Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode

Autores
Moreno Botello, Zulma Liliana; Caneiro, Alberto; Roussel, Pascal; Gauthier, Gilles
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The Y1−xZrxMnO3series (0 ≤ x ≤ 0.30) has been studied to be used as possible SOFC electrode material. These compounds adopt a layered structure of hexagonal symmetry in which the manganese cations are located in trigonal bi-pyramidal coordination of oxygen atoms, different from that of the classical perovskite. The synthesis of the materials has been carried out by solid state reaction and X-ray diffraction technique reveals that pure phases can be obtained until x∼0.10. For x ≥ 0.10, an additional YSZ phase is formed, similar to the SOFC electrolyte material. HT-XRD technique and thermogravimetric analysis of pure or Zr-doped YMnO3indicate that, in diluted dry H2for T > 600 °C, these compounds are unstable, what precludes their use as anode material. On the other hand, reactivity studies at high temperature (T = 1300 °C) between Y1−xZrxMnO3(x = 0, 0.05 and 0.1) and 8YSZ show a chemical compatibility in which the formation of an electrically insulating phase does not take place, but a crossed diffusion of Y3+/Mn3+and Zr4+at the interface between both materials. Thermomechanical compatibility in air between YSZ and Y1−xZrxMnO3is also demonstrated from RT to 850 °C.
Fil: Moreno Botello, Zulma Liliana. Universidad Industrial Santander; Colombia. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Caneiro, Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Roussel, Pascal. Instituto Pasteur; Francia. Centre National de la Recherche Scientifique; Francia. Universite Lille; Francia
Fil: Gauthier, Gilles. Universidad Industrial Santander; Colombia
Materia
Electrode
Reactivity
Reducibility
Solid Oxide Fuel Cells
Yttrium Manganite
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/72566

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network_name_str CONICET Digital (CONICET)
spelling Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrodeMoreno Botello, Zulma LilianaCaneiro, AlbertoRoussel, PascalGauthier, GillesElectrodeReactivityReducibilitySolid Oxide Fuel CellsYttrium Manganitehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The Y1−xZrxMnO3series (0 ≤ x ≤ 0.30) has been studied to be used as possible SOFC electrode material. These compounds adopt a layered structure of hexagonal symmetry in which the manganese cations are located in trigonal bi-pyramidal coordination of oxygen atoms, different from that of the classical perovskite. The synthesis of the materials has been carried out by solid state reaction and X-ray diffraction technique reveals that pure phases can be obtained until x∼0.10. For x ≥ 0.10, an additional YSZ phase is formed, similar to the SOFC electrolyte material. HT-XRD technique and thermogravimetric analysis of pure or Zr-doped YMnO3indicate that, in diluted dry H2for T > 600 °C, these compounds are unstable, what precludes their use as anode material. On the other hand, reactivity studies at high temperature (T = 1300 °C) between Y1−xZrxMnO3(x = 0, 0.05 and 0.1) and 8YSZ show a chemical compatibility in which the formation of an electrically insulating phase does not take place, but a crossed diffusion of Y3+/Mn3+and Zr4+at the interface between both materials. Thermomechanical compatibility in air between YSZ and Y1−xZrxMnO3is also demonstrated from RT to 850 °C.Fil: Moreno Botello, Zulma Liliana. Universidad Industrial Santander; Colombia. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Caneiro, Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Roussel, Pascal. Instituto Pasteur; Francia. Centre National de la Recherche Scientifique; Francia. Universite Lille; FranciaFil: Gauthier, Gilles. Universidad Industrial Santander; ColombiaElsevier Science Sa2017-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/72566Moreno Botello, Zulma Liliana; Caneiro, Alberto; Roussel, Pascal; Gauthier, Gilles; Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode; Elsevier Science Sa; Journal of Alloys and Compounds; 690; 6-2017; 348-3550925-8388CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0925838816325038info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2016.08.125info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:31:06Zoai:ri.conicet.gov.ar:11336/72566instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:31:06.756CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode
title Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode
spellingShingle Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode
Moreno Botello, Zulma Liliana
Electrode
