Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry

Autores
Bengoa, Leandro Nicolás; Ispas, Adriana; Bengoa, Jose Fernando; Bund, A.; Egli, Walter Alfredo
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Electrodeposition of Cu-SiO2 composite coatings from an alkaline non-cyanide electrolyte containing glutamate as complexing agent was studied. Silica mesoporous particles were synthesized using a modified Stöber methodology, and later their surface chemistry was changed by functionalizing them with 3-aminopropyltriethoxysilane. Particles microstructure and morphology were characterized (SEM, TEM, XRD) and their charging behavior in several electrolytes was studied through ζ-potential measurements. Galvanostatic deposition was performed in electrolytes containing both as-prepared and functionalized SiO2 at various current densities, and the influence of ultrasonic irradiation (37 Hz) was evaluated. For some experiments, 1.5 g L− of Polyquaternium 7 were added to the solution. SEM and XRD were used to characterized coatings morphology and microstructure, whereas EDS was used to estimate SiO2 wt%. The results showed that the effect of ultrasound on the codeposition process depends on current density and particle surface chemistry. All the trends observed in this study could be explained taking into account ζ-potential values recorded and previously reported theories. Adjusting the experimental conditions, it was possible to obtain deposits with SiO2 contents of ≈5 wt%. Finally, it was found that both ultrasonic irradiation and Polyquaternium 7 affect the morphology and crystal orientation of the deposits.
Fil: Bengoa, Leandro Nicolás. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Ispas, Adriana. Technische Universität Ilmenau; Alemania
Fil: Bengoa, Jose Fernando. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Bund, A.. Technische Universität Ilmenau; Alemania
Fil: Egli, Walter Alfredo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Materia
ELECTRODEPOSITION
COPPER
COMPOSITES
ULTRASOUND
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/121248
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/121248
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistryBengoa, Leandro NicolásIspas, AdrianaBengoa, Jose FernandoBund, A.Egli, Walter AlfredoELECTRODEPOSITIONCOPPERCOMPOSITESULTRASOUNDhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Electrodeposition of Cu-SiO2 composite coatings from an alkaline non-cyanide electrolyte containing glutamate as complexing agent was studied. Silica mesoporous particles were synthesized using a modified Stöber methodology, and later their surface chemistry was changed by functionalizing them with 3-aminopropyltriethoxysilane. Particles microstructure and morphology were characterized (SEM, TEM, XRD) and their charging behavior in several electrolytes was studied through ζ-potential measurements. Galvanostatic deposition was performed in electrolytes containing both as-prepared and functionalized SiO2 at various current densities, and the influence of ultrasonic irradiation (37 Hz) was evaluated. For some experiments, 1.5 g L− of Polyquaternium 7 were added to the solution. SEM and XRD were used to characterized coatings morphology and microstructure, whereas EDS was used to estimate SiO2 wt%. The results showed that the effect of ultrasound on the codeposition process depends on current density and particle surface chemistry. All the trends observed in this study could be explained taking into account ζ-potential values recorded and previously reported theories. Adjusting the experimental conditions, it was possible to obtain deposits with SiO2 contents of ≈5 wt%. Finally, it was found that both ultrasonic irradiation and Polyquaternium 7 affect the morphology and crystal orientation of the deposits.Fil: Bengoa, Leandro Nicolás. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Ispas, Adriana. Technische Universität Ilmenau; AlemaniaFil: Bengoa, Jose Fernando. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Bund, A.. Technische Universität Ilmenau; AlemaniaFil: Egli, Walter Alfredo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaElectrochemical Society2019-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/121248Bengoa, Leandro Nicolás; Ispas, Adriana; Bengoa, Jose Fernando; Bund, A.; Egli, Walter Alfredo; Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry; Electrochemical Society; Journal of the Electrochemical Society; 166; 8; 4-2019; 244-2510013-4651CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1149/2.0181908jesinfo:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1149/2.0181908jesinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:07:32Zoai:ri.conicet.gov.ar:11336/121248instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:07:33.213CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry
title Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry
spellingShingle Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry
Bengoa, Leandro Nicolás
ELECTRODEPOSITION
COPPER
COMPOSITES
ULTRASOUND
title_short Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry
title_full Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry
title_fullStr Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry
title_full_unstemmed Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry
title_sort Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry
dc.creator.none.fl_str_mv Bengoa, Leandro Nicolás
Ispas, Adriana
Bengoa, Jose Fernando
Bund, A.
Egli, Walter Alfredo
author Bengoa, Leandro Nicolás
author_facet Bengoa, Leandro Nicolás
Ispas, Adriana
Bengoa, Jose Fernando
Bund, A.
Egli, Walter Alfredo
author_role author
author2 Ispas, Adriana
Bengoa, Jose Fernando
Bund, A.
Egli, Walter Alfredo
author2_role author
author
author
author
dc.subject.none.fl_str_mv ELECTRODEPOSITION
COPPER
COMPOSITES
ULTRASOUND
topic ELECTRODEPOSITION
COPPER
COMPOSITES
ULTRASOUND
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Electrodeposition of Cu-SiO2 composite coatings from an alkaline non-cyanide electrolyte containing glutamate as complexing agent was studied. Silica mesoporous particles were synthesized using a modified Stöber methodology, and later their surface chemistry was changed by functionalizing them with 3-aminopropyltriethoxysilane. Particles microstructure and morphology were characterized (SEM, TEM, XRD) and their charging behavior in several electrolytes was studied through ζ-potential measurements. Galvanostatic deposition was performed in electrolytes containing both as-prepared and functionalized SiO2 at various current densities, and the influence of ultrasonic irradiation (37 Hz) was evaluated. For some experiments, 1.5 g L− of Polyquaternium 7 were added to the solution. SEM and XRD were used to characterized coatings morphology and microstructure, whereas EDS was used to estimate SiO2 wt%. The results showed that the effect of ultrasound on the codeposition process depends on current density and particle surface chemistry. All the trends observed in this study could be explained taking into account ζ-potential values recorded and previously reported theories. Adjusting the experimental conditions, it was possible to obtain deposits with SiO2 contents of ≈5 wt%. Finally, it was found that both ultrasonic irradiation and Polyquaternium 7 affect the morphology and crystal orientation of the deposits.
Fil: Bengoa, Leandro Nicolás. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Ispas, Adriana. Technische Universität Ilmenau; Alemania
Fil: Bengoa, Jose Fernando. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
Fil: Bund, A.. Technische Universität Ilmenau; Alemania
Fil: Egli, Walter Alfredo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentina
description Electrodeposition of Cu-SiO2 composite coatings from an alkaline non-cyanide electrolyte containing glutamate as complexing agent was studied. Silica mesoporous particles were synthesized using a modified Stöber methodology, and later their surface chemistry was changed by functionalizing them with 3-aminopropyltriethoxysilane. Particles microstructure and morphology were characterized (SEM, TEM, XRD) and their charging behavior in several electrolytes was studied through ζ-potential measurements. Galvanostatic deposition was performed in electrolytes containing both as-prepared and functionalized SiO2 at various current densities, and the influence of ultrasonic irradiation (37 Hz) was evaluated. For some experiments, 1.5 g L− of Polyquaternium 7 were added to the solution. SEM and XRD were used to characterized coatings morphology and microstructure, whereas EDS was used to estimate SiO2 wt%. The results showed that the effect of ultrasound on the codeposition process depends on current density and particle surface chemistry. All the trends observed in this study could be explained taking into account ζ-potential values recorded and previously reported theories. Adjusting the experimental conditions, it was possible to obtain deposits with SiO2 contents of ≈5 wt%. Finally, it was found that both ultrasonic irradiation and Polyquaternium 7 affect the morphology and crystal orientation of the deposits.
publishDate 2019
dc.date.none.fl_str_mv 2019-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/121248
Bengoa, Leandro Nicolás; Ispas, Adriana; Bengoa, Jose Fernando; Bund, A.; Egli, Walter Alfredo; Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry; Electrochemical Society; Journal of the Electrochemical Society; 166; 8; 4-2019; 244-251
0013-4651
CONICET Digital
CONICET
url http://hdl.handle.net/11336/121248
identifier_str_mv Bengoa, Leandro Nicolás; Ispas, Adriana; Bengoa, Jose Fernando; Bund, A.; Egli, Walter Alfredo; Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry; Electrochemical Society; Journal of the Electrochemical Society; 166; 8; 4-2019; 244-251
0013-4651
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1149/2.0181908jes
info:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1149/2.0181908jes
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Electrochemical Society
publisher.none.fl_str_mv Electrochemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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