High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ
- Autores
- Prado, Fernando Daniel; Abate, Anabella Angela; Caneiro, Alberto; Cuello, Gabriel Julio
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Co1.5Fe1.5O10 - δ has been studied in the temperature range 20 ≤ T ≤ 900 °C by in situ Neutron Powder Diffraction (NPD), and thermogravimetric and linear expansion measurements. The presence of oxygen vacancies at the O(2) and O(4) crystal sites, in the central perovskite layer, along with the variation of the bottleneck space available for oxygen migration with temperature at T > 300 °C indicates the O(4)-O(4) jumps predominate during oxide ion diffusion. Absolute oxygen content measurements support oxygen excess (> 10.0) at temperatures below 300 °C, which is unusual for the n = 3 R-P phases. The total expansion in the temperature range 25 ≤ T ≤ 900 °C, α = αV3 = 26.5 (1) × 10- 6 K- 1, is twice the values reported for the electrolytes. The linear expansion along the c-axis, αc = 34.15 (1) × 10- 6 K- 1, is mainly absorbed by the perovskite block while the width of the rock salt layers remains nearly constant. Additionally, the oxygen chemical expansivity (βC) value determined for this layered compound, βC = 0.670, was found to be approximately three times larger than those reported for the three dimensional perovskite system La1 - xSrxCoO3 - δ.
Fil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; Argentina
Fil: Abate, Anabella Angela. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cuello, Gabriel Julio. Institut Laue Langevin; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina - Materia
-
Lasr3co1.5fe1.5o10 - Δ
Mixed Conductors
Neutron Powder Diffraction
Ruddlesden-Popper Phases
Sofc Cathodes - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/39540
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High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δPrado, Fernando DanielAbate, Anabella AngelaCaneiro, AlbertoCuello, Gabriel JulioLasr3co1.5fe1.5o10 - ΔMixed ConductorsNeutron Powder DiffractionRuddlesden-Popper PhasesSofc Cathodeshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Co1.5Fe1.5O10 - δ has been studied in the temperature range 20 ≤ T ≤ 900 °C by in situ Neutron Powder Diffraction (NPD), and thermogravimetric and linear expansion measurements. The presence of oxygen vacancies at the O(2) and O(4) crystal sites, in the central perovskite layer, along with the variation of the bottleneck space available for oxygen migration with temperature at T > 300 °C indicates the O(4)-O(4) jumps predominate during oxide ion diffusion. Absolute oxygen content measurements support oxygen excess (> 10.0) at temperatures below 300 °C, which is unusual for the n = 3 R-P phases. The total expansion in the temperature range 25 ≤ T ≤ 900 °C, α = αV3 = 26.5 (1) × 10- 6 K- 1, is twice the values reported for the electrolytes. The linear expansion along the c-axis, αc = 34.15 (1) × 10- 6 K- 1, is mainly absorbed by the perovskite block while the width of the rock salt layers remains nearly constant. Additionally, the oxygen chemical expansivity (βC) value determined for this layered compound, βC = 0.670, was found to be approximately three times larger than those reported for the three dimensional perovskite system La1 - xSrxCoO3 - δ.Fil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; ArgentinaFil: Abate, Anabella Angela. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cuello, Gabriel Julio. Institut Laue Langevin; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier Science2015-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/39540Prado, Fernando Daniel; Abate, Anabella Angela; Caneiro, Alberto; Cuello, Gabriel Julio; High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ; Elsevier Science; Solid State Ionics; 270; 1-2-2015; 54-600167-2738CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ssi.2014.12.007info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0167273814005153info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:06:32Zoai:ri.conicet.gov.ar:11336/39540instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:06:32.315CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ |
title |
High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ |
spellingShingle |
High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ Prado, Fernando Daniel Lasr3co1.5fe1.5o10 - Δ Mixed Conductors Neutron Powder Diffraction Ruddlesden-Popper Phases Sofc Cathodes |
title_short |