Reactivity
Reducibility
Solid Oxide Fuel Cells
Yttrium Manganite
title_short Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode
title_full Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode
title_fullStr Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode
title_full_unstemmed Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode
title_sort Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode
dc.creator.none.fl_str_mv Moreno Botello, Zulma Liliana
Caneiro, Alberto
Roussel, Pascal
Gauthier, Gilles
author Moreno Botello, Zulma Liliana
author_facet Moreno Botello, Zulma Liliana
Caneiro, Alberto
Roussel, Pascal
Gauthier, Gilles
author_role author
author2 Caneiro, Alberto
Roussel, Pascal
Gauthier, Gilles
author2_role author
author
author
dc.subject.none.fl_str_mv Electrode
Reactivity
Reducibility
Solid Oxide Fuel Cells
Yttrium Manganite
topic Electrode
Reactivity
Reducibility
Solid Oxide Fuel Cells
Yttrium Manganite
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The Y1−xZrxMnO3series (0 ≤ x ≤ 0.30) has been studied to be used as possible SOFC electrode material. These compounds adopt a layered structure of hexagonal symmetry in which the manganese cations are located in trigonal bi-pyramidal coordination of oxygen atoms, different from that of the classical perovskite. The synthesis of the materials has been carried out by solid state reaction and X-ray diffraction technique reveals that pure phases can be obtained until x∼0.10. For x ≥ 0.10, an additional YSZ phase is formed, similar to the SOFC electrolyte material. HT-XRD technique and thermogravimetric analysis of pure or Zr-doped YMnO3indicate that, in diluted dry H2for T > 600 °C, these compounds are unstable, what precludes their use as anode material. On the other hand, reactivity studies at high temperature (T = 1300 °C) between Y1−xZrxMnO3(x = 0, 0.05 and 0.1) and 8YSZ show a chemical compatibility in which the formation of an electrically insulating phase does not take place, but a crossed diffusion of Y3+/Mn3+and Zr4+at the interface between both materials. Thermomechanical compatibility in air between YSZ and Y1−xZrxMnO3is also demonstrated from RT to 850 °C.
Fil: Moreno Botello, Zulma Liliana. Universidad Industrial Santander; Colombia. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Caneiro, Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Roussel, Pascal. Instituto Pasteur; Francia. Centre National de la Recherche Scientifique; Francia. Universite Lille; Francia
Fil: Gauthier, Gilles. Universidad Industrial Santander; Colombia
description The Y1−xZrxMnO3series (0 ≤ x ≤ 0.30) has been studied to be used as possible SOFC electrode material. These compounds adopt a layered structure of hexagonal symmetry in which the manganese cations are located in trigonal bi-pyramidal coordination of oxygen atoms, different from that of the classical perovskite. The synthesis of the materials has been carried out by solid state reaction and X-ray diffraction technique reveals that pure phases can be obtained until x∼0.10. For x ≥ 0.10, an additional YSZ phase is formed, similar to the SOFC electrolyte material. HT-XRD technique and thermogravimetric analysis of pure or Zr-doped YMnO3indicate that, in diluted dry H2for T > 600 °C, these compounds are unstable, what precludes their use as anode material. On the other hand, reactivity studies at high temperature (T = 1300 °C) between Y1−xZrxMnO3(x = 0, 0.05 and 0.1) and 8YSZ show a chemical compatibility in which the formation of an electrically insulating phase does not take place, but a crossed diffusion of Y3+/Mn3+and Zr4+at the interface between both materials. Thermomechanical compatibility in air between YSZ and Y1−xZrxMnO3is also demonstrated from RT to 850 °C.
publishDate 2017
dc.date.none.fl_str_mv 2017-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/72566
Moreno Botello, Zulma Liliana; Caneiro, Alberto; Roussel, Pascal; Gauthier, Gilles; Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode; Elsevier Science Sa; Journal of Alloys and Compounds; 690; 6-2017; 348-355
0925-8388
CONICET Digital
CONICET
url http://hdl.handle.net/11336/72566
identifier_str_mv Moreno Botello, Zulma Liliana; Caneiro, Alberto; Roussel, Pascal; Gauthier, Gilles; Synthesis and preliminary study of pure and Zr-doped YMnO3 compounds as Solid Oxide Fuel Cells electrode; Elsevier Science Sa; Journal of Alloys and Compounds; 690; 6-2017; 348-355
0925-8388
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0925838816325038
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2016.08.125
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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