Processing and microstructure of PCL/clay nanocomposites

Autores
Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Vázquez, Analía
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The morphology and mechanical properties of polycaprolactone/clay nanocomposite films prepared by two techniques (casting: exfoliation-adsorption; intensive mixing: melt-intercalation) were studied. Casting, which is a laboratory scale technique, was selected because it was supposed that the exfoliation of the layered silicate into single layers would be easier since the solvent acts as an exfoliation agent. The other selected technique was chosen because it can be used in the industry. X-ray diffractograms revealed an intercalated-exfoliated mixed structure for both techniques. For casting, the morphology and mechanical properties are influenced by the used solvent and the preparation conditions being the first one the most critical parameter. Otherwise, in the case of intensive mixing, a higher clay dispersion degree was produced by shear forces and the resultant mechanical properties were superior to those obtained by casting. In both cases, the highest modulus was achieved for 5 wt.% of C30B. Finally, an effective filler-parameters model was used to compare the relative dispersion of clay within the nanocomposites for both processes from the experimental modulus values.
Fil: Ludueña, Leandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Biodegradable
Clay
Montmorillonite
Nanocomposites
Polycaprolactone
Silicate
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/70047
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Processing and microstructure of PCL/clay nanocompositesLudueña, Leandro NicolásAlvarez, Vera AlejandraVázquez, AnalíaBiodegradableClayMontmorilloniteNanocompositesPolycaprolactoneSilicatehttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2The morphology and mechanical properties of polycaprolactone/clay nanocomposite films prepared by two techniques (casting: exfoliation-adsorption; intensive mixing: melt-intercalation) were studied. Casting, which is a laboratory scale technique, was selected because it was supposed that the exfoliation of the layered silicate into single layers would be easier since the solvent acts as an exfoliation agent. The other selected technique was chosen because it can be used in the industry. X-ray diffractograms revealed an intercalated-exfoliated mixed structure for both techniques. For casting, the morphology and mechanical properties are influenced by the used solvent and the preparation conditions being the first one the most critical parameter. Otherwise, in the case of intensive mixing, a higher clay dispersion degree was produced by shear forces and the resultant mechanical properties were superior to those obtained by casting. In both cases, the highest modulus was achieved for 5 wt.% of C30B. Finally, an effective filler-parameters model was used to compare the relative dispersion of clay within the nanocomposites for both processes from the experimental modulus values.Fil: Ludueña, Leandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier Science Sa2007-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70047Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Vázquez, Analía; Processing and microstructure of PCL/clay nanocomposites; Elsevier Science Sa; Materials Science and Engineering A: Structural Materials: Properties, Microstructure and Processing; 460-461; 7-2007; 121-1290921-5093CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.msea.2007.01.104info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0921509307001827info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:22:18Zoai:ri.conicet.gov.ar:11336/70047instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:22:18.945CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Processing and microstructure of PCL/clay nanocomposites
title Processing and microstructure of PCL/clay nanocomposites
spellingShingle Processing and microstructure of PCL/clay nanocomposites
Ludueña, Leandro Nicolás
Biodegradable
Clay
Montmorillonite
Nanocomposites
Polycaprolactone
Silicate
title_short Processing and microstructure of PCL/clay nanocomposites
title_full Processing and microstructure of PCL/clay nanocomposites
title_fullStr Processing and microstructure of PCL/clay nanocomposites
title_full_unstemmed Processing and microstructure of PCL/clay nanocomposites
title_sort Processing and microstructure of PCL/clay nanocomposites
dc.creator.none.fl_str_mv Ludueña, Leandro Nicolás
Alvarez, Vera Alejandra
Vázquez, Analía
author Ludueña, Leandro Nicolás
author_facet Ludueña, Leandro Nicolás
Alvarez, Vera Alejandra
Vázquez, Analía
author_role author
author2 Alvarez, Vera Alejandra
Vázquez, Analía
author2_role author
author
dc.subject.none.fl_str_mv Biodegradable
Clay
Montmorillonite
Nanocomposites
Polycaprolactone
Silicate
topic Biodegradable
Clay
Montmorillonite
Nanocomposites
Polycaprolactone
Silicate
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The morphology and mechanical properties of polycaprolactone/clay nanocomposite films prepared by two techniques (casting: exfoliation-adsorption; intensive mixing: melt-intercalation) were studied. Casting, which is a laboratory scale technique, was selected because it was supposed that the exfoliation of the layered silicate into single layers would be easier since the solvent acts as an exfoliation agent. The other selected technique was chosen because it can be used in the industry. X-ray diffractograms revealed an intercalated-exfoliated mixed structure for both techniques. For casting, the morphology and mechanical properties are influenced by the used solvent and the preparation conditions being the first one the most critical parameter. Otherwise, in the case of intensive mixing, a higher clay dispersion degree was produced by shear forces and the resultant mechanical properties were superior to those obtained by casting. In both cases, the highest modulus was achieved for 5 wt.% of C30B. Finally, an effective filler-parameters model was used to compare the relative dispersion of clay within the nanocomposites for both processes from the experimental modulus values.
Fil: Ludueña, Leandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description The morphology and mechanical properties of polycaprolactone/clay nanocomposite films prepared by two techniques (casting: exfoliation-adsorption; intensive mixing: melt-intercalation) were studied. Casting, which is a laboratory scale technique, was selected because it was supposed that the exfoliation of the layered silicate into single layers would be easier since the solvent acts as an exfoliation agent. The other selected technique was chosen because it can be used in the industry. X-ray diffractograms revealed an intercalated-exfoliated mixed structure for both techniques. For casting, the morphology and mechanical properties are influenced by the used solvent and the preparation conditions being the first one the most critical parameter. Otherwise, in the case of intensive mixing, a higher clay dispersion degree was produced by shear forces and the resultant mechanical properties were superior to those obtained by casting. In both cases, the highest modulus was achieved for 5 wt.% of C30B. Finally, an effective filler-parameters model was used to compare the relative dispersion of clay within the nanocomposites for both processes from the experimental modulus values.
publishDate 2007
dc.date.none.fl_str_mv 2007-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/70047
Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Vázquez, Analía; Processing and microstructure of PCL/clay nanocomposites; Elsevier Science Sa; Materials Science and Engineering A: Structural Materials: Properties, Microstructure and Processing; 460-461; 7-2007; 121-129
0921-5093
CONICET Digital
CONICET
url http://hdl.handle.net/11336/70047
identifier_str_mv Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Vázquez, Analía; Processing and microstructure of PCL/clay nanocomposites; Elsevier Science Sa; Materials Science and Engineering A: Structural Materials: Properties, Microstructure and Processing; 460-461; 7-2007; 121-129
0921-5093
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.msea.2007.01.104
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0921509307001827
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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