Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system

Autores
Plaza Cazón, Josefina del Carmen; Bernardelli, Cecilia Elena; Viera, Marisa Rosana; Donati, Edgardo Ruben; Guibal, Eric
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Zinc and cadmium can be efficiently removed from solutions using the brown algae, Macrocystis pyrifera. Treatment with CaCl 2 allowed stabilization of the biosorbent. The maximum biosorption capacities in mono-component systems were 0.91mmolg -1 and 0.89mmolg -1 and the Langmuir affinity coefficients were 1.76Lmmol -1 and 1.25Lmmol -1 for Zn(II) and Cd(II), respectively. In two-component systems, Zn(II) and Cd(II) adsorption capacities were reduced by 50% and 40%, respectively and the biosorbent showed a preference for Cd(II) over Zn(II). HNO 3 (0.1M) and EDTA (0.1M) achieved 90-100% desorption of both ions from the loaded biomass. While HNO 3 preserved the biomass structure, EDTA destroyed it completely. Fourier transform infrared spectra identified the contribution of carboxylic, amine and sulfonate groups on Zn(II) and Cd(II) biosorption. These results showed that biosorption using M. pyrifera-treated biomass could be an affordable and simple process for cadmium and zinc removal from wastewaters.
Fil: Viera, Marisa Rosana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Fermentaciones Industriales. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Fermentaciones Industriales; Argentina
Materia
ADSORPTION
CADMIUM
DESORPTION
MACROCYSTIS PYRIFERA
ZINC
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/94869
Acceder
id CONICETDig_0f66dcd97cbe6f2189231e4411b439f3
oai_identifier_str oai:ri.conicet.gov.ar:11336/94869
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch systemPlaza Cazón, Josefina del CarmenBernardelli, Cecilia ElenaViera, Marisa RosanaDonati, Edgardo RubenGuibal, EricADSORPTIONCADMIUMDESORPTIONMACROCYSTIS PYRIFERAZINChttps://purl.org/becyt/ford/2.7https://purl.org/becyt/ford/2Zinc and cadmium can be efficiently removed from solutions using the brown algae, Macrocystis pyrifera. Treatment with CaCl 2 allowed stabilization of the biosorbent. The maximum biosorption capacities in mono-component systems were 0.91mmolg -1 and 0.89mmolg -1 and the Langmuir affinity coefficients were 1.76Lmmol -1 and 1.25Lmmol -1 for Zn(II) and Cd(II), respectively. In two-component systems, Zn(II) and Cd(II) adsorption capacities were reduced by 50% and 40%, respectively and the biosorbent showed a preference for Cd(II) over Zn(II). HNO 3 (0.1M) and EDTA (0.1M) achieved 90-100% desorption of both ions from the loaded biomass. While HNO 3 preserved the biomass structure, EDTA destroyed it completely. Fourier transform infrared spectra identified the contribution of carboxylic, amine and sulfonate groups on Zn(II) and Cd(II) biosorption. These results showed that biosorption using M. pyrifera-treated biomass could be an affordable and simple process for cadmium and zinc removal from wastewaters.Fil: Viera, Marisa Rosana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Fermentaciones Industriales. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Fermentaciones Industriales; ArgentinaElsevier2012-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/94869Plaza Cazón, Josefina del Carmen; Bernardelli, Cecilia Elena; Viera, Marisa Rosana; Donati, Edgardo Ruben; Guibal, Eric; Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system; Elsevier; Bioresource Technology; 116; 7-2012; 195-2030960-8524CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0960852412006165info:eu-repo/semantics/altIdentifier/doi/10.1016/j.biortech.2012.04.014info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:37:40Zoai:ri.conicet.gov.ar:11336/94869instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:37:40.8CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system
title Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system
spellingShingle Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system
Plaza Cazón, Josefina del Carmen
ADSORPTION
CADMIUM
DESORPTION
MACROCYSTIS PYRIFERA
ZINC
title_short Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system
