The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine)

Autores
Harvey, Miguel Angel; Suarez, Sebastian; Cukiernik, Fabio Daniel; Baggio, Ricardo Fortunato
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Controlled heating of single crystals of the previously reported [Köferstein & Robl (2007). Z. Anorg. Allg. Chem. 633, 1127-1130] dihydrate {[Co(pht)(bpy)(H2O)2]·2H2O}n, (II) [where pht is phthalate (C8H4O4) and bpy is 4,4'-bi­pyridine (C10H8N2)], produced a topotactic transformation into an un­reported di­aqua anhydrate, namely poly[di­aqua([mu]2-benzene-1,2-di­carboxyl­ato-[kappa]2O1:O2)­([mu]2-4,4'-bi­pyridine-[kappa]2N:N')cobalt(II)], [Co(C8H4O4)(C10H8N2)(H2O)2]n, (IIa). The structural change consists of the loss of the two solvent water mol­ecules linking the original two-dimensional covalent substructures which are the `main frame' of the monoclinic P2/n hydrate (strictly preserved during the transformation), with further reaccommodation of the latter. The anhydrate organizes itself in the ortho­rhom­bic system (space group Pmn21) in a disordered fashion, where the space-group-symmetry restrictions are achieved only in a statistical sense, with mirror-related two-dimensional planar substructures, mirrored in a plane perpendicular to [100]. Thus, the asymmetric unit in the refined model is composed of two superimposed mirror-related `ghosts' of half-occupancy each. Similarities and differences with the parent dihydrate and some other related structures in the literature are discussed.
Fil: Harvey, Miguel Angel. Universidad Nacional de la Patagonia Austral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Centro Nacional Patagónico; Argentina
Fil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Cukiernik, Fabio Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Materia
Crystal Structure
Topotactic Dehydration
Disorder
Average "Mirror" Plane
Robust Two-Dimensional Substructure
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31740
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31740
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine)Harvey, Miguel AngelSuarez, SebastianCukiernik, Fabio DanielBaggio, Ricardo FortunatoCrystal StructureTopotactic DehydrationDisorderAverage "Mirror" PlaneRobust Two-Dimensional Substructurehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Controlled heating of single crystals of the previously reported [Köferstein & Robl (2007). Z. Anorg. Allg. Chem. 633, 1127-1130] dihydrate {[Co(pht)(bpy)(H2O)2]·2H2O}n, (II) [where pht is phthalate (C8H4O4) and bpy is 4,4'-bi­pyridine (C10H8N2)], produced a topotactic transformation into an un­reported di­aqua anhydrate, namely poly[di­aqua([mu]2-benzene-1,2-di­carboxyl­ato-[kappa]2O1:O2)­([mu]2-4,4'-bi­pyridine-[kappa]2N:N')cobalt(II)], [Co(C8H4O4)(C10H8N2)(H2O)2]n, (IIa). The structural change consists of the loss of the two solvent water mol­ecules linking the original two-dimensional covalent substructures which are the `main frame' of the monoclinic P2/n hydrate (strictly preserved during the transformation), with further reaccommodation of the latter. The anhydrate organizes itself in the ortho­rhom­bic system (space group Pmn21) in a disordered fashion, where the space-group-symmetry restrictions are achieved only in a statistical sense, with mirror-related two-dimensional planar substructures, mirrored in a plane perpendicular to [100]. Thus, the asymmetric unit in the refined model is composed of two superimposed mirror-related `ghosts' of half-occupancy each. Similarities and differences with the parent dihydrate and some other related structures in the literature are discussed.Fil: Harvey, Miguel Angel. Universidad Nacional de la Patagonia Austral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Centro Nacional Patagónico; ArgentinaFil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Cukiernik, Fabio Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaInternational Union of Crystallography2014-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31740Baggio, Ricardo Fortunato; Suarez, Sebastian; Harvey, Miguel Angel; Cukiernik, Fabio Daniel; The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine); International Union of Crystallography; Acta Crystallographica Section C-Crystal Structure Communications; C70; 7-2014; 978-9820108-2701CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1107/S2053229614020427info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2053229614020427info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:01:31Zoai:ri.conicet.gov.ar:11336/31740instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:01:31.383CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine)
title The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine)
spellingShingle The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine)
Harvey, Miguel Angel
Crystal Structure
Topotactic Dehydration
Disorder
Average "Mirror" Plane
Robust Two-Dimensional Substructure
title_short The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine)
title_full The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine)
