Behavior of catalytic pellets at high reaction rates. The effect of edges

Autores
Keegan, Sergio Dario; Mariani, Nestor Javier; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The diffusion and reaction problem in catalytic pellets of any shape subject to diffusive transport limitations is undertaken in this contribution. Effective reaction rates in three-dimensional (3D) catalysts can be evaluated through a series solution written in terms of powers of (1/Φ) when strong diffusion limitations are present. In a recent paper, Keegan et al. [Chem. Eng. J. 2005, 110, 41] have clearly demonstrated for smooth catalysts that the second-order term [in (1/Φ)2] depends essentially on the shape of the pellet. In this context, the purpose of this paper is to develop expressions of the second-order term for two-dimensional (2D) or 3D catalytic bodies showing edges. While the first-order term allows definition of the proper size of a catalyst, the second-order term provides a characterization for the shape of the catalyst. The possibility of using this characterization of catalyst shape in a geometrical one-dimensional (1D) model to approximate the behavior of given 2D or 3D pellets is analyzed. Also, the direct use of the two-term truncated series for complementing the numerical evaluation of the conservation equation is described.
Fil: Keegan, Sergio Dario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Mariani, Nestor Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Martinez, Osvaldo Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Barreto, Guillermo Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
Effective Reaction Rate
Catalyst Shape
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/54975
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/54975
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Behavior of catalytic pellets at high reaction rates. The effect of edgesKeegan, Sergio DarioMariani, Nestor JavierMartinez, Osvaldo MiguelBarreto, Guillermo FernandoEffective Reaction RateCatalyst Shapehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The diffusion and reaction problem in catalytic pellets of any shape subject to diffusive transport limitations is undertaken in this contribution. Effective reaction rates in three-dimensional (3D) catalysts can be evaluated through a series solution written in terms of powers of (1/Φ) when strong diffusion limitations are present. In a recent paper, Keegan et al. [Chem. Eng. J. 2005, 110, 41] have clearly demonstrated for smooth catalysts that the second-order term [in (1/Φ)2] depends essentially on the shape of the pellet. In this context, the purpose of this paper is to develop expressions of the second-order term for two-dimensional (2D) or 3D catalytic bodies showing edges. While the first-order term allows definition of the proper size of a catalyst, the second-order term provides a characterization for the shape of the catalyst. The possibility of using this characterization of catalyst shape in a geometrical one-dimensional (1D) model to approximate the behavior of given 2D or 3D pellets is analyzed. Also, the direct use of the two-term truncated series for complementing the numerical evaluation of the conservation equation is described.Fil: Keegan, Sergio Dario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Mariani, Nestor Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Martinez, Osvaldo Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Barreto, Guillermo Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaAmerican Chemical Society2006-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/54975Keegan, Sergio Dario; Mariani, Nestor Javier; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando; Behavior of catalytic pellets at high reaction rates. The effect of edges; American Chemical Society; Industrial & Engineering Chemical Research; 45; 1; 1-2006; 85-970888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ie050740minfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ie050740minfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:25:50Zoai:ri.conicet.gov.ar:11336/54975instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:25:50.235CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Behavior of catalytic pellets at high reaction rates. The effect of edges
title Behavior of catalytic pellets at high reaction rates. The effect of edges
spellingShingle Behavior of catalytic pellets at high reaction rates. The effect of edges
Keegan, Sergio Dario
Effective Reaction Rate
Catalyst Shape
title_short Behavior of catalytic pellets at high reaction rates. The effect of edges
title_full Behavior of catalytic pellets at high reaction rates. The effect of edges
title_fullStr Behavior of catalytic pellets at high reaction rates. The effect of edges
title_full_unstemmed Behavior of catalytic pellets at high reaction rates. The effect of edges
title_sort Behavior of catalytic pellets at high reaction rates. The effect of edges
dc.creator.none.fl_str_mv Keegan, Sergio Dario
Mariani, Nestor Javier
Martinez, Osvaldo Miguel
Barreto, Guillermo Fernando
author Keegan, Sergio Dario
author_facet Keegan, Sergio Dario
Mariani, Nestor Javier
Martinez, Osvaldo Miguel
Barreto, Guillermo Fernando
author_role author
author2 Mariani, Nestor Javier
Martinez, Osvaldo Miguel
Barreto, Guillermo Fernando
author2_role author
author
author
dc.subject.none.fl_str_mv Effective Reaction Rate
Catalyst Shape
topic Effective Reaction Rate
Catalyst Shape
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The diffusion and reaction problem in catalytic pellets of any shape subject to diffusive transport limitations is undertaken in this contribution. Effective reaction rates in three-dimensional (3D) catalysts can be evaluated through a series solution written in terms of powers of (1/Φ) when strong diffusion limitations are present. In a recent paper, Keegan et al. [Chem. Eng. J. 2005, 110, 41] have clearly demonstrated for smooth catalysts that the second-order term [in (1/Φ)2] depends essentially on the shape of the pellet. In this context, the purpose of this paper is to develop expressions of the second-order term for two-dimensional (2D) or 3D catalytic bodies showing edges. While the first-order term allows definition of the proper size of a catalyst, the second-order term provides a characterization for the shape of the catalyst. The possibility of using this characterization of catalyst shape in a geometrical one-dimensional (1D) model to approximate the behavior of given 2D or 3D pellets is analyzed. Also, the direct use of the two-term truncated series for complementing the numerical evaluation of the conservation equation is described.
Fil: Keegan, Sergio Dario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Mariani, Nestor Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Martinez, Osvaldo Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Barreto, Guillermo Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description The diffusion and reaction problem in catalytic pellets of any shape subject to diffusive transport limitations is undertaken in this contribution. Effective reaction rates in three-dimensional (3D) catalysts can be evaluated through a series solution written in terms of powers of (1/Φ) when strong diffusion limitations are present. In a recent paper, Keegan et al. [Chem. Eng. J. 2005, 110, 41] have clearly demonstrated for smooth catalysts that the second-order term [in (1/Φ)2] depends essentially on the shape of the pellet. In this context, the purpose of this paper is to develop expressions of the second-order term for two-dimensional (2D) or 3D catalytic bodies showing edges. While the first-order term allows definition of the proper size of a catalyst, the second-order term provides a characterization for the shape of the catalyst. The possibility of using this characterization of catalyst shape in a geometrical one-dimensional (1D) model to approximate the behavior of given 2D or 3D pellets is analyzed. Also, the direct use of the two-term truncated series for complementing the numerical evaluation of the conservation equation is described.
publishDate 2006
dc.date.none.fl_str_mv 2006-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/54975
Keegan, Sergio Dario; Mariani, Nestor Javier; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando; Behavior of catalytic pellets at high reaction rates. The effect of edges; American Chemical Society; Industrial & Engineering Chemical Research; 45; 1; 1-2006; 85-97
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/54975
identifier_str_mv Keegan, Sergio Dario; Mariani, Nestor Javier; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando; Behavior of catalytic pellets at high reaction rates. The effect of edges; American Chemical Society; Industrial & Engineering Chemical Research; 45; 1; 1-2006; 85-97
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ie050740m
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/ie050740m
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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