From pine sawdust to cellulose nanofibers

Autores
Ehman, Nanci Vanesa; Tarrés, Quim; Delgado Aguilar, Marc; Vallejos, María Evangelina; Felissia, Fernando Esteban; Area, Maria Cristina; Mutjé, Puré
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Biorefinery technology is a current alternative to petroleum based industry to produce energy, chemicals and materials. The use of forest and agricultural lignocellulosic residues as raw materials to generate value-added products has become a topic of great interestdue to their renewability and availability. Pine sawdust is a promising candidate as raw material for biorefinery. This waste, which comes from the primary industrialization of wood, is available in large quantities, at low cost, and is currently open-airburned. The aim of this study was to obtain cellulose nanofiber (CNF) from pine sawdust. Delignification methods were applied to pulp until a kappa number lower than 1was achieved. CNF was produced by the combination of chemical (TEMPO-oxidation) pretreatment and mechanical destructuration in a homogenizer. Once CNF was produced at different oxidation degrees, the degree of polymerization, cationic demand, carboxyl rate, and the yield of fibrillation were determined with the purpose of assessing the effect of the oxidation degree on the final properties thereof.Finally, the suitability of using the obtained CNF as paper strength additive was studied through the assessment of the mechanical properties increase of paper.
Fil: Ehman, Nanci Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Tarrés, Quim. Universidad de Girona; España
Fil: Delgado Aguilar, Marc. Universidad de Girona; España
Fil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Mutjé, Puré. Universidad de Girona; España
Materia
Cellulose Nanofibers
Tempo-Oxidation
Characterization
Papermaking
Cost Production
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44902

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network_name_str CONICET Digital (CONICET)
spelling From pine sawdust to cellulose nanofibersEhman, Nanci VanesaTarrés, QuimDelgado Aguilar, MarcVallejos, María EvangelinaFelissia, Fernando EstebanArea, Maria CristinaMutjé, PuréCellulose NanofibersTempo-OxidationCharacterizationPapermakingCost Productionhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Biorefinery technology is a current alternative to petroleum based industry to produce energy, chemicals and materials. The use of forest and agricultural lignocellulosic residues as raw materials to generate value-added products has become a topic of great interestdue to their renewability and availability. Pine sawdust is a promising candidate as raw material for biorefinery. This waste, which comes from the primary industrialization of wood, is available in large quantities, at low cost, and is currently open-airburned. The aim of this study was to obtain cellulose nanofiber (CNF) from pine sawdust. Delignification methods were applied to pulp until a kappa number lower than 1was achieved. CNF was produced by the combination of chemical (TEMPO-oxidation) pretreatment and mechanical destructuration in a homogenizer. Once CNF was produced at different oxidation degrees, the degree of polymerization, cationic demand, carboxyl rate, and the yield of fibrillation were determined with the purpose of assessing the effect of the oxidation degree on the final properties thereof.Finally, the suitability of using the obtained CNF as paper strength additive was studied through the assessment of the mechanical properties increase of paper.Fil: Ehman, Nanci Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Tarrés, Quim. Universidad de Girona; EspañaFil: Delgado Aguilar, Marc. Universidad de Girona; EspañaFil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Mutjé, Puré. Universidad de Girona; EspañaEditura Acad Romane2016-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44902Ehman, Nanci Vanesa; Tarrés, Quim; Delgado Aguilar, Marc; Vallejos, María Evangelina; Felissia, Fernando Esteban; et al.; From pine sawdust to cellulose nanofibers; Editura Acad Romane; Cellulose Chemistry And Technology; 50; 3; 3-2016; 361-3670576-97872457-9459CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.cellulosechemtechnol.ro/pdf/CCT3-4(2016)/p.361-367.pdfinfo:eu-repo/semantics/altIdentifier/url/http://www.cellulosechemtechnol.ro/onlinearticles.phpinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:59:53Zoai:ri.conicet.gov.ar:11336/44902instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:59:53.668CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv From pine sawdust to cellulose nanofibers
title From pine sawdust to cellulose nanofibers
spellingShingle From pine sawdust to cellulose nanofibers
Ehman, Nanci Vanesa
Cellulose Nanofibers
Tempo-Oxidation
Characterization
Papermaking
Cost Production
title_short From pine sawdust to cellulose nanofibers
