Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes

Autores
Ruiz Varilla, Andrea M.; Baquero, Edwin A.; Silbestri, Gustavo Fabián; Gonzalez Arellano, Camino; de Jesús, Ernesto; Flores, Juan C.
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A series of water-soluble (NHC)Pt(0)(dvtms) and (NHC)Pt(0)(AE) complexes containing different sulfonated NHC ligands (dvtms = divinyltetramethyldisiloxane and AE = diallyl ether) are reported. The dvtms compounds have been found to be quite robust and to display some conformational rigidity, whereas their AE counterparts are less stable and more flexible. The catalytic evaluation of these complexes in the hydrosilylation of alkynes in water revealed no benefits in favor of the complexes containing the more labile spectator diene (AE), and a fairly regular catalytic behavior for all complexes that restricts the location of the sulfonate group to the proximity of the metal site.
Fil: Ruiz Varilla, Andrea M.. Universidad de Alcala. Facultad de Ciencias; España
Fil: Baquero, Edwin A.. Universidad de Alcala. Facultad de Ciencias; España
Fil: Silbestri, Gustavo Fabián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina
Fil: Gonzalez Arellano, Camino. Universidad de Alcala. Facultad de Ciencias; España
Fil: de Jesús, Ernesto. Universidad de Alcala. Facultad de Ciencias; España
Fil: Flores, Juan C.. Universidad de Alcala. Facultad de Ciencias; España
Materia
Nhc-Pt
Sulfonated Nhc
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/4713
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/4713
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexesRuiz Varilla, Andrea M.Baquero, Edwin A.Silbestri, Gustavo FabiánGonzalez Arellano, Caminode Jesús, ErnestoFlores, Juan C.Nhc-PtSulfonated Nhchttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A series of water-soluble (NHC)Pt(0)(dvtms) and (NHC)Pt(0)(AE) complexes containing different sulfonated NHC ligands (dvtms = divinyltetramethyldisiloxane and AE = diallyl ether) are reported. The dvtms compounds have been found to be quite robust and to display some conformational rigidity, whereas their AE counterparts are less stable and more flexible. The catalytic evaluation of these complexes in the hydrosilylation of alkynes in water revealed no benefits in favor of the complexes containing the more labile spectator diene (AE), and a fairly regular catalytic behavior for all complexes that restricts the location of the sulfonate group to the proximity of the metal site.Fil: Ruiz Varilla, Andrea M.. Universidad de Alcala. Facultad de Ciencias; EspañaFil: Baquero, Edwin A.. Universidad de Alcala. Facultad de Ciencias; EspañaFil: Silbestri, Gustavo Fabián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; ArgentinaFil: Gonzalez Arellano, Camino. Universidad de Alcala. Facultad de Ciencias; EspañaFil: de Jesús, Ernesto. Universidad de Alcala. Facultad de Ciencias; EspañaFil: Flores, Juan C.. Universidad de Alcala. Facultad de Ciencias; EspañaRoyal Society Of Chemistry2015-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/4713Ruiz Varilla, Andrea M.; Baquero, Edwin A.; Silbestri, Gustavo Fabián; Gonzalez Arellano, Camino; de Jesús, Ernesto; et al.; Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes; Royal Society Of Chemistry; Dalton Transactions; 44; 42; 8-2015; 18360-183691477-9226enginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2015/DT/C5DT02622A#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/c5dt02622ainfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:15:57Zoai:ri.conicet.gov.ar:11336/4713instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:15:58.25CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes
title Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes
spellingShingle Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes
Ruiz Varilla, Andrea M.
Nhc-Pt
Sulfonated Nhc
title_short Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes
title_full Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes
title_fullStr Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes
title_full_unstemmed Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes
title_sort Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes
dc.creator.none.fl_str_mv Ruiz Varilla, Andrea M.
Baquero, Edwin A.
Silbestri, Gustavo Fabián
Gonzalez Arellano, Camino
de Jesús, Ernesto
Flores, Juan C.
author Ruiz Varilla, Andrea M.
author_facet Ruiz Varilla, Andrea M.
Baquero, Edwin A.
Silbestri, Gustavo Fabián
Gonzalez Arellano, Camino
de Jesús, Ernesto
Flores, Juan C.
author_role author
author2 Baquero, Edwin A.
Silbestri, Gustavo Fabián
Gonzalez Arellano, Camino
de Jesús, Ernesto
Flores, Juan C.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Nhc-Pt
Sulfonated Nhc
topic Nhc-Pt
Sulfonated Nhc
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A series of water-soluble (NHC)Pt(0)(dvtms) and (NHC)Pt(0)(AE) complexes containing different sulfonated NHC ligands (dvtms = divinyltetramethyldisiloxane and AE = diallyl ether) are reported. The dvtms compounds have been found to be quite robust and to display some conformational rigidity, whereas their AE counterparts are less stable and more flexible. The catalytic evaluation of these complexes in the hydrosilylation of alkynes in water revealed no benefits in favor of the complexes containing the more labile spectator diene (AE), and a fairly regular catalytic behavior for all complexes that restricts the location of the sulfonate group to the proximity of the metal site.
Fil: Ruiz Varilla, Andrea M.. Universidad de Alcala. Facultad de Ciencias; España
Fil: Baquero, Edwin A.. Universidad de Alcala. Facultad de Ciencias; España
Fil: Silbestri, Gustavo Fabián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina
Fil: Gonzalez Arellano, Camino. Universidad de Alcala. Facultad de Ciencias; España
Fil: de Jesús, Ernesto. Universidad de Alcala. Facultad de Ciencias; España
Fil: Flores, Juan C.. Universidad de Alcala. Facultad de Ciencias; España
description A series of water-soluble (NHC)Pt(0)(dvtms) and (NHC)Pt(0)(AE) complexes containing different sulfonated NHC ligands (dvtms = divinyltetramethyldisiloxane and AE = diallyl ether) are reported. The dvtms compounds have been found to be quite robust and to display some conformational rigidity, whereas their AE counterparts are less stable and more flexible. The catalytic evaluation of these complexes in the hydrosilylation of alkynes in water revealed no benefits in favor of the complexes containing the more labile spectator diene (AE), and a fairly regular catalytic behavior for all complexes that restricts the location of the sulfonate group to the proximity of the metal site.
publishDate 2015
dc.date.none.fl_str_mv 2015-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/4713
Ruiz Varilla, Andrea M.; Baquero, Edwin A.; Silbestri, Gustavo Fabián; Gonzalez Arellano, Camino; de Jesús, Ernesto; et al.; Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes; Royal Society Of Chemistry; Dalton Transactions; 44; 42; 8-2015; 18360-18369
1477-9226
url http://hdl.handle.net/11336/4713
identifier_str_mv Ruiz Varilla, Andrea M.; Baquero, Edwin A.; Silbestri, Gustavo Fabián; Gonzalez Arellano, Camino; de Jesús, Ernesto; et al.; Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η4-diene) platinum(0) complexes; Royal Society Of Chemistry; Dalton Transactions; 44; 42; 8-2015; 18360-18369
1477-9226
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2015/DT/C5DT02622A#!divAbstract
info:eu-repo/semantics/altIdentifier/doi/10.1039/c5dt02622a
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society Of Chemistry
publisher.none.fl_str_mv Royal Society Of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083307711758336
score 13.216834

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