Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes

Autores
Zubair, Usman; Jori, Khalil; Thomas, Jorge Enrique; Amici, Julia; Francia, Carlotta; Bodoardo, Silvia
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Various metal oxides are investigated to catalyse lithium polysulfides (LiPS) conversion to promote the surface-bound insoluble intermediates and limit the LiPS shuttle. Herein, an effective methodology is reported to enhance LiPS catalytic conversion by applying electrodeposited hybrid phase composite films of manganese oxide (MnOx) on carbonized cotton cloth. Synergistic effects of porous carbon fabric with remnant lumen and high interfacial MnOx composite film of nanoflakes greatly contribute towards freestanding high-loaded sulfur cathodes. Various MnOx phases are realized by controlled annealing of MnOOH electrodeposited nanoflakes on carbon cloth. Oxygen deficient phases especially active interfaces among various phases are proposed to accelerate the LiPS oxidation to polythionate complexes that can interact with LiPS to assist their onsite conversion into sulfides. Pristine and LiPS interacted deposited films are investigated by X-ray photoelectron spectra and X-ray absorption spectra. The cathodes bearing high oxygen-deficient manganese oxide nanoflakes achieve high initial discharge capacity of 1153.7 mA h g−1 at 0.1 C and high reversible capacity of 824 mA h g−1 at 0.5 C over 200 cycles at sulfur areal loading of 5 mg cm−2, while initial discharge capacity of 1085.9 mA h g−1 and reversible capacity of 410 mA h g−1 are obtained for MnO2 rich heterostructure film.
Fil: Zubair, Usman. Politecnico di Torino; Italia
Fil: Jori, Khalil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Thomas, Jorge Enrique. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Amici, Julia. Politecnico di Torino; Italia
Fil: Francia, Carlotta. Politecnico di Torino; Italia
Fil: Bodoardo, Silvia. Politecnico di Torino; Italia
Materia
LI-S BATTERY
MANGANESE OXIDE
OXYGEN VACANCIES
POLYSULFIDES REDOX
SURFACE ENGINEERING
SURFACE-BOUND INSOLUBLE INTERMEDIATES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/230119
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/230119
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodesZubair, UsmanJori, KhalilThomas, Jorge EnriqueAmici, JuliaFrancia, CarlottaBodoardo, SilviaLI-S BATTERYMANGANESE OXIDEOXYGEN VACANCIESPOLYSULFIDES REDOXSURFACE ENGINEERINGSURFACE-BOUND INSOLUBLE INTERMEDIATEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Various metal oxides are investigated to catalyse lithium polysulfides (LiPS) conversion to promote the surface-bound insoluble intermediates and limit the LiPS shuttle. Herein, an effective methodology is reported to enhance LiPS catalytic conversion by applying electrodeposited hybrid phase composite films of manganese oxide (MnOx) on carbonized cotton cloth. Synergistic effects of porous carbon fabric with remnant lumen and high interfacial MnOx composite film of nanoflakes greatly contribute towards freestanding high-loaded sulfur cathodes. Various MnOx phases are realized by controlled annealing of MnOOH electrodeposited nanoflakes on carbon cloth. Oxygen deficient phases especially active interfaces among various phases are proposed to accelerate the LiPS oxidation to polythionate complexes that can interact with LiPS to assist their onsite conversion into sulfides. Pristine and LiPS interacted deposited films are investigated by X-ray photoelectron spectra and X-ray absorption spectra. The cathodes bearing high oxygen-deficient manganese oxide nanoflakes achieve high initial discharge capacity of 1153.7 mA h g−1 at 0.1 C and high reversible capacity of 824 mA h g−1 at 0.5 C over 200 cycles at sulfur areal loading of 5 mg cm−2, while initial discharge capacity of 1085.9 mA h g−1 and reversible capacity of 410 mA h g−1 are obtained for MnO2 rich heterostructure film.Fil: Zubair, Usman. Politecnico di Torino; ItaliaFil: Jori, Khalil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Thomas, Jorge Enrique. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Amici, Julia. Politecnico di Torino; ItaliaFil: Francia, Carlotta. Politecnico di Torino; ItaliaFil: Bodoardo, Silvia. Politecnico di Torino; ItaliaElsevier Science2023-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/230119Zubair, Usman; Jori, Khalil; Thomas, Jorge Enrique; Amici, Julia; Francia, Carlotta; et al.; Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes; Elsevier Science; Journal of Power Sources; 580; 10-2023; 1-130378-7753CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jpowsour.2023.233457info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:15:40Zoai:ri.conicet.gov.ar:11336/230119instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:15:40.387CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes
title Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes
spellingShingle Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes
Zubair, Usman
LI-S BATTERY
MANGANESE OXIDE
OXYGEN VACANCIES
POLYSULFIDES REDOX
SURFACE ENGINEERING
SURFACE-BOUND INSOLUBLE INTERMEDIATES
