Nanoscale Toroidal Ferroelectricity in PbTiO 3

Autores
Stachiotti, Marcelo Gabriel; Sepliarsky, Marcelo Claudio
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We applied a first-principles-based atomistic approach to investigate the formation of dipole patterns in isolated stress-free PbTiO3 nanoparticles of rectangular shape. We found that a sequence of topological transformations takes place as the aspect ratio of the nanostructure changes from elongated nanorods to flat nanoplatelets. Of a particular interest is the formation of a four-vortex state with cores aligned along a closed path. In this way, the vortex structure forms a ring-shaped torus, and a ferroelectric bubble is developed at the center of the ring. The thermal properties of the bubbles indicate that this state is suitable for the development of nanometric ferroelectric devices. Our results cover, for the first time, the gap between the nanodots and wires and between the nanodots and thin films, that is between 0D and 1D as well as between 0D and 2D objects.
Fil: Stachiotti, Marcelo Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
Fil: Sepliarsky, Marcelo Claudio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
Materia
FERROELECTRICS
NANOPARTICLES
SIMULATIONS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/272012
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Nanoscale Toroidal Ferroelectricity in PbTiO 3Stachiotti, Marcelo GabrielSepliarsky, Marcelo ClaudioFERROELECTRICSNANOPARTICLESSIMULATIONShttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1We applied a first-principles-based atomistic approach to investigate the formation of dipole patterns in isolated stress-free PbTiO3 nanoparticles of rectangular shape. We found that a sequence of topological transformations takes place as the aspect ratio of the nanostructure changes from elongated nanorods to flat nanoplatelets. Of a particular interest is the formation of a four-vortex state with cores aligned along a closed path. In this way, the vortex structure forms a ring-shaped torus, and a ferroelectric bubble is developed at the center of the ring. The thermal properties of the bubbles indicate that this state is suitable for the development of nanometric ferroelectric devices. Our results cover, for the first time, the gap between the nanodots and wires and between the nanodots and thin films, that is between 0D and 1D as well as between 0D and 2D objects.Fil: Stachiotti, Marcelo Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; ArgentinaFil: Sepliarsky, Marcelo Claudio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; ArgentinaTaylor & Francis Ltd2012-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/272012Stachiotti, Marcelo Gabriel; Sepliarsky, Marcelo Claudio; Nanoscale Toroidal Ferroelectricity in PbTiO 3; Taylor & Francis Ltd; Ferroelectrics; 427; 1; 3-2012; 41-510015-0193CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/00150193.2012.673916info:eu-repo/semantics/altIdentifier/doi/10.1080/00150193.2012.673916info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:42:18Zoai:ri.conicet.gov.ar:11336/272012instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:42:19.014CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Nanoscale Toroidal Ferroelectricity in PbTiO 3
title Nanoscale Toroidal Ferroelectricity in PbTiO 3
spellingShingle Nanoscale Toroidal Ferroelectricity in PbTiO 3
Stachiotti, Marcelo Gabriel
FERROELECTRICS
NANOPARTICLES
SIMULATIONS
title_short Nanoscale Toroidal Ferroelectricity in PbTiO 3
title_full Nanoscale Toroidal Ferroelectricity in PbTiO 3
title_fullStr Nanoscale Toroidal Ferroelectricity in PbTiO 3
title_full_unstemmed Nanoscale Toroidal Ferroelectricity in PbTiO 3
title_sort Nanoscale Toroidal Ferroelectricity in PbTiO 3
dc.creator.none.fl_str_mv Stachiotti, Marcelo Gabriel
Sepliarsky, Marcelo Claudio
author Stachiotti, Marcelo Gabriel
author_facet Stachiotti, Marcelo Gabriel
Sepliarsky, Marcelo Claudio
author_role author
author2 Sepliarsky, Marcelo Claudio
author2_role author
dc.subject.none.fl_str_mv FERROELECTRICS
NANOPARTICLES
SIMULATIONS
topic FERROELECTRICS
NANOPARTICLES
SIMULATIONS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We applied a first-principles-based atomistic approach to investigate the formation of dipole patterns in isolated stress-free PbTiO3 nanoparticles of rectangular shape. We found that a sequence of topological transformations takes place as the aspect ratio of the nanostructure changes from elongated nanorods to flat nanoplatelets. Of a particular interest is the formation of a four-vortex state with cores aligned along a closed path. In this way, the vortex structure forms a ring-shaped torus, and a ferroelectric bubble is developed at the center of the ring. The thermal properties of the bubbles indicate that this state is suitable for the development of nanometric ferroelectric devices. Our results cover, for the first time, the gap between the nanodots and wires and between the nanodots and thin films, that is between 0D and 1D as well as between 0D and 2D objects.
Fil: Stachiotti, Marcelo Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
Fil: Sepliarsky, Marcelo Claudio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Física de Rosario. Universidad Nacional de Rosario. Instituto de Física de Rosario; Argentina
description We applied a first-principles-based atomistic approach to investigate the formation of dipole patterns in isolated stress-free PbTiO3 nanoparticles of rectangular shape. We found that a sequence of topological transformations takes place as the aspect ratio of the nanostructure changes from elongated nanorods to flat nanoplatelets. Of a particular interest is the formation of a four-vortex state with cores aligned along a closed path. In this way, the vortex structure forms a ring-shaped torus, and a ferroelectric bubble is developed at the center of the ring. The thermal properties of the bubbles indicate that this state is suitable for the development of nanometric ferroelectric devices. Our results cover, for the first time, the gap between the nanodots and wires and between the nanodots and thin films, that is between 0D and 1D as well as between 0D and 2D objects.
publishDate 2012
dc.date.none.fl_str_mv 2012-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/272012
Stachiotti, Marcelo Gabriel; Sepliarsky, Marcelo Claudio; Nanoscale Toroidal Ferroelectricity in PbTiO 3; Taylor & Francis Ltd; Ferroelectrics; 427; 1; 3-2012; 41-51
0015-0193
CONICET Digital
CONICET
url http://hdl.handle.net/11336/272012
identifier_str_mv Stachiotti, Marcelo Gabriel; Sepliarsky, Marcelo Claudio; Nanoscale Toroidal Ferroelectricity in PbTiO 3; Taylor & Francis Ltd; Ferroelectrics; 427; 1; 3-2012; 41-51
0015-0193
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/00150193.2012.673916
info:eu-repo/semantics/altIdentifier/doi/10.1080/00150193.2012.673916
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis Ltd
publisher.none.fl_str_mv Taylor & Francis Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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