Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability
- Autores
- Diez, Veronica Karina; Di Cosimo, Juana Isabel; Apesteguia, Carlos Rodolfo
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The liquid-phase citral/acetone reaction was studied on MgO, Al2O3 and MgyAlOx mixed oxides with Mg/Al molar ratios of 0.11-3. The density, strength and nature of surface acid sites were determined by NH3 thermodesorption and FTIR of pyridine. The surface basic properties were probed by temperature-programmed desorption of CO2. The rate of the citral/acetone cross-aldolization to pseudoionones increased linearly with the density of strong O2- base sites. Thus, the pseudoionone synthesis was efficiently promoted on MgO and Mg-rich MgyAlOx samples. In contrast, the initial rate of the parallel acetone self-condensation reaction increased with the density of Lewis acid sites, and diacetone alcohol was more rapidly formed on Al2O3 and Al-rich MgyAlOx samples. Differences in the reactant adsorption strength on surface Al3+ sites may explain the observed differences between the acid-catalyzed mechanisms of cross- and self-aldolization reactions. In situ catalyst deactivation was determined by performing two consecutive catalytic runs. The activity decay of MgyAlOx samples during the citral/acetone reaction was between 15 and 20%, irrespective of the catalyst composition.
Fil: Diez, Veronica Karina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Di Cosimo, Juana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina - Materia
-
Aldol Condensation
Citral/Acetone Reaction
Fine Chemicals
Mgyalox Catalysts
Pseudoionone Synthesis - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/65250
Ver los metadatos del registro completo
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Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stabilityDiez, Veronica KarinaDi Cosimo, Juana IsabelApesteguia, Carlos RodolfoAldol CondensationCitral/Acetone ReactionFine ChemicalsMgyalox CatalystsPseudoionone Synthesishttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The liquid-phase citral/acetone reaction was studied on MgO, Al2O3 and MgyAlOx mixed oxides with Mg/Al molar ratios of 0.11-3. The density, strength and nature of surface acid sites were determined by NH3 thermodesorption and FTIR of pyridine. The surface basic properties were probed by temperature-programmed desorption of CO2. The rate of the citral/acetone cross-aldolization to pseudoionones increased linearly with the density of strong O2- base sites. Thus, the pseudoionone synthesis was efficiently promoted on MgO and Mg-rich MgyAlOx samples. In contrast, the initial rate of the parallel acetone self-condensation reaction increased with the density of Lewis acid sites, and diacetone alcohol was more rapidly formed on Al2O3 and Al-rich MgyAlOx samples. Differences in the reactant adsorption strength on surface Al3+ sites may explain the observed differences between the acid-catalyzed mechanisms of cross- and self-aldolization reactions. In situ catalyst deactivation was determined by performing two consecutive catalytic runs. The activity decay of MgyAlOx samples during the citral/acetone reaction was between 15 and 20%, irrespective of the catalyst composition.Fil: Diez, Veronica Karina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Di Cosimo, Juana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2008-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/65250Diez, Veronica Karina; Di Cosimo, Juana Isabel; Apesteguia, Carlos Rodolfo; Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability; Elsevier Science; Applied Catalysis A: General; 345; 2; 8-2008; 143-1510926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2008.04.035info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:46:36Zoai:ri.conicet.gov.ar:11336/65250instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:46:36.451CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability |
title |
Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability |
spellingShingle |
Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability Diez, Veronica Karina Aldol Condensation Citral/Acetone Reaction Fine Chemicals Mgyalox Catalysts Pseudoionone Synthesis |
title_short |
Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability |
title_full |
Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability |
title_fullStr |
Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability |
title_full_unstemmed |
Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability |
title_sort |
Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability |
dc.creator.none.fl_str_mv |
Diez, Veronica Karina Di Cosimo, Juana Isabel Apesteguia, Carlos Rodolfo |
author |
Diez, Veronica Karina |
author_facet |
Diez, Veronica Karina Di Cosimo, Juana Isabel Apesteguia, Carlos Rodolfo |
author_role |
author |
author2 |
Di Cosimo, Juana Isabel Apesteguia, Carlos Rodolfo |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Aldol Condensation Citral/Acetone Reaction Fine Chemicals Mgyalox Catalysts Pseudoionone Synthesis |
topic |
Aldol Condensation Citral/Acetone Reaction Fine Chemicals Mgyalox Catalysts Pseudoionone Synthesis |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The liquid-phase citral/acetone reaction was studied on MgO, Al2O3 and MgyAlOx mixed oxides with Mg/Al molar ratios of 0.11-3. The density, strength and nature of surface acid sites were determined by NH3 thermodesorption and FTIR of pyridine. The surface basic properties were probed by temperature-programmed desorption of CO2. The rate of the citral/acetone cross-aldolization to pseudoionones increased linearly with the density of strong O2- base sites. Thus, the pseudoionone synthesis was efficiently promoted on MgO and Mg-rich MgyAlOx samples. In contrast, the initial rate of the parallel acetone self-condensation reaction increased with the density of Lewis acid sites, and diacetone alcohol was more rapidly formed on Al2O3 and Al-rich MgyAlOx samples. Differences in the reactant adsorption strength on surface Al3+ sites may explain the observed differences between the acid-catalyzed mechanisms of cross- and self-aldolization reactions. In situ catalyst deactivation was determined by performing two consecutive catalytic runs. The activity decay of MgyAlOx samples during the citral/acetone reaction was between 15 and 20%, irrespective of the catalyst composition. Fil: Diez, Veronica Karina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Di Cosimo, Juana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina |
description |
The liquid-phase citral/acetone reaction was studied on MgO, Al2O3 and MgyAlOx mixed oxides with Mg/Al molar ratios of 0.11-3. The density, strength and nature of surface acid sites were determined by NH3 thermodesorption and FTIR of pyridine. The surface basic properties were probed by temperature-programmed desorption of CO2. The rate of the citral/acetone cross-aldolization to pseudoionones increased linearly with the density of strong O2- base sites. Thus, the pseudoionone synthesis was efficiently promoted on MgO and Mg-rich MgyAlOx samples. In contrast, the initial rate of the parallel acetone self-condensation reaction increased with the density of Lewis acid sites, and diacetone alcohol was more rapidly formed on Al2O3 and Al-rich MgyAlOx samples. Differences in the reactant adsorption strength on surface Al3+ sites may explain the observed differences between the acid-catalyzed mechanisms of cross- and self-aldolization reactions. In situ catalyst deactivation was determined by performing two consecutive catalytic runs. The activity decay of MgyAlOx samples during the citral/acetone reaction was between 15 and 20%, irrespective of the catalyst composition. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/65250 Diez, Veronica Karina; Di Cosimo, Juana Isabel; Apesteguia, Carlos Rodolfo; Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability; Elsevier Science; Applied Catalysis A: General; 345; 2; 8-2008; 143-151 0926-860X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/65250 |
identifier_str_mv |
Diez, Veronica Karina; Di Cosimo, Juana Isabel; Apesteguia, Carlos Rodolfo; Study of the citral/acetone reaction on MgyAlOx oxides: Effect of the chemical composition on catalyst activity, selectivity and stability; Elsevier Science; Applied Catalysis A: General; 345; 2; 8-2008; 143-151 0926-860X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2008.04.035 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613454777810944 |
score |
13.070432 |