A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures

Autores
Nazari Sam, Mona; Caggiano, Antonio; Mankel, Christoph; Koenders, Eddie
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Thermal-Energy Storage (TES) properties of organic phase change materials have been experimentally investigated and reported in this paper. Three paraffin-based Phase Change Materials (PCMs) and one bio-based PCM are considered with melting temperatures of 24 °C, 25 °C and 26 °C. Sensible heat storage capacities, melting characteristics and latent heat enthalpies of the studied PCMs are investigated through Differential Scanning Calorimetry (DSC) measurements. Two alternative methods, namely the classical dynamic DSC and a stepwise approach, are performed and compared with the aim to eliminate and/or overcome possible measurement errors. In particular, for DSC measurements this could be related to the size of the samples and its representativity, heating rate effects and low thermal conductivity of the PCMs, which may affect the results and possibly cause a loss of objectivity of the measurements. Based on results achieved from this study, clear information can be figured out on how to conduct and characterize paraffin and bio-based PCMs, and how to apply them in TES calculations for building applications and/or simulations. It is observed that both paraffinic and bio-based PCMs possess a comparable TES capacity within the selected phase transition temperature, being representative for the human thermal comfort zone. The phase change of bio-based PCMs occurred over a much narrower temperature range when compared to the wider windows characterizing the paraffin-based materials. Bio-based PCMs turned out to be very suitable for building applications and can be an environmentally friendly substitute for petroleum-based PCMs.
Fil: Nazari Sam, Mona. Universitat Technische Darmstadt; Alemania
Fil: Caggiano, Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina. Universitat Technische Darmstadt; Alemania
Fil: Mankel, Christoph. Universitat Technische Darmstadt; Alemania
Fil: Koenders, Eddie. Universitat Technische Darmstadt; Alemania
Materia
DIFFERENTIAL SCANNING CALORIMETRY
IEA METHOD
LATENT ENTHALPY
MELTING TEMPERATURE
PHASE CHANGE MATERIALS (PCMS)
THERMAL-ENERGY STORAGE (TES)
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/132238
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC ProceduresNazari Sam, MonaCaggiano, AntonioMankel, ChristophKoenders, EddieDIFFERENTIAL SCANNING CALORIMETRYIEA METHODLATENT ENTHALPYMELTING TEMPERATUREPHASE CHANGE MATERIALS (PCMS)THERMAL-ENERGY STORAGE (TES)https://purl.org/becyt/ford/2.1https://purl.org/becyt/ford/2Thermal-Energy Storage (TES) properties of organic phase change materials have been experimentally investigated and reported in this paper. Three paraffin-based Phase Change Materials (PCMs) and one bio-based PCM are considered with melting temperatures of 24 °C, 25 °C and 26 °C. Sensible heat storage capacities, melting characteristics and latent heat enthalpies of the studied PCMs are investigated through Differential Scanning Calorimetry (DSC) measurements. Two alternative methods, namely the classical dynamic DSC and a stepwise approach, are performed and compared with the aim to eliminate and/or overcome possible measurement errors. In particular, for DSC measurements this could be related to the size of the samples and its representativity, heating rate effects and low thermal conductivity of the PCMs, which may affect the results and possibly cause a loss of objectivity of the measurements. Based on results achieved from this study, clear information can be figured out on how to conduct and characterize paraffin and bio-based PCMs, and how to apply them in TES calculations for building applications and/or simulations. It is observed that both paraffinic and bio-based PCMs possess a comparable TES capacity within the selected phase transition temperature, being representative for the human thermal comfort zone. The phase change of bio-based PCMs occurred over a much narrower temperature range when compared to the wider windows characterizing the paraffin-based materials. Bio-based PCMs turned out to be very suitable for building applications and can be an environmentally friendly substitute for petroleum-based PCMs.Fil: Nazari Sam, Mona. Universitat Technische Darmstadt; AlemaniaFil: Caggiano, Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina. Universitat Technische Darmstadt; AlemaniaFil: Mankel, Christoph. Universitat Technische Darmstadt; AlemaniaFil: Koenders, Eddie. Universitat Technische Darmstadt; AlemaniaMDPI2020-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/132238Nazari Sam, Mona; Caggiano, Antonio; Mankel, Christoph; Koenders, Eddie; A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures; MDPI; Materials; 13; 7; 4-2020; 1-221996-1944CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1944/13/7/1705info:eu-repo/semantics/altIdentifier/doi/10.3390/ma13071705info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:25:56Zoai:ri.conicet.gov.ar:11336/132238instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:25:56.647CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures
title A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures
spellingShingle A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures
Nazari Sam, Mona
DIFFERENTIAL SCANNING CALORIMETRY
IEA METHOD
LATENT ENTHALPY
MELTING TEMPERATURE
PHASE CHANGE MATERIALS (PCMS)
THERMAL-ENERGY STORAGE (TES)
