Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine

Autores
Kiemde, Abdoul Fattah; Marin, Jérôme; Flexer, Victoria; Chagnes, Alexandre
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The extraction properties of mono-hydroxy alcohols (2-butyl-1-octanol, 2-ethyl-1-hexanol, 1-octanol) and dihydroxy alcohols (2-ethyl-1,3-hexanediol, 2-butyl-2-ethyl-1,3-propanediol, 2-methyl-2,4-pentanediol) towards boron, potassium, lithium, sodium, calcium and magnesium ions were investigated as a function of pH and phase volume ratio (O/A) by considering an aqueous phase with a composition mimicking the brine from the Salar de Hombre Muerto in Argentina, in the Lithium Triangle. The mono-hydroxy alcohols are soluble in kerosene and sulfonated kerosene whereas the di-hydroxy alcohols are only soluble in mixtures of kerosene and toluene or mxylene.No significant effect of the diluent on the extraction properties is observed. All alcohols exhibit high selectivity for boron over potassium, lithium, sodium, calcium and magnesium at acidic pH (pH=1–5.5). A significant decrease of the extraction efficiency of boron by the mono-hydroxy alcohols is observed at pH >5.5 while no significant decrease of the extraction efficiency occurs with di-hydroxy alcohols. Finally, the best conditions to selectively extract boron from the synthetic brine with 1 mol L−1 mono-hydroxy alcohols or di-hydroxy alcohols at 35 °C are pH = 5.5 and O/A = 4 when the diluent is kerosene and O/A = 2 when the diluent is a mixture of kerosene and toluene.
Fil: Kiemde, Abdoul Fattah. Universite de Lorraine.; Francia
Fil: Marin, Jérôme. Universite de Lorraine.; Francia
Fil: Flexer, Victoria. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; Argentina
Fil: Chagnes, Alexandre. Universite de Lorraine.; Francia
Materia
Boron
Lithium-rich brine
Solvent extraction
Alcohols
Diluent
Hydrometallurgy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/233520
Acceder
id CONICETDig_2cd80f24ead83bbfcfda1f20cb8af9b6
oai_identifier_str oai:ri.conicet.gov.ar:11336/233520
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brineKiemde, Abdoul FattahMarin, JérômeFlexer, VictoriaChagnes, AlexandreBoronLithium-rich brineSolvent extractionAlcoholsDiluentHydrometallurgyhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The extraction properties of mono-hydroxy alcohols (2-butyl-1-octanol, 2-ethyl-1-hexanol, 1-octanol) and dihydroxy alcohols (2-ethyl-1,3-hexanediol, 2-butyl-2-ethyl-1,3-propanediol, 2-methyl-2,4-pentanediol) towards boron, potassium, lithium, sodium, calcium and magnesium ions were investigated as a function of pH and phase volume ratio (O/A) by considering an aqueous phase with a composition mimicking the brine from the Salar de Hombre Muerto in Argentina, in the Lithium Triangle. The mono-hydroxy alcohols are soluble in kerosene and sulfonated kerosene whereas the di-hydroxy alcohols are only soluble in mixtures of kerosene and toluene or mxylene.No significant effect of the diluent on the extraction properties is observed. All alcohols exhibit high selectivity for boron over potassium, lithium, sodium, calcium and magnesium at acidic pH (pH=1–5.5). A significant decrease of the extraction efficiency of boron by the mono-hydroxy alcohols is observed at pH >5.5 while no significant decrease of the extraction efficiency occurs with di-hydroxy alcohols. Finally, the best conditions to selectively extract boron from the synthetic brine with 1 mol L−1 mono-hydroxy alcohols or di-hydroxy alcohols at 35 °C are pH = 5.5 and O/A = 4 when the diluent is kerosene and O/A = 2 when the diluent is a mixture of kerosene and toluene.Fil: Kiemde, Abdoul Fattah. Universite de Lorraine.; FranciaFil: Marin, Jérôme. Universite de Lorraine.; FranciaFil: Flexer, Victoria. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; ArgentinaFil: Chagnes, Alexandre. Universite de Lorraine.; FranciaElsevier Science2024-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/233520Kiemde, Abdoul Fattah; Marin, Jérôme; Flexer, Victoria; Chagnes, Alexandre; Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine; Elsevier Science; Hydrometallurgy (Amsterdam); 225; 2-2024; 1-110304-386XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0304386X24000203info:eu-repo/semantics/altIdentifier/doi/10.1016/j.hydromet.2024.106280info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:51:09Zoai:ri.conicet.gov.ar:11336/233520instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:51:09.497CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine
title Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine
spellingShingle Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine
Kiemde, Abdoul Fattah
Boron
Lithium-rich brine
Solvent extraction
Alcohols
Diluent
