Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization

Autores
Aranda, Pedro Rodolfo; Pacheco, Pablo Hugo; Olsina, Roberto Antonio; Martinez, Luis Dante; Gil, Raul Andres
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
An automated procedure for total and inorganic mercury determination in biodiesel by CV-AFS was studied. The samples were introduced directly as oil-in-water emulsions in a flow injection manifold followed by cold vapor generation coupled to atomic fluorescence spectrometry (FI-CV-AFS). After irradiation with an UV source, organic mercury (e.g. MeHg+ and PhHg+ among others) was decomposed. Mercury vapors were generated using an acidic SnCl2 solution in a continuous flow system and were then determined. This strategy reduced sample handling, avoiding sample contamination and analyte losses. The limit of detection was calculated as 0.2 g Kg-1 (0.03 g L-1 for the emulsions) and the relative standard deviation was better than 8% at levels of 3.0 g L-1 in the emulsion, calculated from the peaks obtained. The accuracy was verified by comparing the results with a total microwave-assisted digestion.
Fil: Aranda, Pedro Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Pacheco, Pablo Hugo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Materia
Biodiesel
Oil-in-water emulsion formation
Multivariate Optimization
FI-CV-AFS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/92915
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/92915
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimizationAranda, Pedro RodolfoPacheco, Pablo HugoOlsina, Roberto AntonioMartinez, Luis DanteGil, Raul AndresBiodieselOil-in-water emulsion formationMultivariate OptimizationFI-CV-AFShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1An automated procedure for total and inorganic mercury determination in biodiesel by CV-AFS was studied. The samples were introduced directly as oil-in-water emulsions in a flow injection manifold followed by cold vapor generation coupled to atomic fluorescence spectrometry (FI-CV-AFS). After irradiation with an UV source, organic mercury (e.g. MeHg+ and PhHg+ among others) was decomposed. Mercury vapors were generated using an acidic SnCl2 solution in a continuous flow system and were then determined. This strategy reduced sample handling, avoiding sample contamination and analyte losses. The limit of detection was calculated as 0.2 g Kg-1 (0.03 g L-1 for the emulsions) and the relative standard deviation was better than 8% at levels of 3.0 g L-1 in the emulsion, calculated from the peaks obtained. The accuracy was verified by comparing the results with a total microwave-assisted digestion.Fil: Aranda, Pedro Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Pacheco, Pablo Hugo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaRoyal Society of Chemistry2009-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/92915Aranda, Pedro Rodolfo; Pacheco, Pablo Hugo; Olsina, Roberto Antonio; Martinez, Luis Dante; Gil, Raul Andres; Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 24; 10; 6-2009; 1441-14450267-9477CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/b903113hinfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2009/JA/b903113h#!divAbstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:52Zoai:ri.conicet.gov.ar:11336/92915instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:52.718CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization
title Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization
spellingShingle Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization
Aranda, Pedro Rodolfo
Biodiesel
Oil-in-water emulsion formation
Multivariate Optimization
FI-CV-AFS
title_short Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization
title_full Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization
title_fullStr Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization
title_full_unstemmed Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization
title_sort Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization
dc.creator.none.fl_str_mv Aranda, Pedro Rodolfo
Pacheco, Pablo Hugo
Olsina, Roberto Antonio
Martinez, Luis Dante
Gil, Raul Andres
author Aranda, Pedro Rodolfo
author_facet Aranda, Pedro Rodolfo
Pacheco, Pablo Hugo
Olsina, Roberto Antonio
Martinez, Luis Dante
Gil, Raul Andres
author_role author
author2 Pacheco, Pablo Hugo
Olsina, Roberto Antonio
Martinez, Luis Dante
Gil, Raul Andres
author2_role author
author
author
author
dc.subject.none.fl_str_mv Biodiesel
Oil-in-water emulsion formation
Multivariate Optimization
FI-CV-AFS
topic Biodiesel
Oil-in-water emulsion formation
Multivariate Optimization
FI-CV-AFS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv An automated procedure for total and inorganic mercury determination in biodiesel by CV-AFS was studied. The samples were introduced directly as oil-in-water emulsions in a flow injection manifold followed by cold vapor generation coupled to atomic fluorescence spectrometry (FI-CV-AFS). After irradiation with an UV source, organic mercury (e.g. MeHg+ and PhHg+ among others) was decomposed. Mercury vapors were generated using an acidic SnCl2 solution in a continuous flow system and were then determined. This strategy reduced sample handling, avoiding sample contamination and analyte losses. The limit of detection was calculated as 0.2 g Kg-1 (0.03 g L-1 for the emulsions) and the relative standard deviation was better than 8% at levels of 3.0 g L-1 in the emulsion, calculated from the peaks obtained. The accuracy was verified by comparing the results with a total microwave-assisted digestion.
Fil: Aranda, Pedro Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Pacheco, Pablo Hugo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
description An automated procedure for total and inorganic mercury determination in biodiesel by CV-AFS was studied. The samples were introduced directly as oil-in-water emulsions in a flow injection manifold followed by cold vapor generation coupled to atomic fluorescence spectrometry (FI-CV-AFS). After irradiation with an UV source, organic mercury (e.g. MeHg+ and PhHg+ among others) was decomposed. Mercury vapors were generated using an acidic SnCl2 solution in a continuous flow system and were then determined. This strategy reduced sample handling, avoiding sample contamination and analyte losses. The limit of detection was calculated as 0.2 g Kg-1 (0.03 g L-1 for the emulsions) and the relative standard deviation was better than 8% at levels of 3.0 g L-1 in the emulsion, calculated from the peaks obtained. The accuracy was verified by comparing the results with a total microwave-assisted digestion.
publishDate 2009
dc.date.none.fl_str_mv 2009-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/92915
Aranda, Pedro Rodolfo; Pacheco, Pablo Hugo; Olsina, Roberto Antonio; Martinez, Luis Dante; Gil, Raul Andres; Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 24; 10; 6-2009; 1441-1445
0267-9477
CONICET Digital
CONICET
url http://hdl.handle.net/11336/92915
identifier_str_mv Aranda, Pedro Rodolfo; Pacheco, Pablo Hugo; Olsina, Roberto Antonio; Martinez, Luis Dante; Gil, Raul Andres; Total and inorganic mercury determination in biodiesel by emulsion sample introduction and FI-CV-AFS after multivariate optimization; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 24; 10; 6-2009; 1441-1445
0267-9477
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/b903113h
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2009/JA/b903113h#!divAbstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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