Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water

Autores
Rossi, Ezequiel; Montoya Rojo, Ursula Maria; Cerrutti, Patricia; Foresti, María Laura; Errea, María Inés
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Carboxymethylated bacterial cellulose (CMBC) was synthesized under controlled reaction condition to provide a material with a degree of substitution (DS) that guarantees that the characteristic water insolubility of cellulose is retained (DS = 0.17). The CMBC synthesized was fully characterized by conductometric titration, infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, thermogravimetric analysis and solubility assays. The suitability of the produced CMBC for lead removal from water was evaluated. Experimental isotherm data were fitted to different models of sorption isotherms: Langmuir, Freundlich, Dubinin-Radushkevich, and Frumkin, with Langmuir equation resulting in the best fit. Kinetic data were also adjusted to pseudo-first-order and pseudo-second-order models and results undoubtedly showed that the pseudo-second-order kinetic equation was the one that most appropriately described the lead adsorption of CMBC, indicating that lead is adsorbed on CMBC predominantly by chemical interaction. The breakthrough curve was fitted to different models: Bohart-Adams, Clark and Modified Dose-Response, being the Bohart-Adams equation the one that gave the best fit. Desorption studies were carried out in order to know the technical feasibility of the reuse of CMBC. Almost 96% of the retained lead was eluted in just 20 mL, and the CMBC lifetime was over 50 adsorption/desorption cycles. Overall, results obtained suggest that the CMBC herein synthesized may result in an alternative economic and environmentally friendly lead adsorbent for water treatment.
Fil: Rossi, Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto Tecnológico de Buenos Aires; Argentina
Fil: Montoya Rojo, Ursula Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Cerrutti, Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; Argentina
Fil: Foresti, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Errea, María Inés. Instituto Tecnológico de Buenos Aires; Argentina
Materia
ADSORPTION
BREAKTHROUGH CURVE
CARBOXYMETHYLATED BACTERIAL CELLULOSE
ION EXCHANGER
LEAD
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/93071
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/93071
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from waterRossi, EzequielMontoya Rojo, Ursula MariaCerrutti, PatriciaForesti, María LauraErrea, María InésADSORPTIONBREAKTHROUGH CURVECARBOXYMETHYLATED BACTERIAL CELLULOSEION EXCHANGERLEADhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Carboxymethylated bacterial cellulose (CMBC) was synthesized under controlled reaction condition to provide a material with a degree of substitution (DS) that guarantees that the characteristic water insolubility of cellulose is retained (DS = 0.17). The CMBC synthesized was fully characterized by conductometric titration, infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, thermogravimetric analysis and solubility assays. The suitability of the produced CMBC for lead removal from water was evaluated. Experimental isotherm data were fitted to different models of sorption isotherms: Langmuir, Freundlich, Dubinin-Radushkevich, and Frumkin, with Langmuir equation resulting in the best fit. Kinetic data were also adjusted to pseudo-first-order and pseudo-second-order models and results undoubtedly showed that the pseudo-second-order kinetic equation was the one that most appropriately described the lead adsorption of CMBC, indicating that lead is adsorbed on CMBC predominantly by chemical interaction. The breakthrough curve was fitted to different models: Bohart-Adams, Clark and Modified Dose-Response, being the Bohart-Adams equation the one that gave the best fit. Desorption studies were carried out in order to know the technical feasibility of the reuse of CMBC. Almost 96% of the retained lead was eluted in just 20 mL, and the CMBC lifetime was over 50 adsorption/desorption cycles. Overall, results obtained suggest that the CMBC herein synthesized may result in an alternative economic and environmentally friendly lead adsorbent for water treatment.Fil: Rossi, Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto Tecnológico de Buenos Aires; ArgentinaFil: Montoya Rojo, Ursula Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Cerrutti, Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; ArgentinaFil: Foresti, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Errea, María Inés. Instituto Tecnológico de Buenos Aires; ArgentinaElsevier2018-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/93071Rossi, Ezequiel; Montoya Rojo, Ursula Maria; Cerrutti, Patricia; Foresti, María Laura; Errea, María Inés; Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water; Elsevier; Journal of Environmental Chemical Engineering; 6; 6; 12-2018; 6844-68522213-3437CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S221334371830664Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2018.10.055info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:51:44Zoai:ri.conicet.gov.ar:11336/93071instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:51:44.716CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water
title Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water
spellingShingle Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water
Rossi, Ezequiel
ADSORPTION
BREAKTHROUGH CURVE
CARBOXYMETHYLATED BACTERIAL CELLULOSE
ION EXCHANGER
LEAD
title_short Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water
