High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ

Autores
Prado, Fernando Daniel; Abate, Anabella Angela; Caneiro, Alberto; Cuello, Gabriel Julio
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Co1.5Fe1.5O10 - δ has been studied in the temperature range 20 ≤ T ≤ 900 °C by in situ Neutron Powder Diffraction (NPD), and thermogravimetric and linear expansion measurements. The presence of oxygen vacancies at the O(2) and O(4) crystal sites, in the central perovskite layer, along with the variation of the bottleneck space available for oxygen migration with temperature at T > 300 °C indicates the O(4)-O(4) jumps predominate during oxide ion diffusion. Absolute oxygen content measurements support oxygen excess (> 10.0) at temperatures below 300 °C, which is unusual for the n = 3 R-P phases. The total expansion in the temperature range 25 ≤ T ≤ 900 °C, α = αV3 = 26.5 (1) × 10- 6 K- 1, is twice the values reported for the electrolytes. The linear expansion along the c-axis, αc = 34.15 (1) × 10- 6 K- 1, is mainly absorbed by the perovskite block while the width of the rock salt layers remains nearly constant. Additionally, the oxygen chemical expansivity (βC) value determined for this layered compound, βC = 0.670, was found to be approximately three times larger than those reported for the three dimensional perovskite system La1 - xSrxCoO3 - δ.
Fil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; Argentina
Fil: Abate, Anabella Angela. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cuello, Gabriel Julio. Institut Laue Langevin; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Lasr3co1.5fe1.5o10 - Δ
Mixed Conductors
Neutron Powder Diffraction
Ruddlesden-Popper Phases
Sofc Cathodes
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/39540
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/39540
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δPrado, Fernando DanielAbate, Anabella AngelaCaneiro, AlbertoCuello, Gabriel JulioLasr3co1.5fe1.5o10 - ΔMixed ConductorsNeutron Powder DiffractionRuddlesden-Popper PhasesSofc Cathodeshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Co1.5Fe1.5O10 - δ has been studied in the temperature range 20 ≤ T ≤ 900 °C by in situ Neutron Powder Diffraction (NPD), and thermogravimetric and linear expansion measurements. The presence of oxygen vacancies at the O(2) and O(4) crystal sites, in the central perovskite layer, along with the variation of the bottleneck space available for oxygen migration with temperature at T > 300 °C indicates the O(4)-O(4) jumps predominate during oxide ion diffusion. Absolute oxygen content measurements support oxygen excess (> 10.0) at temperatures below 300 °C, which is unusual for the n = 3 R-P phases. The total expansion in the temperature range 25 ≤ T ≤ 900 °C, α = αV3 = 26.5 (1) × 10- 6 K- 1, is twice the values reported for the electrolytes. The linear expansion along the c-axis, αc = 34.15 (1) × 10- 6 K- 1, is mainly absorbed by the perovskite block while the width of the rock salt layers remains nearly constant. Additionally, the oxygen chemical expansivity (βC) value determined for this layered compound, βC = 0.670, was found to be approximately three times larger than those reported for the three dimensional perovskite system La1 - xSrxCoO3 - δ.Fil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; ArgentinaFil: Abate, Anabella Angela. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cuello, Gabriel Julio. Institut Laue Langevin; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier Science2015-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/39540Prado, Fernando Daniel; Abate, Anabella Angela; Caneiro, Alberto; Cuello, Gabriel Julio; High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ; Elsevier Science; Solid State Ionics; 270; 1-2-2015; 54-600167-2738CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ssi.2014.12.007info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0167273814005153info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:36:23Zoai:ri.conicet.gov.ar:11336/39540instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:36:23.687CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ
title High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ
spellingShingle High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ
Prado, Fernando Daniel
Lasr3co1.5fe1.5o10 - Δ
Mixed Conductors
Neutron Powder Diffraction
Ruddlesden-Popper Phases
Sofc Cathodes
title_short High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ
