, Yohann. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones No Nucleares. Gerencia Física (CAC). Departamento de Física de la Materia Condensada; Argentina Fil: Bruno, Mariano Martín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones No Nucleares. Gerencia Física (CAC). Departamento de Física de la Materia Condensada; Argentina Fil: Corti, Horacio Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Comisión Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones No Nucleares. Gerencia Física (CAC). Departamento de Física de la Materia Condensada; Argentina |
description |
The preparation and characterization of a monolithic mesoporous carbon structure, which could be used as diffusion layer in PEM and DMPEM micro fuel cells, is described. Several characteristics of the monolithic carbon were studied, such as specific surface area, pore size distribution, bulk electrical resistivity, contact resistance with graphite plates, along with the wettability, imbibition and permeability of methanol aqueous solution. These properties were compared to those reported for commercial carbon paper and carbon cloth materials commonly used as diffusion layers in PEM fuel cells. The electrical properties of the mesoporous carbon meet the requirements to be employed as diffusion layers in PEM stacks assembled at pressures above 15 bar. The rapid spreading and imbibition of concentrated methanol solutions in the mesoporous carbon, as well as the permeability of the aqueous methanol through it, also make this mesostructured carbon a possible candidate for diffusion layer and catalyst support in passive direct methanol micro fuel cells. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/194865 Thomas, Yohann; Bruno, Mariano Martín; Corti, Horacio Roberto; Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application; Elsevier Science; Microporous and Mesoporous Materials; 155; 6-2012; 47-55 1387-1811 1873-3093 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/194865 |
identifier_str_mv |
Thomas, Yohann; Bruno, Mariano Martín; Corti, Horacio Roberto; Characterization of a monolithic mesoporous carbon as diffusion layer for micro fuel cells application; Elsevier Science; Microporous and Mesoporous Materials; 155; 6-2012; 47-55 1387-1811 1873-3093 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1387181112000224 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2012.01.012 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614282237444096 |
score |
13.070432 |