title_full Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system
title_fullStr Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system
title_full_unstemmed Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system
title_sort Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system
dc.creator.none.fl_str_mv Plaza Cazón, Josefina del Carmen
Bernardelli, Cecilia Elena
Viera, Marisa Rosana
Donati, Edgardo Ruben
Guibal, Eric
author Plaza Cazón, Josefina del Carmen
author_facet Plaza Cazón, Josefina del Carmen
Bernardelli, Cecilia Elena
Viera, Marisa Rosana
Donati, Edgardo Ruben
Guibal, Eric
author_role author
author2 Bernardelli, Cecilia Elena
Viera, Marisa Rosana
Donati, Edgardo Ruben
Guibal, Eric
author2_role author
author
author
author
dc.subject.none.fl_str_mv ADSORPTION
CADMIUM
DESORPTION
MACROCYSTIS PYRIFERA
ZINC
topic ADSORPTION
CADMIUM
DESORPTION
MACROCYSTIS PYRIFERA
ZINC
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Zinc and cadmium can be efficiently removed from solutions using the brown algae, Macrocystis pyrifera. Treatment with CaCl 2 allowed stabilization of the biosorbent. The maximum biosorption capacities in mono-component systems were 0.91mmolg -1 and 0.89mmolg -1 and the Langmuir affinity coefficients were 1.76Lmmol -1 and 1.25Lmmol -1 for Zn(II) and Cd(II), respectively. In two-component systems, Zn(II) and Cd(II) adsorption capacities were reduced by 50% and 40%, respectively and the biosorbent showed a preference for Cd(II) over Zn(II). HNO 3 (0.1M) and EDTA (0.1M) achieved 90-100% desorption of both ions from the loaded biomass. While HNO 3 preserved the biomass structure, EDTA destroyed it completely. Fourier transform infrared spectra identified the contribution of carboxylic, amine and sulfonate groups on Zn(II) and Cd(II) biosorption. These results showed that biosorption using M. pyrifera-treated biomass could be an affordable and simple process for cadmium and zinc removal from wastewaters.
Fil: Viera, Marisa Rosana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Fermentaciones Industriales. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Fermentaciones Industriales; Argentina
description Zinc and cadmium can be efficiently removed from solutions using the brown algae, Macrocystis pyrifera. Treatment with CaCl 2 allowed stabilization of the biosorbent. The maximum biosorption capacities in mono-component systems were 0.91mmolg -1 and 0.89mmolg -1 and the Langmuir affinity coefficients were 1.76Lmmol -1 and 1.25Lmmol -1 for Zn(II) and Cd(II), respectively. In two-component systems, Zn(II) and Cd(II) adsorption capacities were reduced by 50% and 40%, respectively and the biosorbent showed a preference for Cd(II) over Zn(II). HNO 3 (0.1M) and EDTA (0.1M) achieved 90-100% desorption of both ions from the loaded biomass. While HNO 3 preserved the biomass structure, EDTA destroyed it completely. Fourier transform infrared spectra identified the contribution of carboxylic, amine and sulfonate groups on Zn(II) and Cd(II) biosorption. These results showed that biosorption using M. pyrifera-treated biomass could be an affordable and simple process for cadmium and zinc removal from wastewaters.
publishDate 2012
dc.date.none.fl_str_mv 2012-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/94869
Plaza Cazón, Josefina del Carmen; Bernardelli, Cecilia Elena; Viera, Marisa Rosana; Donati, Edgardo Ruben; Guibal, Eric; Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system; Elsevier; Bioresource Technology; 116; 7-2012; 195-203
0960-8524
CONICET Digital
CONICET
url http://hdl.handle.net/11336/94869
identifier_str_mv Plaza Cazón, Josefina del Carmen; Bernardelli, Cecilia Elena; Viera, Marisa Rosana; Donati, Edgardo Ruben; Guibal, Eric; Zinc and cadmium biosorption by untreated and calcium-treated Macrocystis pyrifera in a batch system; Elsevier; Bioresource Technology; 116; 7-2012; 195-203
0960-8524
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0960852412006165
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.biortech.2012.04.014
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083497143304192
score 13.22299

Publicaciones similares