Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant

Autores
Lépori, Cristian Marcelo Oscar; Silber, Juana J.; Falcone, Ruben Dario; Correa, Nestor Mariano
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In the present work we have synthesized, via acid-base reaction between bis-(2-ethylhexyl)phosphoric acid (HDEHP) and 1-methylimidazole, a new protic ionic liquid: 1-methylimidazolium bis-(2-ethylhexyl) phosphate (imim-DEHP) with amphiphilic character. The ability of imim-DEHP to create RMs in different nonpolar solvents (n-heptane, benzene and toluene) and spontaneously unilamellar vesicles in water was evaluated by different techniques such as dynamic (DLS) and static (SLS) light scattering and transmission electron microscopy (TEM). The results obtained were compared with the properties of sodium bis-(2-ethylhexyl) phosphate (Na-DEHP) in order to elucidate how the surfactant chemical structure affects the organized media generated. Our results show that imim-DEHP forms RMs in aromatic and aliphatic nonpolar solvents and allows the dissolution of a considerable amount of water in both systems. Additionally, imim-DEHP has the capacity to create spontaneously unilamellar vesicles. Interestingly, imim-DEHP shows better characteristics as a surfactant than Na-DEHP. In this sense, we consider that the present work introduces imim-DEHP as a very promising surfactant for future applications as nanoreactors and in nanotechnology.
Fil: Lépori, Cristian Marcelo Oscar. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Silber, Juana J.. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Falcone, Ruben Dario. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Correa, Nestor Mariano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Protic Ionic Liquids
Surfactant
Reverse Micelles
Vesicles
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/74951
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/74951
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactantLépori, Cristian Marcelo OscarSilber, Juana J.Falcone, Ruben DarioCorrea, Nestor MarianoProtic Ionic LiquidsSurfactantReverse MicellesVesicleshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In the present work we have synthesized, via acid-base reaction between bis-(2-ethylhexyl)phosphoric acid (HDEHP) and 1-methylimidazole, a new protic ionic liquid: 1-methylimidazolium bis-(2-ethylhexyl) phosphate (imim-DEHP) with amphiphilic character. The ability of imim-DEHP to create RMs in different nonpolar solvents (n-heptane, benzene and toluene) and spontaneously unilamellar vesicles in water was evaluated by different techniques such as dynamic (DLS) and static (SLS) light scattering and transmission electron microscopy (TEM). The results obtained were compared with the properties of sodium bis-(2-ethylhexyl) phosphate (Na-DEHP) in order to elucidate how the surfactant chemical structure affects the organized media generated. Our results show that imim-DEHP forms RMs in aromatic and aliphatic nonpolar solvents and allows the dissolution of a considerable amount of water in both systems. Additionally, imim-DEHP has the capacity to create spontaneously unilamellar vesicles. Interestingly, imim-DEHP shows better characteristics as a surfactant than Na-DEHP. In this sense, we consider that the present work introduces imim-DEHP as a very promising surfactant for future applications as nanoreactors and in nanotechnology.Fil: Lépori, Cristian Marcelo Oscar. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Silber, Juana J.. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Falcone, Ruben Dario. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Correa, Nestor Mariano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaRoyal Society of Chemistry2017-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/74951Lépori, Cristian Marcelo Oscar; Silber, Juana J.; Falcone, Ruben Dario; Correa, Nestor Mariano; Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant; Royal Society of Chemistry; RSC Advances; 7; 71; 9-2017; 44743-447502046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c7ra08907dinfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/RA/C7RA08907Dinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:42Zoai:ri.conicet.gov.ar:11336/74951instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:42.329CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant
title Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant
spellingShingle Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant
Lépori, Cristian Marcelo Oscar
Protic Ionic Liquids
Surfactant
Reverse Micelles
Vesicles
title_short Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant
title_full Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant
title_fullStr Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant
title_full_unstemmed Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant
title_sort Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant
dc.creator.none.fl_str_mv Lépori, Cristian Marcelo Oscar
Silber, Juana J.