title_full From pine sawdust to cellulose nanofibers
title_fullStr From pine sawdust to cellulose nanofibers
title_full_unstemmed From pine sawdust to cellulose nanofibers
title_sort From pine sawdust to cellulose nanofibers
dc.creator.none.fl_str_mv Ehman, Nanci Vanesa
Tarrés, Quim
Delgado Aguilar, Marc
Vallejos, María Evangelina
Felissia, Fernando Esteban
Area, Maria Cristina
Mutjé, Puré
author Ehman, Nanci Vanesa
author_facet Ehman, Nanci Vanesa
Tarrés, Quim
Delgado Aguilar, Marc
Vallejos, María Evangelina
Felissia, Fernando Esteban
Area, Maria Cristina
Mutjé, Puré
author_role author
author2 Tarrés, Quim
Delgado Aguilar, Marc
Vallejos, María Evangelina
Felissia, Fernando Esteban
Area, Maria Cristina
Mutjé, Puré
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Cellulose Nanofibers
Tempo-Oxidation
Characterization
Papermaking
Cost Production
topic Cellulose Nanofibers
Tempo-Oxidation
Characterization
Papermaking
Cost Production
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Biorefinery technology is a current alternative to petroleum based industry to produce energy, chemicals and materials. The use of forest and agricultural lignocellulosic residues as raw materials to generate value-added products has become a topic of great interestdue to their renewability and availability. Pine sawdust is a promising candidate as raw material for biorefinery. This waste, which comes from the primary industrialization of wood, is available in large quantities, at low cost, and is currently open-airburned. The aim of this study was to obtain cellulose nanofiber (CNF) from pine sawdust. Delignification methods were applied to pulp until a kappa number lower than 1was achieved. CNF was produced by the combination of chemical (TEMPO-oxidation) pretreatment and mechanical destructuration in a homogenizer. Once CNF was produced at different oxidation degrees, the degree of polymerization, cationic demand, carboxyl rate, and the yield of fibrillation were determined with the purpose of assessing the effect of the oxidation degree on the final properties thereof.Finally, the suitability of using the obtained CNF as paper strength additive was studied through the assessment of the mechanical properties increase of paper.
Fil: Ehman, Nanci Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Tarrés, Quim. Universidad de Girona; España
Fil: Delgado Aguilar, Marc. Universidad de Girona; España
Fil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Mutjé, Puré. Universidad de Girona; España
description Biorefinery technology is a current alternative to petroleum based industry to produce energy, chemicals and materials. The use of forest and agricultural lignocellulosic residues as raw materials to generate value-added products has become a topic of great interestdue to their renewability and availability. Pine sawdust is a promising candidate as raw material for biorefinery. This waste, which comes from the primary industrialization of wood, is available in large quantities, at low cost, and is currently open-airburned. The aim of this study was to obtain cellulose nanofiber (CNF) from pine sawdust. Delignification methods were applied to pulp until a kappa number lower than 1was achieved. CNF was produced by the combination of chemical (TEMPO-oxidation) pretreatment and mechanical destructuration in a homogenizer. Once CNF was produced at different oxidation degrees, the degree of polymerization, cationic demand, carboxyl rate, and the yield of fibrillation were determined with the purpose of assessing the effect of the oxidation degree on the final properties thereof.Finally, the suitability of using the obtained CNF as paper strength additive was studied through the assessment of the mechanical properties increase of paper.
publishDate 2016
dc.date.none.fl_str_mv 2016-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44902
Ehman, Nanci Vanesa; Tarrés, Quim; Delgado Aguilar, Marc; Vallejos, María Evangelina; Felissia, Fernando Esteban; et al.; From pine sawdust to cellulose nanofibers; Editura Acad Romane; Cellulose Chemistry And Technology; 50; 3; 3-2016; 361-367
0576-9787
2457-9459
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44902
identifier_str_mv Ehman, Nanci Vanesa; Tarrés, Quim; Delgado Aguilar, Marc; Vallejos, María Evangelina; Felissia, Fernando Esteban; et al.; From pine sawdust to cellulose nanofibers; Editura Acad Romane; Cellulose Chemistry And Technology; 50; 3; 3-2016; 361-367
0576-9787
2457-9459
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.cellulosechemtechnol.ro/pdf/CCT3-4(2016)/p.361-367.pdf
info:eu-repo/semantics/altIdentifier/url/http://www.cellulosechemtechnol.ro/onlinearticles.php
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Editura Acad Romane
publisher.none.fl_str_mv Editura Acad Romane
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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