Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites

Autores
Wang, Changlong; Ciganda, Roberto; Yate, Luis; Tuninetti, Jimena Soledad; Shalabaeva, Victoria; Salmon, Lionel; Moya, Sergio; Ruiz, Jaime; Astruc, Didier
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Although nanocatalysis is a promising area, increased efficiency and greenness are actively sought. Here we report the principle of the syntheses of graphene oxide (GO)-supported metal nanocatalysts (MNPs) for a variety of transition metals including both noble metals and biometal using either exergonic or endergonic redox reactions between GO and the transition metal salts. These new nanocatalysts are highly efficient in water at ambient temperature for 4-nitrophenol reduction (the test reaction), Sonogashira coupling, azide-alkyne 1,3-cycloaddition (click reaction) and dihydrogen production upon hydrolysis of ammonia-borane and recyclable.
Fil: Wang, Changlong. Centre National de la Recherche Scientifique; Francia. Universite de Bordeaux; Francia
Fil: Ciganda, Roberto. Centre National de la Recherche Scientifique; Francia. Universite de Bordeaux; Francia
Fil: Yate, Luis. CIC biomaGUNE; España
Fil: Tuninetti, Jimena Soledad. CIC biomaGUNE; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Shalabaeva, Victoria. Centre National de la Recherche Scientifique; Francia
Fil: Salmon, Lionel. Centre National de la Recherche Scientifique; Francia
Fil: Moya, Sergio. CIC biomaGUNE; España
Fil: Ruiz, Jaime. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Astruc, Didier. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; Francia
Materia
Transition Metal Nanoparticles
Graphene Oxide
Catalysis
Nanocomposites
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/63905
Acceder
id CONICETDig_1f9a98e89e283f87111b37bd9901439f
oai_identifier_str oai:ri.conicet.gov.ar:11336/63905
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocompositesWang, ChanglongCiganda, RobertoYate, LuisTuninetti, Jimena SoledadShalabaeva, VictoriaSalmon, LionelMoya, SergioRuiz, JaimeAstruc, DidierTransition Metal NanoparticlesGraphene OxideCatalysisNanocompositeshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Although nanocatalysis is a promising area, increased efficiency and greenness are actively sought. Here we report the principle of the syntheses of graphene oxide (GO)-supported metal nanocatalysts (MNPs) for a variety of transition metals including both noble metals and biometal using either exergonic or endergonic redox reactions between GO and the transition metal salts. These new nanocatalysts are highly efficient in water at ambient temperature for 4-nitrophenol reduction (the test reaction), Sonogashira coupling, azide-alkyne 1,3-cycloaddition (click reaction) and dihydrogen production upon hydrolysis of ammonia-borane and recyclable.Fil: Wang, Changlong. Centre National de la Recherche Scientifique; Francia. Universite de Bordeaux; FranciaFil: Ciganda, Roberto. Centre National de la Recherche Scientifique; Francia. Universite de Bordeaux; FranciaFil: Yate, Luis. CIC biomaGUNE; EspañaFil: Tuninetti, Jimena Soledad. CIC biomaGUNE; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Shalabaeva, Victoria. Centre National de la Recherche Scientifique; FranciaFil: Salmon, Lionel. Centre National de la Recherche Scientifique; FranciaFil: Moya, Sergio. CIC biomaGUNE; EspañaFil: Ruiz, Jaime. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; FranciaFil: Astruc, Didier. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; FranciaRoyal Society of Chemistry2017-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/63905Wang, Changlong; Ciganda, Roberto; Yate, Luis; Tuninetti, Jimena Soledad; Shalabaeva, Victoria; et al.; Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites; Royal Society of Chemistry; Journal of Materials Chemistry A; 5; 41; 10-2017; 21947-219542050-7496CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c7ta06182jinfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/TA/C7TA06182Jinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:56:59Zoai:ri.conicet.gov.ar:11336/63905instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:56:59.688CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites
title Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites
spellingShingle Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites
Wang, Changlong
Transition Metal Nanoparticles
Graphene Oxide
Catalysis
Nanocomposites
title_short Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites
title_full Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites
title_fullStr Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites
title_full_unstemmed Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites
title_sort Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites
dc.creator.none.fl_str_mv Wang, Changlong
Ciganda, Roberto
Yate, Luis
Tuninetti, Jimena Soledad
Shalabaeva, Victoria
Salmon, Lionel
Moya, Sergio
Ruiz, Jaime
Astruc, Didier
author Wang, Changlong
author_facet Wang, Changlong
Ciganda, Roberto
Yate, Luis
Tuninetti, Jimena Soledad
Shalabaeva, Victoria
Salmon, Lionel
Moya, Sergio
Ruiz, Jaime
Astruc, Didier
author_role author
author2 Ciganda, Roberto
Yate, Luis
Tuninetti, Jimena Soledad
Shalabaeva, Victoria
Salmon, Lionel
Moya, Sergio
Ruiz, Jaime
Astruc, Didier
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Transition Metal Nanoparticles
Graphene Oxide
Catalysis
Nanocomposites
topic Transition Metal Nanoparticles
Graphene Oxide
Catalysis
Nanocomposites
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Although nanocatalysis is a promising area, increased efficiency and greenness are actively sought. Here we report the principle of the syntheses of graphene oxide (GO)-supported metal nanocatalysts (MNPs) for a variety of transition metals including both noble metals and biometal using either exergonic or endergonic redox reactions between GO and the transition metal salts. These new nanocatalysts are highly efficient in water at ambient temperature for 4-nitrophenol reduction (the test reaction), Sonogashira coupling, azide-alkyne 1,3-cycloaddition (click reaction) and dihydrogen production upon hydrolysis of ammonia-borane and recyclable.
Fil: Wang, Changlong. Centre National de la Recherche Scientifique; Francia. Universite de Bordeaux; Francia
Fil: Ciganda, Roberto. Centre National de la Recherche Scientifique; Francia. Universite de Bordeaux; Francia
Fil: Yate, Luis. CIC biomaGUNE; España
Fil: Tuninetti, Jimena Soledad. CIC biomaGUNE; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Shalabaeva, Victoria. Centre National de la Recherche Scientifique; Francia
Fil: Salmon, Lionel. Centre National de la Recherche Scientifique; Francia
Fil: Moya, Sergio. CIC biomaGUNE; España
Fil: Ruiz, Jaime. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; Francia
Fil: Astruc, Didier. Universite de Bordeaux; Francia. Centre National de la Recherche Scientifique; Francia
description Although nanocatalysis is a promising area, increased efficiency and greenness are actively sought. Here we report the principle of the syntheses of graphene oxide (GO)-supported metal nanocatalysts (MNPs) for a variety of transition metals including both noble metals and biometal using either exergonic or endergonic redox reactions between GO and the transition metal salts. These new nanocatalysts are highly efficient in water at ambient temperature for 4-nitrophenol reduction (the test reaction), Sonogashira coupling, azide-alkyne 1,3-cycloaddition (click reaction) and dihydrogen production upon hydrolysis of ammonia-borane and recyclable.
publishDate 2017
dc.date.none.fl_str_mv 2017-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/63905
Wang, Changlong; Ciganda, Roberto; Yate, Luis; Tuninetti, Jimena Soledad; Shalabaeva, Victoria; et al.; Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites; Royal Society of Chemistry; Journal of Materials Chemistry A; 5; 41; 10-2017; 21947-21954
2050-7496
CONICET Digital
CONICET
url http://hdl.handle.net/11336/63905
identifier_str_mv Wang, Changlong; Ciganda, Roberto; Yate, Luis; Tuninetti, Jimena Soledad; Shalabaeva, Victoria; et al.; Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites; Royal Society of Chemistry; Journal of Materials Chemistry A; 5; 41; 10-2017; 21947-21954
2050-7496
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/c7ta06182j
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/TA/C7TA06182J
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269432866406400
score 13.13397

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