Falcone, Ruben Dario
Correa, Nestor Mariano
author Lépori, Cristian Marcelo Oscar
author_facet Lépori, Cristian Marcelo Oscar
Silber, Juana J.
Falcone, Ruben Dario
Correa, Nestor Mariano
author_role author
author2 Silber, Juana J.
Falcone, Ruben Dario
Correa, Nestor Mariano
author2_role author
author
author
dc.subject.none.fl_str_mv Protic Ionic Liquids
Surfactant
Reverse Micelles
Vesicles
topic Protic Ionic Liquids
Surfactant
Reverse Micelles
Vesicles
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In the present work we have synthesized, via acid-base reaction between bis-(2-ethylhexyl)phosphoric acid (HDEHP) and 1-methylimidazole, a new protic ionic liquid: 1-methylimidazolium bis-(2-ethylhexyl) phosphate (imim-DEHP) with amphiphilic character. The ability of imim-DEHP to create RMs in different nonpolar solvents (n-heptane, benzene and toluene) and spontaneously unilamellar vesicles in water was evaluated by different techniques such as dynamic (DLS) and static (SLS) light scattering and transmission electron microscopy (TEM). The results obtained were compared with the properties of sodium bis-(2-ethylhexyl) phosphate (Na-DEHP) in order to elucidate how the surfactant chemical structure affects the organized media generated. Our results show that imim-DEHP forms RMs in aromatic and aliphatic nonpolar solvents and allows the dissolution of a considerable amount of water in both systems. Additionally, imim-DEHP has the capacity to create spontaneously unilamellar vesicles. Interestingly, imim-DEHP shows better characteristics as a surfactant than Na-DEHP. In this sense, we consider that the present work introduces imim-DEHP as a very promising surfactant for future applications as nanoreactors and in nanotechnology.
Fil: Lépori, Cristian Marcelo Oscar. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Silber, Juana J.. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Falcone, Ruben Dario. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Correa, Nestor Mariano. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description In the present work we have synthesized, via acid-base reaction between bis-(2-ethylhexyl)phosphoric acid (HDEHP) and 1-methylimidazole, a new protic ionic liquid: 1-methylimidazolium bis-(2-ethylhexyl) phosphate (imim-DEHP) with amphiphilic character. The ability of imim-DEHP to create RMs in different nonpolar solvents (n-heptane, benzene and toluene) and spontaneously unilamellar vesicles in water was evaluated by different techniques such as dynamic (DLS) and static (SLS) light scattering and transmission electron microscopy (TEM). The results obtained were compared with the properties of sodium bis-(2-ethylhexyl) phosphate (Na-DEHP) in order to elucidate how the surfactant chemical structure affects the organized media generated. Our results show that imim-DEHP forms RMs in aromatic and aliphatic nonpolar solvents and allows the dissolution of a considerable amount of water in both systems. Additionally, imim-DEHP has the capacity to create spontaneously unilamellar vesicles. Interestingly, imim-DEHP shows better characteristics as a surfactant than Na-DEHP. In this sense, we consider that the present work introduces imim-DEHP as a very promising surfactant for future applications as nanoreactors and in nanotechnology.
publishDate 2017
dc.date.none.fl_str_mv 2017-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/74951
Lépori, Cristian Marcelo Oscar; Silber, Juana J.; Falcone, Ruben Dario; Correa, Nestor Mariano; Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant; Royal Society of Chemistry; RSC Advances; 7; 71; 9-2017; 44743-44750
2046-2069
CONICET Digital
CONICET
url http://hdl.handle.net/11336/74951
identifier_str_mv Lépori, Cristian Marcelo Oscar; Silber, Juana J.; Falcone, Ruben Dario; Correa, Nestor Mariano; Improvement of the amphiphilic properties of a dialkyl phosphate by creation of a protic ionic liquid-like surfactant; Royal Society of Chemistry; RSC Advances; 7; 71; 9-2017; 44743-44750
2046-2069
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/c7ra08907d
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/RA/C7RA08907D
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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