title_short Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes
title_full Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes
title_fullStr Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes
title_full_unstemmed Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes
title_sort Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes
dc.creator.none.fl_str_mv Zubair, Usman
Jori, Khalil
Thomas, Jorge Enrique
Amici, Julia
Francia, Carlotta
Bodoardo, Silvia
author Zubair, Usman
author_facet Zubair, Usman
Jori, Khalil
Thomas, Jorge Enrique
Amici, Julia
Francia, Carlotta
Bodoardo, Silvia
author_role author
author2 Jori, Khalil
Thomas, Jorge Enrique
Amici, Julia
Francia, Carlotta
Bodoardo, Silvia
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv LI-S BATTERY
MANGANESE OXIDE
OXYGEN VACANCIES
POLYSULFIDES REDOX
SURFACE ENGINEERING
SURFACE-BOUND INSOLUBLE INTERMEDIATES
topic LI-S BATTERY
MANGANESE OXIDE
OXYGEN VACANCIES
POLYSULFIDES REDOX
SURFACE ENGINEERING
SURFACE-BOUND INSOLUBLE INTERMEDIATES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Various metal oxides are investigated to catalyse lithium polysulfides (LiPS) conversion to promote the surface-bound insoluble intermediates and limit the LiPS shuttle. Herein, an effective methodology is reported to enhance LiPS catalytic conversion by applying electrodeposited hybrid phase composite films of manganese oxide (MnOx) on carbonized cotton cloth. Synergistic effects of porous carbon fabric with remnant lumen and high interfacial MnOx composite film of nanoflakes greatly contribute towards freestanding high-loaded sulfur cathodes. Various MnOx phases are realized by controlled annealing of MnOOH electrodeposited nanoflakes on carbon cloth. Oxygen deficient phases especially active interfaces among various phases are proposed to accelerate the LiPS oxidation to polythionate complexes that can interact with LiPS to assist their onsite conversion into sulfides. Pristine and LiPS interacted deposited films are investigated by X-ray photoelectron spectra and X-ray absorption spectra. The cathodes bearing high oxygen-deficient manganese oxide nanoflakes achieve high initial discharge capacity of 1153.7 mA h g−1 at 0.1 C and high reversible capacity of 824 mA h g−1 at 0.5 C over 200 cycles at sulfur areal loading of 5 mg cm−2, while initial discharge capacity of 1085.9 mA h g−1 and reversible capacity of 410 mA h g−1 are obtained for MnO2 rich heterostructure film.
Fil: Zubair, Usman. Politecnico di Torino; Italia
Fil: Jori, Khalil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Thomas, Jorge Enrique. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Amici, Julia. Politecnico di Torino; Italia
Fil: Francia, Carlotta. Politecnico di Torino; Italia
Fil: Bodoardo, Silvia. Politecnico di Torino; Italia
description Various metal oxides are investigated to catalyse lithium polysulfides (LiPS) conversion to promote the surface-bound insoluble intermediates and limit the LiPS shuttle. Herein, an effective methodology is reported to enhance LiPS catalytic conversion by applying electrodeposited hybrid phase composite films of manganese oxide (MnOx) on carbonized cotton cloth. Synergistic effects of porous carbon fabric with remnant lumen and high interfacial MnOx composite film of nanoflakes greatly contribute towards freestanding high-loaded sulfur cathodes. Various MnOx phases are realized by controlled annealing of MnOOH electrodeposited nanoflakes on carbon cloth. Oxygen deficient phases especially active interfaces among various phases are proposed to accelerate the LiPS oxidation to polythionate complexes that can interact with LiPS to assist their onsite conversion into sulfides. Pristine and LiPS interacted deposited films are investigated by X-ray photoelectron spectra and X-ray absorption spectra. The cathodes bearing high oxygen-deficient manganese oxide nanoflakes achieve high initial discharge capacity of 1153.7 mA h g−1 at 0.1 C and high reversible capacity of 824 mA h g−1 at 0.5 C over 200 cycles at sulfur areal loading of 5 mg cm−2, while initial discharge capacity of 1085.9 mA h g−1 and reversible capacity of 410 mA h g−1 are obtained for MnO2 rich heterostructure film.
publishDate 2023
dc.date.none.fl_str_mv 2023-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/230119
Zubair, Usman; Jori, Khalil; Thomas, Jorge Enrique; Amici, Julia; Francia, Carlotta; et al.; Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes; Elsevier Science; Journal of Power Sources; 580; 10-2023; 1-13
0378-7753
CONICET Digital
CONICET
url http://hdl.handle.net/11336/230119
identifier_str_mv Zubair, Usman; Jori, Khalil; Thomas, Jorge Enrique; Amici, Julia; Francia, Carlotta; et al.; Electrodeposited heterostructured manganese oxides on carbonized clothes for enhanced lithium polysulfides conversion as free-standing sulfur cathodes; Elsevier Science; Journal of Power Sources; 580; 10-2023; 1-13
0378-7753
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jpowsour.2023.233457
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846782571796496384
score 12.982451

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