title_fullStr The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine)
title_full_unstemmed The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine)
title_sort The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine)
dc.creator.none.fl_str_mv Harvey, Miguel Angel
Suarez, Sebastian
Cukiernik, Fabio Daniel
Baggio, Ricardo Fortunato
author Harvey, Miguel Angel
author_facet Harvey, Miguel Angel
Suarez, Sebastian
Cukiernik, Fabio Daniel
Baggio, Ricardo Fortunato
author_role author
author2 Suarez, Sebastian
Cukiernik, Fabio Daniel
Baggio, Ricardo Fortunato
author2_role author
author
author
dc.subject.none.fl_str_mv Crystal Structure
Topotactic Dehydration
Disorder
Average "Mirror" Plane
Robust Two-Dimensional Substructure
topic Crystal Structure
Topotactic Dehydration
Disorder
Average "Mirror" Plane
Robust Two-Dimensional Substructure
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Controlled heating of single crystals of the previously reported [Köferstein & Robl (2007). Z. Anorg. Allg. Chem. 633, 1127-1130] dihydrate {[Co(pht)(bpy)(H2O)2]·2H2O}n, (II) [where pht is phthalate (C8H4O4) and bpy is 4,4'-bi­pyridine (C10H8N2)], produced a topotactic transformation into an un­reported di­aqua anhydrate, namely poly[di­aqua([mu]2-benzene-1,2-di­carboxyl­ato-[kappa]2O1:O2)­([mu]2-4,4'-bi­pyridine-[kappa]2N:N')cobalt(II)], [Co(C8H4O4)(C10H8N2)(H2O)2]n, (IIa). The structural change consists of the loss of the two solvent water mol­ecules linking the original two-dimensional covalent substructures which are the `main frame' of the monoclinic P2/n hydrate (strictly preserved during the transformation), with further reaccommodation of the latter. The anhydrate organizes itself in the ortho­rhom­bic system (space group Pmn21) in a disordered fashion, where the space-group-symmetry restrictions are achieved only in a statistical sense, with mirror-related two-dimensional planar substructures, mirrored in a plane perpendicular to [100]. Thus, the asymmetric unit in the refined model is composed of two superimposed mirror-related `ghosts' of half-occupancy each. Similarities and differences with the parent dihydrate and some other related structures in the literature are discussed.
Fil: Harvey, Miguel Angel. Universidad Nacional de la Patagonia Austral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Centro Nacional Patagónico; Argentina
Fil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Cukiernik, Fabio Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
description Controlled heating of single crystals of the previously reported [Köferstein & Robl (2007). Z. Anorg. Allg. Chem. 633, 1127-1130] dihydrate {[Co(pht)(bpy)(H2O)2]·2H2O}n, (II) [where pht is phthalate (C8H4O4) and bpy is 4,4'-bi­pyridine (C10H8N2)], produced a topotactic transformation into an un­reported di­aqua anhydrate, namely poly[di­aqua([mu]2-benzene-1,2-di­carboxyl­ato-[kappa]2O1:O2)­([mu]2-4,4'-bi­pyridine-[kappa]2N:N')cobalt(II)], [Co(C8H4O4)(C10H8N2)(H2O)2]n, (IIa). The structural change consists of the loss of the two solvent water mol­ecules linking the original two-dimensional covalent substructures which are the `main frame' of the monoclinic P2/n hydrate (strictly preserved during the transformation), with further reaccommodation of the latter. The anhydrate organizes itself in the ortho­rhom­bic system (space group Pmn21) in a disordered fashion, where the space-group-symmetry restrictions are achieved only in a statistical sense, with mirror-related two-dimensional planar substructures, mirrored in a plane perpendicular to [100]. Thus, the asymmetric unit in the refined model is composed of two superimposed mirror-related `ghosts' of half-occupancy each. Similarities and differences with the parent dihydrate and some other related structures in the literature are discussed.
publishDate 2014
dc.date.none.fl_str_mv 2014-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31740
Baggio, Ricardo Fortunato; Suarez, Sebastian; Harvey, Miguel Angel; Cukiernik, Fabio Daniel; The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine); International Union of Crystallography; Acta Crystallographica Section C-Crystal Structure Communications; C70; 7-2014; 978-982
0108-2701
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31740
identifier_str_mv Baggio, Ricardo Fortunato; Suarez, Sebastian; Harvey, Miguel Angel; Cukiernik, Fabio Daniel; The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}n into ortho­rhom­bic [Co(pht)(bpy)(H2O)2]n (pht is phthalate and bpy is 4,4'-bi­pyridine); International Union of Crystallography; Acta Crystallographica Section C-Crystal Structure Communications; C70; 7-2014; 978-982
0108-2701
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1107/S2053229614020427
info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2053229614020427
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
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dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
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instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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