Processing and microstructure of PCL/clay nanocomposites
- Autores
- Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Vázquez, Analía
- Año de publicación
- 2007
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The morphology and mechanical properties of polycaprolactone/clay nanocomposite films prepared by two techniques (casting: exfoliation-adsorption; intensive mixing: melt-intercalation) were studied. Casting, which is a laboratory scale technique, was selected because it was supposed that the exfoliation of the layered silicate into single layers would be easier since the solvent acts as an exfoliation agent. The other selected technique was chosen because it can be used in the industry. X-ray diffractograms revealed an intercalated-exfoliated mixed structure for both techniques. For casting, the morphology and mechanical properties are influenced by the used solvent and the preparation conditions being the first one the most critical parameter. Otherwise, in the case of intensive mixing, a higher clay dispersion degree was produced by shear forces and the resultant mechanical properties were superior to those obtained by casting. In both cases, the highest modulus was achieved for 5 wt.% of C30B. Finally, an effective filler-parameters model was used to compare the relative dispersion of clay within the nanocomposites for both processes from the experimental modulus values.
Fil: Ludueña, Leandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
Biodegradable
Clay
Montmorillonite
Nanocomposites
Polycaprolactone
Silicate - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/70047
Ver los metadatos del registro completo
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Processing and microstructure of PCL/clay nanocompositesLudueña, Leandro NicolásAlvarez, Vera AlejandraVázquez, AnalíaBiodegradableClayMontmorilloniteNanocompositesPolycaprolactoneSilicatehttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2The morphology and mechanical properties of polycaprolactone/clay nanocomposite films prepared by two techniques (casting: exfoliation-adsorption; intensive mixing: melt-intercalation) were studied. Casting, which is a laboratory scale technique, was selected because it was supposed that the exfoliation of the layered silicate into single layers would be easier since the solvent acts as an exfoliation agent. The other selected technique was chosen because it can be used in the industry. X-ray diffractograms revealed an intercalated-exfoliated mixed structure for both techniques. For casting, the morphology and mechanical properties are influenced by the used solvent and the preparation conditions being the first one the most critical parameter. Otherwise, in the case of intensive mixing, a higher clay dispersion degree was produced by shear forces and the resultant mechanical properties were superior to those obtained by casting. In both cases, the highest modulus was achieved for 5 wt.% of C30B. Finally, an effective filler-parameters model was used to compare the relative dispersion of clay within the nanocomposites for both processes from the experimental modulus values.Fil: Ludueña, Leandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier Science Sa2007-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70047Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Vázquez, Analía; Processing and microstructure of PCL/clay nanocomposites; Elsevier Science Sa; Materials Science and Engineering A: Structural Materials: Properties, Microstructure and Processing; 460-461; 7-2007; 121-1290921-5093CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.msea.2007.01.104info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0921509307001827info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:05Zoai:ri.conicet.gov.ar:11336/70047instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:05.838CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Processing and microstructure of PCL/clay nanocomposites |
title |
Processing and microstructure of PCL/clay nanocomposites |
spellingShingle |
Processing and microstructure of PCL/clay nanocomposites Ludueña, Leandro Nicolás Biodegradable Clay Montmorillonite Nanocomposites Polycaprolactone Silicate |
title_short |
Processing and microstructure of PCL/clay nanocomposites |
title_full |
Processing and microstructure of PCL/clay nanocomposites |
title_fullStr |
Processing and microstructure of PCL/clay nanocomposites |
title_full_unstemmed |
Processing and microstructure of PCL/clay nanocomposites |
title_sort |
Processing and microstructure of PCL/clay nanocomposites |
dc.creator.none.fl_str_mv |
Ludueña, Leandro Nicolás Alvarez, Vera Alejandra Vázquez, Analía |
author |
Ludueña, Leandro Nicolás |
author_facet |
Ludueña, Leandro Nicolás Alvarez, Vera Alejandra Vázquez, Analía |
author_role |
author |
author2 |
Alvarez, Vera Alejandra Vázquez, Analía |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Biodegradable Clay Montmorillonite Nanocomposites Polycaprolactone Silicate |
topic |
Biodegradable Clay Montmorillonite Nanocomposites Polycaprolactone Silicate |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.10 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The morphology and mechanical properties of polycaprolactone/clay nanocomposite films prepared by two techniques (casting: exfoliation-adsorption; intensive mixing: melt-intercalation) were studied. Casting, which is a laboratory scale technique, was selected because it was supposed that the exfoliation of the layered silicate into single layers would be easier since the solvent acts as an exfoliation agent. The other selected technique was chosen because it can be used in the industry. X-ray diffractograms revealed an intercalated-exfoliated mixed structure for both techniques. For casting, the morphology and mechanical properties are influenced by the used solvent and the preparation conditions being the first one the most critical parameter. Otherwise, in the case of intensive mixing, a higher clay dispersion degree was produced by shear forces and the resultant mechanical properties were superior to those obtained by casting. In both cases, the highest modulus was achieved for 5 wt.% of C30B. Finally, an effective filler-parameters model was used to compare the relative dispersion of clay within the nanocomposites for both processes from the experimental modulus values. Fil: Ludueña, Leandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
The morphology and mechanical properties of polycaprolactone/clay nanocomposite films prepared by two techniques (casting: exfoliation-adsorption; intensive mixing: melt-intercalation) were studied. Casting, which is a laboratory scale technique, was selected because it was supposed that the exfoliation of the layered silicate into single layers would be easier since the solvent acts as an exfoliation agent. The other selected technique was chosen because it can be used in the industry. X-ray diffractograms revealed an intercalated-exfoliated mixed structure for both techniques. For casting, the morphology and mechanical properties are influenced by the used solvent and the preparation conditions being the first one the most critical parameter. Otherwise, in the case of intensive mixing, a higher clay dispersion degree was produced by shear forces and the resultant mechanical properties were superior to those obtained by casting. In both cases, the highest modulus was achieved for 5 wt.% of C30B. Finally, an effective filler-parameters model was used to compare the relative dispersion of clay within the nanocomposites for both processes from the experimental modulus values. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007-07 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/70047 Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Vázquez, Analía; Processing and microstructure of PCL/clay nanocomposites; Elsevier Science Sa; Materials Science and Engineering A: Structural Materials: Properties, Microstructure and Processing; 460-461; 7-2007; 121-129 0921-5093 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/70047 |
identifier_str_mv |
Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Vázquez, Analía; Processing and microstructure of PCL/clay nanocomposites; Elsevier Science Sa; Materials Science and Engineering A: Structural Materials: Properties, Microstructure and Processing; 460-461; 7-2007; 121-129 0921-5093 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.msea.2007.01.104 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0921509307001827 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science Sa |
publisher.none.fl_str_mv |
Elsevier Science Sa |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |