Rational design of covalently bridged [FeIII 2M IIO] clusters
- Autores
- Alborés, Pablo; Rentschler, Eva
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- We are reporting the first supramolecular dimeric units of basic carboxylates. The neutral [FeIII 2MIIO] motif for different 3d M metals is covalently bound through 2,2′-bipyrimidine. We have structurally characterized the hexanuclear clusters and the related trinuclear building blocks. Their magnetic properties have been fully analyzed and DFT calculations have been performed as a supplementary tool. All results evidence a weak antiferromagnetic interaction through the bpym bridge between isolated spin ground states (in some examples) arising from intra-Fe 2MO core exchange couplings.
Fil: Alborés, Pablo. Johannes Gutenberg Universitat Mainz; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Rentschler, Eva. Johannes Gutenberg Universitat Mainz; Alemania - Materia
-
Basic Carboxylate
Bipyrimidine
Magnetic Properties
Covalently Link - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/71352
Ver los metadatos del registro completo
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Rational design of covalently bridged [FeIII 2M IIO] clustersAlborés, PabloRentschler, EvaBasic CarboxylateBipyrimidineMagnetic PropertiesCovalently Linkhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We are reporting the first supramolecular dimeric units of basic carboxylates. The neutral [FeIII 2MIIO] motif for different 3d M metals is covalently bound through 2,2′-bipyrimidine. We have structurally characterized the hexanuclear clusters and the related trinuclear building blocks. Their magnetic properties have been fully analyzed and DFT calculations have been performed as a supplementary tool. All results evidence a weak antiferromagnetic interaction through the bpym bridge between isolated spin ground states (in some examples) arising from intra-Fe 2MO core exchange couplings.Fil: Alborés, Pablo. Johannes Gutenberg Universitat Mainz; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Rentschler, Eva. Johannes Gutenberg Universitat Mainz; AlemaniaRoyal Society of Chemistry2010-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/71352Alborés, Pablo; Rentschler, Eva; Rational design of covalently bridged [FeIII 2M IIO] clusters; Royal Society of Chemistry; Dalton Transactions; 39; 20; 3-2010; 5005-50191477-9226CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/b925214binfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2010/DT/b925214binfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:07:20Zoai:ri.conicet.gov.ar:11336/71352instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:07:20.504CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Rational design of covalently bridged [FeIII 2M IIO] clusters |
| title |
Rational design of covalently bridged [FeIII 2M IIO] clusters |
| spellingShingle |
Rational design of covalently bridged [FeIII 2M IIO] clusters Alborés, Pablo Basic Carboxylate Bipyrimidine Magnetic Properties Covalently Link |
| title_short |
Rational design of covalently bridged [FeIII 2M IIO] clusters |
| title_full |
Rational design of covalently bridged [FeIII 2M IIO] clusters |
| title_fullStr |
Rational design of covalently bridged [FeIII 2M IIO] clusters |
| title_full_unstemmed |
Rational design of covalently bridged [FeIII 2M IIO] clusters |
| title_sort |
Rational design of covalently bridged [FeIII 2M IIO] clusters |
| dc.creator.none.fl_str_mv |
Alborés, Pablo Rentschler, Eva |
| author |
Alborés, Pablo |
| author_facet |
Alborés, Pablo Rentschler, Eva |
| author_role |
author |
| author2 |
Rentschler, Eva |
| author2_role |
author |
| dc.subject.none.fl_str_mv |
Basic Carboxylate Bipyrimidine Magnetic Properties Covalently Link |
| topic |
Basic Carboxylate Bipyrimidine Magnetic Properties Covalently Link |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| dc.description.none.fl_txt_mv |
We are reporting the first supramolecular dimeric units of basic carboxylates. The neutral [FeIII 2MIIO] motif for different 3d M metals is covalently bound through 2,2′-bipyrimidine. We have structurally characterized the hexanuclear clusters and the related trinuclear building blocks. Their magnetic properties have been fully analyzed and DFT calculations have been performed as a supplementary tool. All results evidence a weak antiferromagnetic interaction through the bpym bridge between isolated spin ground states (in some examples) arising from intra-Fe 2MO core exchange couplings. Fil: Alborés, Pablo. Johannes Gutenberg Universitat Mainz; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina Fil: Rentschler, Eva. Johannes Gutenberg Universitat Mainz; Alemania |
| description |
We are reporting the first supramolecular dimeric units of basic carboxylates. The neutral [FeIII 2MIIO] motif for different 3d M metals is covalently bound through 2,2′-bipyrimidine. We have structurally characterized the hexanuclear clusters and the related trinuclear building blocks. Their magnetic properties have been fully analyzed and DFT calculations have been performed as a supplementary tool. All results evidence a weak antiferromagnetic interaction through the bpym bridge between isolated spin ground states (in some examples) arising from intra-Fe 2MO core exchange couplings. |
| publishDate |
2010 |
| dc.date.none.fl_str_mv |
2010-03 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://hdl.handle.net/11336/71352 Alborés, Pablo; Rentschler, Eva; Rational design of covalently bridged [FeIII 2M IIO] clusters; Royal Society of Chemistry; Dalton Transactions; 39; 20; 3-2010; 5005-5019 1477-9226 CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/71352 |
| identifier_str_mv |
Alborés, Pablo; Rentschler, Eva; Rational design of covalently bridged [FeIII 2M IIO] clusters; Royal Society of Chemistry; Dalton Transactions; 39; 20; 3-2010; 5005-5019 1477-9226 CONICET Digital CONICET |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
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info:eu-repo/semantics/altIdentifier/doi/10.1039/b925214b info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2010/DT/b925214b |
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openAccess |
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application/pdf application/pdf |
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Royal Society of Chemistry |
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Royal Society of Chemistry |
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