Hydrometallurgy
title_short Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine
title_full Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine
title_fullStr Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine
title_full_unstemmed Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine
title_sort Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine
dc.creator.none.fl_str_mv Kiemde, Abdoul Fattah
Marin, Jérôme
Flexer, Victoria
Chagnes, Alexandre
author Kiemde, Abdoul Fattah
author_facet Kiemde, Abdoul Fattah
Marin, Jérôme
Flexer, Victoria
Chagnes, Alexandre
author_role author
author2 Marin, Jérôme
Flexer, Victoria
Chagnes, Alexandre
author2_role author
author
author
dc.subject.none.fl_str_mv Boron
Lithium-rich brine
Solvent extraction
Alcohols
Diluent
Hydrometallurgy
topic Boron
Lithium-rich brine
Solvent extraction
Alcohols
Diluent
Hydrometallurgy
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The extraction properties of mono-hydroxy alcohols (2-butyl-1-octanol, 2-ethyl-1-hexanol, 1-octanol) and dihydroxy alcohols (2-ethyl-1,3-hexanediol, 2-butyl-2-ethyl-1,3-propanediol, 2-methyl-2,4-pentanediol) towards boron, potassium, lithium, sodium, calcium and magnesium ions were investigated as a function of pH and phase volume ratio (O/A) by considering an aqueous phase with a composition mimicking the brine from the Salar de Hombre Muerto in Argentina, in the Lithium Triangle. The mono-hydroxy alcohols are soluble in kerosene and sulfonated kerosene whereas the di-hydroxy alcohols are only soluble in mixtures of kerosene and toluene or mxylene.No significant effect of the diluent on the extraction properties is observed. All alcohols exhibit high selectivity for boron over potassium, lithium, sodium, calcium and magnesium at acidic pH (pH=1–5.5). A significant decrease of the extraction efficiency of boron by the mono-hydroxy alcohols is observed at pH >5.5 while no significant decrease of the extraction efficiency occurs with di-hydroxy alcohols. Finally, the best conditions to selectively extract boron from the synthetic brine with 1 mol L−1 mono-hydroxy alcohols or di-hydroxy alcohols at 35 °C are pH = 5.5 and O/A = 4 when the diluent is kerosene and O/A = 2 when the diluent is a mixture of kerosene and toluene.
Fil: Kiemde, Abdoul Fattah. Universite de Lorraine.; Francia
Fil: Marin, Jérôme. Universite de Lorraine.; Francia
Fil: Flexer, Victoria. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; Argentina
Fil: Chagnes, Alexandre. Universite de Lorraine.; Francia
description The extraction properties of mono-hydroxy alcohols (2-butyl-1-octanol, 2-ethyl-1-hexanol, 1-octanol) and dihydroxy alcohols (2-ethyl-1,3-hexanediol, 2-butyl-2-ethyl-1,3-propanediol, 2-methyl-2,4-pentanediol) towards boron, potassium, lithium, sodium, calcium and magnesium ions were investigated as a function of pH and phase volume ratio (O/A) by considering an aqueous phase with a composition mimicking the brine from the Salar de Hombre Muerto in Argentina, in the Lithium Triangle. The mono-hydroxy alcohols are soluble in kerosene and sulfonated kerosene whereas the di-hydroxy alcohols are only soluble in mixtures of kerosene and toluene or mxylene.No significant effect of the diluent on the extraction properties is observed. All alcohols exhibit high selectivity for boron over potassium, lithium, sodium, calcium and magnesium at acidic pH (pH=1–5.5). A significant decrease of the extraction efficiency of boron by the mono-hydroxy alcohols is observed at pH >5.5 while no significant decrease of the extraction efficiency occurs with di-hydroxy alcohols. Finally, the best conditions to selectively extract boron from the synthetic brine with 1 mol L−1 mono-hydroxy alcohols or di-hydroxy alcohols at 35 °C are pH = 5.5 and O/A = 4 when the diluent is kerosene and O/A = 2 when the diluent is a mixture of kerosene and toluene.
publishDate 2024
dc.date.none.fl_str_mv 2024-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/233520
Kiemde, Abdoul Fattah; Marin, Jérôme; Flexer, Victoria; Chagnes, Alexandre; Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine; Elsevier Science; Hydrometallurgy (Amsterdam); 225; 2-2024; 1-11
0304-386X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/233520
identifier_str_mv Kiemde, Abdoul Fattah; Marin, Jérôme; Flexer, Victoria; Chagnes, Alexandre; Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine; Elsevier Science; Hydrometallurgy (Amsterdam); 225; 2-2024; 1-11
0304-386X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0304386X24000203
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.hydromet.2024.106280
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083037365796864
score 13.22299

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