title_short A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures
title_full A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures
title_fullStr A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures
title_full_unstemmed A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures
title_sort A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures
dc.creator.none.fl_str_mv Nazari Sam, Mona
Caggiano, Antonio
Mankel, Christoph
Koenders, Eddie
author Nazari Sam, Mona
author_facet Nazari Sam, Mona
Caggiano, Antonio
Mankel, Christoph
Koenders, Eddie
author_role author
author2 Caggiano, Antonio
Mankel, Christoph
Koenders, Eddie
author2_role author
author
author
dc.subject.none.fl_str_mv DIFFERENTIAL SCANNING CALORIMETRY
IEA METHOD
LATENT ENTHALPY
MELTING TEMPERATURE
PHASE CHANGE MATERIALS (PCMS)
THERMAL-ENERGY STORAGE (TES)
topic DIFFERENTIAL SCANNING CALORIMETRY
IEA METHOD
LATENT ENTHALPY
MELTING TEMPERATURE
PHASE CHANGE MATERIALS (PCMS)
THERMAL-ENERGY STORAGE (TES)
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.1
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Thermal-Energy Storage (TES) properties of organic phase change materials have been experimentally investigated and reported in this paper. Three paraffin-based Phase Change Materials (PCMs) and one bio-based PCM are considered with melting temperatures of 24 °C, 25 °C and 26 °C. Sensible heat storage capacities, melting characteristics and latent heat enthalpies of the studied PCMs are investigated through Differential Scanning Calorimetry (DSC) measurements. Two alternative methods, namely the classical dynamic DSC and a stepwise approach, are performed and compared with the aim to eliminate and/or overcome possible measurement errors. In particular, for DSC measurements this could be related to the size of the samples and its representativity, heating rate effects and low thermal conductivity of the PCMs, which may affect the results and possibly cause a loss of objectivity of the measurements. Based on results achieved from this study, clear information can be figured out on how to conduct and characterize paraffin and bio-based PCMs, and how to apply them in TES calculations for building applications and/or simulations. It is observed that both paraffinic and bio-based PCMs possess a comparable TES capacity within the selected phase transition temperature, being representative for the human thermal comfort zone. The phase change of bio-based PCMs occurred over a much narrower temperature range when compared to the wider windows characterizing the paraffin-based materials. Bio-based PCMs turned out to be very suitable for building applications and can be an environmentally friendly substitute for petroleum-based PCMs.
Fil: Nazari Sam, Mona. Universitat Technische Darmstadt; Alemania
Fil: Caggiano, Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina. Universitat Technische Darmstadt; Alemania
Fil: Mankel, Christoph. Universitat Technische Darmstadt; Alemania
Fil: Koenders, Eddie. Universitat Technische Darmstadt; Alemania
description Thermal-Energy Storage (TES) properties of organic phase change materials have been experimentally investigated and reported in this paper. Three paraffin-based Phase Change Materials (PCMs) and one bio-based PCM are considered with melting temperatures of 24 °C, 25 °C and 26 °C. Sensible heat storage capacities, melting characteristics and latent heat enthalpies of the studied PCMs are investigated through Differential Scanning Calorimetry (DSC) measurements. Two alternative methods, namely the classical dynamic DSC and a stepwise approach, are performed and compared with the aim to eliminate and/or overcome possible measurement errors. In particular, for DSC measurements this could be related to the size of the samples and its representativity, heating rate effects and low thermal conductivity of the PCMs, which may affect the results and possibly cause a loss of objectivity of the measurements. Based on results achieved from this study, clear information can be figured out on how to conduct and characterize paraffin and bio-based PCMs, and how to apply them in TES calculations for building applications and/or simulations. It is observed that both paraffinic and bio-based PCMs possess a comparable TES capacity within the selected phase transition temperature, being representative for the human thermal comfort zone. The phase change of bio-based PCMs occurred over a much narrower temperature range when compared to the wider windows characterizing the paraffin-based materials. Bio-based PCMs turned out to be very suitable for building applications and can be an environmentally friendly substitute for petroleum-based PCMs.
publishDate 2020
dc.date.none.fl_str_mv 2020-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/132238
Nazari Sam, Mona; Caggiano, Antonio; Mankel, Christoph; Koenders, Eddie; A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures; MDPI; Materials; 13; 7; 4-2020; 1-22
1996-1944
CONICET Digital
CONICET
url http://hdl.handle.net/11336/132238
identifier_str_mv Nazari Sam, Mona; Caggiano, Antonio; Mankel, Christoph; Koenders, Eddie; A Comparative Study on the Thermal Energy Storage Performance of Bio-Based and Paraffin-Based PCMs Using DSC Procedures; MDPI; Materials; 13; 7; 4-2020; 1-22
1996-1944
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1944/13/7/1705
info:eu-repo/semantics/altIdentifier/doi/10.3390/ma13071705
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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