title_full High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ
title_fullStr High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ
title_full_unstemmed High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ
title_sort High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ
dc.creator.none.fl_str_mv Prado, Fernando Daniel
Abate, Anabella Angela
Caneiro, Alberto
Cuello, Gabriel Julio
author Prado, Fernando Daniel
author_facet Prado, Fernando Daniel
Abate, Anabella Angela
Caneiro, Alberto
Cuello, Gabriel Julio
author_role author
author2 Abate, Anabella Angela
Caneiro, Alberto
Cuello, Gabriel Julio
author2_role author
author
author
dc.subject.none.fl_str_mv Lasr3co1.5fe1.5o10 - Δ
Mixed Conductors
Neutron Powder Diffraction
Ruddlesden-Popper Phases
Sofc Cathodes
topic Lasr3co1.5fe1.5o10 - Δ
Mixed Conductors
Neutron Powder Diffraction
Ruddlesden-Popper Phases
Sofc Cathodes
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Co1.5Fe1.5O10 - δ has been studied in the temperature range 20 ≤ T ≤ 900 °C by in situ Neutron Powder Diffraction (NPD), and thermogravimetric and linear expansion measurements. The presence of oxygen vacancies at the O(2) and O(4) crystal sites, in the central perovskite layer, along with the variation of the bottleneck space available for oxygen migration with temperature at T > 300 °C indicates the O(4)-O(4) jumps predominate during oxide ion diffusion. Absolute oxygen content measurements support oxygen excess (> 10.0) at temperatures below 300 °C, which is unusual for the n = 3 R-P phases. The total expansion in the temperature range 25 ≤ T ≤ 900 °C, α = αV3 = 26.5 (1) × 10- 6 K- 1, is twice the values reported for the electrolytes. The linear expansion along the c-axis, αc = 34.15 (1) × 10- 6 K- 1, is mainly absorbed by the perovskite block while the width of the rock salt layers remains nearly constant. Additionally, the oxygen chemical expansivity (βC) value determined for this layered compound, βC = 0.670, was found to be approximately three times larger than those reported for the three dimensional perovskite system La1 - xSrxCoO3 - δ.
Fil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Sur; Argentina
Fil: Abate, Anabella Angela. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cuello, Gabriel Julio. Institut Laue Langevin; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description The crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Co1.5Fe1.5O10 - δ has been studied in the temperature range 20 ≤ T ≤ 900 °C by in situ Neutron Powder Diffraction (NPD), and thermogravimetric and linear expansion measurements. The presence of oxygen vacancies at the O(2) and O(4) crystal sites, in the central perovskite layer, along with the variation of the bottleneck space available for oxygen migration with temperature at T > 300 °C indicates the O(4)-O(4) jumps predominate during oxide ion diffusion. Absolute oxygen content measurements support oxygen excess (> 10.0) at temperatures below 300 °C, which is unusual for the n = 3 R-P phases. The total expansion in the temperature range 25 ≤ T ≤ 900 °C, α = αV3 = 26.5 (1) × 10- 6 K- 1, is twice the values reported for the electrolytes. The linear expansion along the c-axis, αc = 34.15 (1) × 10- 6 K- 1, is mainly absorbed by the perovskite block while the width of the rock salt layers remains nearly constant. Additionally, the oxygen chemical expansivity (βC) value determined for this layered compound, βC = 0.670, was found to be approximately three times larger than those reported for the three dimensional perovskite system La1 - xSrxCoO3 - δ.
publishDate 2015
dc.date.none.fl_str_mv 2015-02-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/39540
Prado, Fernando Daniel; Abate, Anabella Angela; Caneiro, Alberto; Cuello, Gabriel Julio; High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ; Elsevier Science; Solid State Ionics; 270; 1-2-2015; 54-60
0167-2738
CONICET Digital
CONICET
url http://hdl.handle.net/11336/39540
identifier_str_mv Prado, Fernando Daniel; Abate, Anabella Angela; Caneiro, Alberto; Cuello, Gabriel Julio; High temperature crystal chemistry of the n = 3 Ruddlesden-Popper phase LaSr3Fe1.5Co1.5O10 - δ; Elsevier Science; Solid State Ionics; 270; 1-2-2015; 54-60
0167-2738
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ssi.2014.12.007
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0167273814005153
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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