Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study

Autores
Musso, Telma Belén; Carlos, Luciano; Parolo, Maria Eugenia; Francisca, Franco Matias; Pettinari, Gisela Roxana; Giuliano, Valeria Noemí; Ruffato, Marianerla
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Clay materials used as low-permeability barriers at landfill sites can also chemically attenuate inorganic contaminants (heavy metals) in leachate. In this study, Cu(II) removal capacity from aqueous media of a raw calcareous mudstone, used as a liner material, was evaluated through both batch and column tests. Batch experiments were conducted varying contact time, pH, and Cu(II) concentration. In order to simulate waste leachates composition, the effect of the presence of some organic compounds on Cu(II) uptake was also evaluated. Column tests of compacted calcareous mudstone-sand mixtures were performed to evaluate sorption in dynamic systems. The studied calcareous mudstone exhibited higher removal capacity in a wider pH range than a commercial Na-bentonite, which is a widely used heavy metal sorbent and clay liner. It was evidenced that calcite, an important component of the calcareous mudstone and found as very small and highly porous calcareous nannofossils, contributed to its sorption properties playing a significant role in the Cu(II) removal. The presence of an anionic surfactant or phenol slightly affected the removal of Cu(II). In the clay fraction (< 2 µm), Cu(II) sorption was favored by the presence of humic acids, which add new adsorption sites for this metal. The extremely high retardation factor obtained for the raw calcareous mudstone is in good agreement with the high adsorption capacity experimentally proved in batch tests and demonstrated a great ability of this material to retain heavy metal mass during the transport in solution within porous media.
Fil: Musso, Telma Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Carlos, Luciano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Parolo, Maria Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Centro de Investigaciones en Toxicología Ambiental y Agrobiotecnología del Comahue. Universidad Nacional del Comahue. Facultad de Ciencias Agrarias. Centro de Investigaciones en Toxicología Ambiental y Agrobiotecnología del Comahue; Argentina
Fil: Francisca, Franco Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Estudios Avanzados en Ingeniería y Tecnología. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto de Estudios Avanzados en Ingeniería y Tecnología; Argentina
Fil: Pettinari, Gisela Roxana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Giuliano, Valeria Noemí. Universidad Nacional del Comahue. Facultad de Ingeniería; Argentina
Fil: Ruffato, Marianerla. Universidad Nacional del Comahue. Facultad de Ingeniería; Argentina
Materia
ADSORPTION
CALCITE
CLAY LINERS
HEAVY METAL
LEACHATE
PRECIPITATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/210569
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/210569
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption StudyMusso, Telma BelénCarlos, LucianoParolo, Maria EugeniaFrancisca, Franco MatiasPettinari, Gisela RoxanaGiuliano, Valeria NoemíRuffato, MarianerlaADSORPTIONCALCITECLAY LINERSHEAVY METALLEACHATEPRECIPITATIONhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Clay materials used as low-permeability barriers at landfill sites can also chemically attenuate inorganic contaminants (heavy metals) in leachate. In this study, Cu(II) removal capacity from aqueous media of a raw calcareous mudstone, used as a liner material, was evaluated through both batch and column tests. Batch experiments were conducted varying contact time, pH, and Cu(II) concentration. In order to simulate waste leachates composition, the effect of the presence of some organic compounds on Cu(II) uptake was also evaluated. Column tests of compacted calcareous mudstone-sand mixtures were performed to evaluate sorption in dynamic systems. The studied calcareous mudstone exhibited higher removal capacity in a wider pH range than a commercial Na-bentonite, which is a widely used heavy metal sorbent and clay liner. It was evidenced that calcite, an important component of the calcareous mudstone and found as very small and highly porous calcareous nannofossils, contributed to its sorption properties playing a significant role in the Cu(II) removal. The presence of an anionic surfactant or phenol slightly affected the removal of Cu(II). In the clay fraction (< 2 µm), Cu(II) sorption was favored by the presence of humic acids, which add new adsorption sites for this metal. The extremely high retardation factor obtained for the raw calcareous mudstone is in good agreement with the high adsorption capacity experimentally proved in batch tests and demonstrated a great ability of this material to retain heavy metal mass during the transport in solution within porous media.Fil: Musso, Telma Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Carlos, Luciano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Parolo, Maria Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Centro de Investigaciones en Toxicología Ambiental y Agrobiotecnología del Comahue. Universidad Nacional del Comahue. Facultad de Ciencias Agrarias. Centro de Investigaciones en Toxicología Ambiental y Agrobiotecnología del Comahue; ArgentinaFil: Francisca, Franco Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Estudios Avanzados en Ingeniería y Tecnología. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto de Estudios Avanzados en Ingeniería y Tecnología; ArgentinaFil: Pettinari, Gisela Roxana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Giuliano, Valeria Noemí. Universidad Nacional del Comahue. Facultad de Ingeniería; ArgentinaFil: Ruffato, Marianerla. Universidad Nacional del Comahue. Facultad de Ingeniería; ArgentinaSpringer2022-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/210569Musso, Telma Belén; Carlos, Luciano; Parolo, Maria Eugenia; Francisca, Franco Matias; Pettinari, Gisela Roxana; et al.; Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study; Springer; Water, Air and Soil Pollution; 233; 4; 4-2022; 1-160049-6979CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://link.springer.com/10.1007/s11270-022-05610-zinfo:eu-repo/semantics/altIdentifier/doi/10.1007/s11270-022-05610-zinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:52:08Zoai:ri.conicet.gov.ar:11336/210569instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:52:08.548CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study
title Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study
