Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy

Autores
Flamini, Daniel Omar; Saidman, Silvana Beatriz
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Polypyrrole (PPy) films were electrodeposited onto nickel--titanium alloy (NiTi) employing sodium bis(2-ethylhexyl) sulfosuccinate (Aerosol OT or AOT) solutions. Polarizing anodically NiTi samples recovered by PPy in a monomer-free solution increases adhesion of the coating. Electrochemical techniques, scanning electron microscopy (SEM) and element analysis were used in determining the corrosion performance of the coated samples in chloride solution. The polymer improves the corrosion performance at the open circuit potential and at potentials where the bare substrate suffers pitting attack. The improvement in both, adhesion and corrosion performance, is discussed considering substrate/polymer interaction, overoxidation of PPy and the role played by AOT. © 2009 Elsevier Ltd. All rights reserved.
Fil: Flamini, Daniel Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Saidman, Silvana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Materia
A. Aot
A. Nickel--Titanium Alloy
A. Polypyrrole
C. Electropolymerization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/62001

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spelling Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloyFlamini, Daniel OmarSaidman, Silvana BeatrizA. AotA. Nickel--Titanium AlloyA. PolypyrroleC. Electropolymerizationhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Polypyrrole (PPy) films were electrodeposited onto nickel--titanium alloy (NiTi) employing sodium bis(2-ethylhexyl) sulfosuccinate (Aerosol OT or AOT) solutions. Polarizing anodically NiTi samples recovered by PPy in a monomer-free solution increases adhesion of the coating. Electrochemical techniques, scanning electron microscopy (SEM) and element analysis were used in determining the corrosion performance of the coated samples in chloride solution. The polymer improves the corrosion performance at the open circuit potential and at potentials where the bare substrate suffers pitting attack. The improvement in both, adhesion and corrosion performance, is discussed considering substrate/polymer interaction, overoxidation of PPy and the role played by AOT. © 2009 Elsevier Ltd. All rights reserved.Fil: Flamini, Daniel Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; ArgentinaFil: Saidman, Silvana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; ArgentinaPergamon-Elsevier Science Ltd2010-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/62001Flamini, Daniel Omar; Saidman, Silvana Beatriz; Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy; Pergamon-Elsevier Science Ltd; Corrosion Science; 52; 1; 1-2010; 229-2340010-938XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0010938X09004417info:eu-repo/semantics/altIdentifier/doi/10.1016/j.corsci.2009.09.008info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:09:07Zoai:ri.conicet.gov.ar:11336/62001instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:09:07.717CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy
title Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy
spellingShingle Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy
Flamini, Daniel Omar
A. Aot
A. Nickel--Titanium Alloy
A. Polypyrrole
C. Electropolymerization
title_short Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy
title_full Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy
title_fullStr Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy
title_full_unstemmed Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy
title_sort Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy
dc.creator.none.fl_str_mv Flamini, Daniel Omar
Saidman, Silvana Beatriz
author Flamini, Daniel Omar
author_facet Flamini, Daniel Omar
Saidman, Silvana Beatriz
author_role author
author2 Saidman, Silvana Beatriz
author2_role author
dc.subject.none.fl_str_mv A. Aot
A. Nickel--Titanium Alloy
A. Polypyrrole
C. Electropolymerization
topic A. Aot
A. Nickel--Titanium Alloy
A. Polypyrrole
C. Electropolymerization
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Polypyrrole (PPy) films were electrodeposited onto nickel--titanium alloy (NiTi) employing sodium bis(2-ethylhexyl) sulfosuccinate (Aerosol OT or AOT) solutions. Polarizing anodically NiTi samples recovered by PPy in a monomer-free solution increases adhesion of the coating. Electrochemical techniques, scanning electron microscopy (SEM) and element analysis were used in determining the corrosion performance of the coated samples in chloride solution. The polymer improves the corrosion performance at the open circuit potential and at potentials where the bare substrate suffers pitting attack. The improvement in both, adhesion and corrosion performance, is discussed considering substrate/polymer interaction, overoxidation of PPy and the role played by AOT. © 2009 Elsevier Ltd. All rights reserved.
Fil: Flamini, Daniel Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Saidman, Silvana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
description Polypyrrole (PPy) films were electrodeposited onto nickel--titanium alloy (NiTi) employing sodium bis(2-ethylhexyl) sulfosuccinate (Aerosol OT or AOT) solutions. Polarizing anodically NiTi samples recovered by PPy in a monomer-free solution increases adhesion of the coating. Electrochemical techniques, scanning electron microscopy (SEM) and element analysis were used in determining the corrosion performance of the coated samples in chloride solution. The polymer improves the corrosion performance at the open circuit potential and at potentials where the bare substrate suffers pitting attack. The improvement in both, adhesion and corrosion performance, is discussed considering substrate/polymer interaction, overoxidation of PPy and the role played by AOT. © 2009 Elsevier Ltd. All rights reserved.
publishDate 2010
dc.date.none.fl_str_mv 2010-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/62001
Flamini, Daniel Omar; Saidman, Silvana Beatriz; Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy; Pergamon-Elsevier Science Ltd; Corrosion Science; 52; 1; 1-2010; 229-234
0010-938X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/62001
identifier_str_mv Flamini, Daniel Omar; Saidman, Silvana Beatriz; Electrodeposition of polypyrrole onto NiTi and the corrosion behaviour of the coated alloy; Pergamon-Elsevier Science Ltd; Corrosion Science; 52; 1; 1-2010; 229-234
0010-938X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0010938X09004417
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.corsci.2009.09.008
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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