Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes

Autores
Dabrowski, Sergio Gustavo; Tudino, Mabel Beatriz; Molina, Fernando Víctor
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, the electrochemical response of Vanadium(V) species on magnetite film electrodes is investigated. Magnetite is deposited electrochemically on glassy carbon electrodes, with an intermediate layer of poly(thiophene) to avoid water infiltration. These electrodes show good reproducibility and stability up to pH = 2.0. Mononuclear V(V) species show low electroactivity on this surface. Cyclic voltammetry at low V(V) concentration shows that it is electroactive only at pH < 3. i.e. as VO2 +. A single reduction peak is observed at ~− 0.7 V vs SCE (at 50 mV s− 1), and an oxidation one at ~ 0.5 V vs SCE, indicating high irreversibility of the V(V)/V(IV) couple; these peaks are found to be solution phase reactions. These features are interpreted in terms of mononuclear V species. At higher V concentrations, where polymeric V(V) species are dominant, a somewhat higher electroactivity is observed, with two reduction peaks and two/three oxidation peaks.
Fil: Dabrowski, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Tudino, Mabel Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Molina, Fernando Víctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
Conducting Polymer
Cyclic Voltammetry
Iron Oxide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/65338
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/65338
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodesDabrowski, Sergio GustavoTudino, Mabel BeatrizMolina, Fernando VíctorConducting PolymerCyclic VoltammetryIron Oxidehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work, the electrochemical response of Vanadium(V) species on magnetite film electrodes is investigated. Magnetite is deposited electrochemically on glassy carbon electrodes, with an intermediate layer of poly(thiophene) to avoid water infiltration. These electrodes show good reproducibility and stability up to pH = 2.0. Mononuclear V(V) species show low electroactivity on this surface. Cyclic voltammetry at low V(V) concentration shows that it is electroactive only at pH < 3. i.e. as VO2 +. A single reduction peak is observed at ~− 0.7 V vs SCE (at 50 mV s− 1), and an oxidation one at ~ 0.5 V vs SCE, indicating high irreversibility of the V(V)/V(IV) couple; these peaks are found to be solution phase reactions. These features are interpreted in terms of mononuclear V species. At higher V concentrations, where polymeric V(V) species are dominant, a somewhat higher electroactivity is observed, with two reduction peaks and two/three oxidation peaks.Fil: Dabrowski, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Tudino, Mabel Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Molina, Fernando Víctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaElsevier Science Sa2018-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/65338Dabrowski, Sergio Gustavo; Tudino, Mabel Beatriz; Molina, Fernando Víctor; Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 819; 6-2018; 283-2881572-6657CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S1572665717307610info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2017.10.053info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:27Zoai:ri.conicet.gov.ar:11336/65338instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:27.333CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes
title Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes
spellingShingle Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes
Dabrowski, Sergio Gustavo
Conducting Polymer
Cyclic Voltammetry
Iron Oxide
title_short Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes
title_full Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes
title_fullStr Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes
title_full_unstemmed Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes
title_sort Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes
dc.creator.none.fl_str_mv Dabrowski, Sergio Gustavo
Tudino, Mabel Beatriz
Molina, Fernando Víctor
author Dabrowski, Sergio Gustavo
author_facet Dabrowski, Sergio Gustavo
Tudino, Mabel Beatriz
Molina, Fernando Víctor
author_role author
author2 Tudino, Mabel Beatriz
Molina, Fernando Víctor
author2_role author
author
dc.subject.none.fl_str_mv Conducting Polymer
Cyclic Voltammetry
Iron Oxide
topic Conducting Polymer
Cyclic Voltammetry
Iron Oxide
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work, the electrochemical response of Vanadium(V) species on magnetite film electrodes is investigated. Magnetite is deposited electrochemically on glassy carbon electrodes, with an intermediate layer of poly(thiophene) to avoid water infiltration. These electrodes show good reproducibility and stability up to pH = 2.0. Mononuclear V(V) species show low electroactivity on this surface. Cyclic voltammetry at low V(V) concentration shows that it is electroactive only at pH < 3. i.e. as VO2 +. A single reduction peak is observed at ~− 0.7 V vs SCE (at 50 mV s− 1), and an oxidation one at ~ 0.5 V vs SCE, indicating high irreversibility of the V(V)/V(IV) couple; these peaks are found to be solution phase reactions. These features are interpreted in terms of mononuclear V species. At higher V concentrations, where polymeric V(V) species are dominant, a somewhat higher electroactivity is observed, with two reduction peaks and two/three oxidation peaks.
Fil: Dabrowski, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Tudino, Mabel Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Molina, Fernando Víctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description In this work, the electrochemical response of Vanadium(V) species on magnetite film electrodes is investigated. Magnetite is deposited electrochemically on glassy carbon electrodes, with an intermediate layer of poly(thiophene) to avoid water infiltration. These electrodes show good reproducibility and stability up to pH = 2.0. Mononuclear V(V) species show low electroactivity on this surface. Cyclic voltammetry at low V(V) concentration shows that it is electroactive only at pH < 3. i.e. as VO2 +. A single reduction peak is observed at ~− 0.7 V vs SCE (at 50 mV s− 1), and an oxidation one at ~ 0.5 V vs SCE, indicating high irreversibility of the V(V)/V(IV) couple; these peaks are found to be solution phase reactions. These features are interpreted in terms of mononuclear V species. At higher V concentrations, where polymeric V(V) species are dominant, a somewhat higher electroactivity is observed, with two reduction peaks and two/three oxidation peaks.
publishDate 2018
dc.date.none.fl_str_mv 2018-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/65338
Dabrowski, Sergio Gustavo; Tudino, Mabel Beatriz; Molina, Fernando Víctor; Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 819; 6-2018; 283-288
1572-6657
CONICET Digital
CONICET
url http://hdl.handle.net/11336/65338
identifier_str_mv Dabrowski, Sergio Gustavo; Tudino, Mabel Beatriz; Molina, Fernando Víctor; Electrochemical behaviour of Vanadium(V) on electrochemically synthesized magnetite film electrodes; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 819; 6-2018; 283-288
1572-6657
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S1572665717307610
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2017.10.053
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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