spellingShingle Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study
Musso, Telma Belén
ADSORPTION
CALCITE
CLAY LINERS
HEAVY METAL
LEACHATE
PRECIPITATION
title_short Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study
title_full Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study
title_fullStr Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study
title_full_unstemmed Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study
title_sort Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study
dc.creator.none.fl_str_mv Musso, Telma Belén
Carlos, Luciano
Parolo, Maria Eugenia
Francisca, Franco Matias
Pettinari, Gisela Roxana
Giuliano, Valeria Noemí
Ruffato, Marianerla
author Musso, Telma Belén
author_facet Musso, Telma Belén
Carlos, Luciano
Parolo, Maria Eugenia
Francisca, Franco Matias
Pettinari, Gisela Roxana
Giuliano, Valeria Noemí
Ruffato, Marianerla
author_role author
author2 Carlos, Luciano
Parolo, Maria Eugenia
Francisca, Franco Matias
Pettinari, Gisela Roxana
Giuliano, Valeria Noemí
Ruffato, Marianerla
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv ADSORPTION
CALCITE
CLAY LINERS
HEAVY METAL
LEACHATE
PRECIPITATION
topic ADSORPTION
CALCITE
CLAY LINERS
HEAVY METAL
LEACHATE
PRECIPITATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Clay materials used as low-permeability barriers at landfill sites can also chemically attenuate inorganic contaminants (heavy metals) in leachate. In this study, Cu(II) removal capacity from aqueous media of a raw calcareous mudstone, used as a liner material, was evaluated through both batch and column tests. Batch experiments were conducted varying contact time, pH, and Cu(II) concentration. In order to simulate waste leachates composition, the effect of the presence of some organic compounds on Cu(II) uptake was also evaluated. Column tests of compacted calcareous mudstone-sand mixtures were performed to evaluate sorption in dynamic systems. The studied calcareous mudstone exhibited higher removal capacity in a wider pH range than a commercial Na-bentonite, which is a widely used heavy metal sorbent and clay liner. It was evidenced that calcite, an important component of the calcareous mudstone and found as very small and highly porous calcareous nannofossils, contributed to its sorption properties playing a significant role in the Cu(II) removal. The presence of an anionic surfactant or phenol slightly affected the removal of Cu(II). In the clay fraction (< 2 µm), Cu(II) sorption was favored by the presence of humic acids, which add new adsorption sites for this metal. The extremely high retardation factor obtained for the raw calcareous mudstone is in good agreement with the high adsorption capacity experimentally proved in batch tests and demonstrated a great ability of this material to retain heavy metal mass during the transport in solution within porous media.
Fil: Musso, Telma Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Carlos, Luciano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Parolo, Maria Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Centro de Investigaciones en Toxicología Ambiental y Agrobiotecnología del Comahue. Universidad Nacional del Comahue. Facultad de Ciencias Agrarias. Centro de Investigaciones en Toxicología Ambiental y Agrobiotecnología del Comahue; Argentina
Fil: Francisca, Franco Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Estudios Avanzados en Ingeniería y Tecnología. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Instituto de Estudios Avanzados en Ingeniería y Tecnología; Argentina
Fil: Pettinari, Gisela Roxana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina
Fil: Giuliano, Valeria Noemí. Universidad Nacional del Comahue. Facultad de Ingeniería; Argentina
Fil: Ruffato, Marianerla. Universidad Nacional del Comahue. Facultad de Ingeniería; Argentina
description Clay materials used as low-permeability barriers at landfill sites can also chemically attenuate inorganic contaminants (heavy metals) in leachate. In this study, Cu(II) removal capacity from aqueous media of a raw calcareous mudstone, used as a liner material, was evaluated through both batch and column tests. Batch experiments were conducted varying contact time, pH, and Cu(II) concentration. In order to simulate waste leachates composition, the effect of the presence of some organic compounds on Cu(II) uptake was also evaluated. Column tests of compacted calcareous mudstone-sand mixtures were performed to evaluate sorption in dynamic systems. The studied calcareous mudstone exhibited higher removal capacity in a wider pH range than a commercial Na-bentonite, which is a widely used heavy metal sorbent and clay liner. It was evidenced that calcite, an important component of the calcareous mudstone and found as very small and highly porous calcareous nannofossils, contributed to its sorption properties playing a significant role in the Cu(II) removal. The presence of an anionic surfactant or phenol slightly affected the removal of Cu(II). In the clay fraction (< 2 µm), Cu(II) sorption was favored by the presence of humic acids, which add new adsorption sites for this metal. The extremely high retardation factor obtained for the raw calcareous mudstone is in good agreement with the high adsorption capacity experimentally proved in batch tests and demonstrated a great ability of this material to retain heavy metal mass during the transport in solution within porous media.
publishDate 2022
dc.date.none.fl_str_mv 2022-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/210569
Musso, Telma Belén; Carlos, Luciano; Parolo, Maria Eugenia; Francisca, Franco Matias; Pettinari, Gisela Roxana; et al.; Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study; Springer; Water, Air and Soil Pollution; 233; 4; 4-2022; 1-16
0049-6979
CONICET Digital
CONICET
url http://hdl.handle.net/11336/210569
identifier_str_mv Musso, Telma Belén; Carlos, Luciano; Parolo, Maria Eugenia; Francisca, Franco Matias; Pettinari, Gisela Roxana; et al.; Mudstones as Landfill Liner Material for Heavy Metal Removal: Equilibrium and Dynamic Sorption Study; Springer; Water, Air and Soil Pollution; 233; 4; 4-2022; 1-16
0049-6979
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/10.1007/s11270-022-05610-z
info:eu-repo/semantics/altIdentifier/doi/10.1007/s11270-022-05610-z
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
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eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
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dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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