High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ |
title_full |
High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ |
title_fullStr |
High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ |
title_full_unstemmed |
High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ |
title_sort |
High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ |
dc.creator.none.fl_str_mv |
Prado, Fernando Daniel Abate, Anabella Angela Caneiro, Alberto Cuello, Gabriel Julio |
author |
Prado, Fernando Daniel |
author_facet |
Prado, Fernando Daniel Abate, Anabella Angela Caneiro, Alberto Cuello, Gabriel Julio |
author_role |
author |
author2 |
Abate, Anabella Angela Caneiro, Alberto Cuello, Gabriel Julio |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Lasr3co1.5fe1.5o10 - Δ Mixed Conductors Neutron Powder Diffraction Ruddlesden-Popper Phases Sofc Cathodes |
topic |
Lasr3co1.5fe1.5o10 - Δ Mixed Conductors Neutron Powder Diffraction Ruddlesden-Popper Phases Sofc Cathodes |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Co1.5Fe1.5O10 - δ has been studied in the temperature range 20 ≤ T ≤ 900 °C by in situ Neutron Powder Diffraction (NPD), and thermogravimetric and linear expansion measurements. The presence of oxygen vacancies at the O(2) and O(4) crystal sites, in the central perovskite layer, along with the variation of the bottleneck space available for oxygen migration with temperature at T > 300 °C indicates the O(4)-O(4) jumps predominate during oxide ion diffusion. Absolute oxygen content measurements support oxygen excess (> 10.0) at temperatures below 300 °C, which is unusual for the n = 3 R-P phases. The total expansion in the temperature range 25 ≤ T ≤ 900 °C, α = αV3 = 26.5 (1) × 10- 6 K- 1, is twice the values reported for the electrolytes. The linear expansion along the c-axis, αc = 34.15 (1) × 10- 6 K- 1, is mainly absorbed by the perovskite block while the width of the rock salt layers remains nearly constant. Additionally, the oxygen chemical expansivity (βC) value determined for this layered compound, βC = 0.670, was found to be approximately three times larger than those reported for the three dimensional perovskite system La1 - xSrxCoO3 - δ. Fil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; Argentina Fil: Abate, Anabella Angela. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Cuello, Gabriel Julio. Institut Laue Langevin; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina |
description |
The crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Co1.5Fe1.5O10 - δ has been studied in the temperature range 20 ≤ T ≤ 900 °C by in situ Neutron Powder Diffraction (NPD), and thermogravimetric and linear expansion measurements. The presence of oxygen vacancies at the O(2) and O(4) crystal sites, in the central perovskite layer, along with the variation of the bottleneck space available for oxygen migration with temperature at T > 300 °C indicates the O(4)-O(4) jumps predominate during oxide ion diffusion. Absolute oxygen content measurements support oxygen excess (> 10.0) at temperatures below 300 °C, which is unusual for the n = 3 R-P phases. The total expansion in the temperature range 25 ≤ T ≤ 900 °C, α = αV3 = 26.5 (1) × 10- 6 K- 1, is twice the values reported for the electrolytes. The linear expansion along the c-axis, αc = 34.15 (1) × 10- 6 K- 1, is mainly absorbed by the perovskite block while the width of the rock salt layers remains nearly constant. Additionally, the oxygen chemical expansivity (βC) value determined for this layered compound, βC = 0.670, was found to be approximately three times larger than those reported for the three dimensional perovskite system La1 - xSrxCoO3 - δ. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-02-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/39540 Prado, Fernando Daniel; Abate, Anabella Angela; Caneiro, Alberto; Cuello, Gabriel Julio; High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ; Elsevier Science; Solid State Ionics; 270; 1-2-2015; 54-60 0167-2738 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/39540 |
identifier_str_mv |
Prado, Fernando Daniel; Abate, Anabella Angela; Caneiro, Alberto; Cuello, Gabriel Julio; High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ; Elsevier Science; Solid State Ionics; 270; 1-2-2015; 54-60 0167-2738 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ssi.2014.12.007 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0167273814005153 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613914916028416 |
score |
13.070432 |