title_full Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water
title_fullStr Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water
title_full_unstemmed Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water
title_sort Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water
dc.creator.none.fl_str_mv Rossi, Ezequiel
Montoya Rojo, Ursula Maria
Cerrutti, Patricia
Foresti, María Laura
Errea, María Inés
author Rossi, Ezequiel
author_facet Rossi, Ezequiel
Montoya Rojo, Ursula Maria
Cerrutti, Patricia
Foresti, María Laura
Errea, María Inés
author_role author
author2 Montoya Rojo, Ursula Maria
Cerrutti, Patricia
Foresti, María Laura
Errea, María Inés
author2_role author
author
author
author
dc.subject.none.fl_str_mv ADSORPTION
BREAKTHROUGH CURVE
CARBOXYMETHYLATED BACTERIAL CELLULOSE
ION EXCHANGER
LEAD
topic ADSORPTION
BREAKTHROUGH CURVE
CARBOXYMETHYLATED BACTERIAL CELLULOSE
ION EXCHANGER
LEAD
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Carboxymethylated bacterial cellulose (CMBC) was synthesized under controlled reaction condition to provide a material with a degree of substitution (DS) that guarantees that the characteristic water insolubility of cellulose is retained (DS = 0.17). The CMBC synthesized was fully characterized by conductometric titration, infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, thermogravimetric analysis and solubility assays. The suitability of the produced CMBC for lead removal from water was evaluated. Experimental isotherm data were fitted to different models of sorption isotherms: Langmuir, Freundlich, Dubinin-Radushkevich, and Frumkin, with Langmuir equation resulting in the best fit. Kinetic data were also adjusted to pseudo-first-order and pseudo-second-order models and results undoubtedly showed that the pseudo-second-order kinetic equation was the one that most appropriately described the lead adsorption of CMBC, indicating that lead is adsorbed on CMBC predominantly by chemical interaction. The breakthrough curve was fitted to different models: Bohart-Adams, Clark and Modified Dose-Response, being the Bohart-Adams equation the one that gave the best fit. Desorption studies were carried out in order to know the technical feasibility of the reuse of CMBC. Almost 96% of the retained lead was eluted in just 20 mL, and the CMBC lifetime was over 50 adsorption/desorption cycles. Overall, results obtained suggest that the CMBC herein synthesized may result in an alternative economic and environmentally friendly lead adsorbent for water treatment.
Fil: Rossi, Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto Tecnológico de Buenos Aires; Argentina
Fil: Montoya Rojo, Ursula Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Cerrutti, Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; Argentina
Fil: Foresti, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Errea, María Inés. Instituto Tecnológico de Buenos Aires; Argentina
description Carboxymethylated bacterial cellulose (CMBC) was synthesized under controlled reaction condition to provide a material with a degree of substitution (DS) that guarantees that the characteristic water insolubility of cellulose is retained (DS = 0.17). The CMBC synthesized was fully characterized by conductometric titration, infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, thermogravimetric analysis and solubility assays. The suitability of the produced CMBC for lead removal from water was evaluated. Experimental isotherm data were fitted to different models of sorption isotherms: Langmuir, Freundlich, Dubinin-Radushkevich, and Frumkin, with Langmuir equation resulting in the best fit. Kinetic data were also adjusted to pseudo-first-order and pseudo-second-order models and results undoubtedly showed that the pseudo-second-order kinetic equation was the one that most appropriately described the lead adsorption of CMBC, indicating that lead is adsorbed on CMBC predominantly by chemical interaction. The breakthrough curve was fitted to different models: Bohart-Adams, Clark and Modified Dose-Response, being the Bohart-Adams equation the one that gave the best fit. Desorption studies were carried out in order to know the technical feasibility of the reuse of CMBC. Almost 96% of the retained lead was eluted in just 20 mL, and the CMBC lifetime was over 50 adsorption/desorption cycles. Overall, results obtained suggest that the CMBC herein synthesized may result in an alternative economic and environmentally friendly lead adsorbent for water treatment.
publishDate 2018
dc.date.none.fl_str_mv 2018-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/93071
Rossi, Ezequiel; Montoya Rojo, Ursula Maria; Cerrutti, Patricia; Foresti, María Laura; Errea, María Inés; Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water; Elsevier; Journal of Environmental Chemical Engineering; 6; 6; 12-2018; 6844-6852
2213-3437
CONICET Digital
CONICET
url http://hdl.handle.net/11336/93071
identifier_str_mv Rossi, Ezequiel; Montoya Rojo, Ursula Maria; Cerrutti, Patricia; Foresti, María Laura; Errea, María Inés; Carboxymethylated bacterial cellulose: An environmentally friendly adsorbent for lead removal from water; Elsevier; Journal of Environmental Chemical Engineering; 6; 6; 12-2018; 6844-6852
2213-3437
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S221334371830664X
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2018.10.055
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
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eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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