Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence

Autores
Martinez, Ramon Alberto; Fechner, Diana Corina; Ruiz, Daniel; Vazquez, Antonio
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In textile industries effluents we can be found surfactants of various characteristics, alkalis, and sulfides partially or totally hydrolyzed dyes, among other things, which are used as dyeing material. This study aims to create an unconventional tool to evaluate the degree of environmental contamination as a consequence of the discharge of these compounds that constitute the effluents of the textile industry prior to its final disposal, with or without purification systems, following one or more of its constituents possessing fluorescent properties. It was designed a technique to determine and quantify surfactant compounds used in textile industry. The conditions of the technique by HPLC with fluorescence detector designed are: Mobile phase: H3CCN/NaClO4 (12.3 g/L) 65:35; flow: 1 mL/min; column: Waters Symmetry C18 5 μm; 4.6 x 150 mm; pre-column: Kromasil 100-5C18; λex: 225 nm; λem: 290 nm. It was found that the commercial textile surfactants analyzed have matching constituents, but also have some unique characteristics that identify and discriminate. Surfactants Tensia MA, Unipal DLE and Croscolor Miro have their own fluorescent compounds, which will be used as contamination indicators to monitor or evaluate the environmental impact of textile effluents on water bodies receiving.
Fil: Martinez, Ramon Alberto. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina
Fil: Fechner, Diana Corina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste; Argentina. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina
Fil: Ruiz, Daniel. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina
Fil: Vazquez, Antonio. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina
Materia
EFFLUENT
OXIDATION
REMEDIATION
TEXTILE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/64409
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-FluorescenceMartinez, Ramon AlbertoFechner, Diana CorinaRuiz, DanielVazquez, AntonioEFFLUENTOXIDATIONREMEDIATIONTEXTILEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In textile industries effluents we can be found surfactants of various characteristics, alkalis, and sulfides partially or totally hydrolyzed dyes, among other things, which are used as dyeing material. This study aims to create an unconventional tool to evaluate the degree of environmental contamination as a consequence of the discharge of these compounds that constitute the effluents of the textile industry prior to its final disposal, with or without purification systems, following one or more of its constituents possessing fluorescent properties. It was designed a technique to determine and quantify surfactant compounds used in textile industry. The conditions of the technique by HPLC with fluorescence detector designed are: Mobile phase: H3CCN/NaClO4 (12.3 g/L) 65:35; flow: 1 mL/min; column: Waters Symmetry C18 5 μm; 4.6 x 150 mm; pre-column: Kromasil 100-5C18; λex: 225 nm; λem: 290 nm. It was found that the commercial textile surfactants analyzed have matching constituents, but also have some unique characteristics that identify and discriminate. Surfactants Tensia MA, Unipal DLE and Croscolor Miro have their own fluorescent compounds, which will be used as contamination indicators to monitor or evaluate the environmental impact of textile effluents on water bodies receiving.Fil: Martinez, Ramon Alberto. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; ArgentinaFil: Fechner, Diana Corina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste; Argentina. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; ArgentinaFil: Ruiz, Daniel. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; ArgentinaFil: Vazquez, Antonio. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; ArgentinaScience Domain International2017-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/64409Martinez, Ramon Alberto; Fechner, Diana Corina; Ruiz, Daniel; Vazquez, Antonio; Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence; Science Domain International; International Research Journal of Pure and Applied Chemistry; 14; 4; 1-2017; 1-102231-3443CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.9734/IRJPAC/2017/36636info:eu-repo/semantics/altIdentifier/url/http://www.sciencedomain.org/abstract/21205info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:12:05Zoai:ri.conicet.gov.ar:11336/64409instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:12:05.945CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence
title Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence
spellingShingle Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence
Martinez, Ramon Alberto
EFFLUENT
OXIDATION
REMEDIATION
TEXTILE
title_short Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence
title_full Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence
title_fullStr Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence
title_full_unstemmed Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence
title_sort Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence
dc.creator.none.fl_str_mv Martinez, Ramon Alberto
Fechner, Diana Corina
Ruiz, Daniel
Vazquez, Antonio
author Martinez, Ramon Alberto
author_facet Martinez, Ramon Alberto
Fechner, Diana Corina
Ruiz, Daniel
Vazquez, Antonio
author_role author
author2 Fechner, Diana Corina
Ruiz, Daniel
Vazquez, Antonio
author2_role author
author
author
dc.subject.none.fl_str_mv EFFLUENT
OXIDATION
REMEDIATION
TEXTILE
topic EFFLUENT
OXIDATION
REMEDIATION
TEXTILE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In textile industries effluents we can be found surfactants of various characteristics, alkalis, and sulfides partially or totally hydrolyzed dyes, among other things, which are used as dyeing material. This study aims to create an unconventional tool to evaluate the degree of environmental contamination as a consequence of the discharge of these compounds that constitute the effluents of the textile industry prior to its final disposal, with or without purification systems, following one or more of its constituents possessing fluorescent properties. It was designed a technique to determine and quantify surfactant compounds used in textile industry. The conditions of the technique by HPLC with fluorescence detector designed are: Mobile phase: H3CCN/NaClO4 (12.3 g/L) 65:35; flow: 1 mL/min; column: Waters Symmetry C18 5 μm; 4.6 x 150 mm; pre-column: Kromasil 100-5C18; λex: 225 nm; λem: 290 nm. It was found that the commercial textile surfactants analyzed have matching constituents, but also have some unique characteristics that identify and discriminate. Surfactants Tensia MA, Unipal DLE and Croscolor Miro have their own fluorescent compounds, which will be used as contamination indicators to monitor or evaluate the environmental impact of textile effluents on water bodies receiving.
Fil: Martinez, Ramon Alberto. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina
Fil: Fechner, Diana Corina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste; Argentina. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina
Fil: Ruiz, Daniel. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina
Fil: Vazquez, Antonio. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura; Argentina
description In textile industries effluents we can be found surfactants of various characteristics, alkalis, and sulfides partially or totally hydrolyzed dyes, among other things, which are used as dyeing material. This study aims to create an unconventional tool to evaluate the degree of environmental contamination as a consequence of the discharge of these compounds that constitute the effluents of the textile industry prior to its final disposal, with or without purification systems, following one or more of its constituents possessing fluorescent properties. It was designed a technique to determine and quantify surfactant compounds used in textile industry. The conditions of the technique by HPLC with fluorescence detector designed are: Mobile phase: H3CCN/NaClO4 (12.3 g/L) 65:35; flow: 1 mL/min; column: Waters Symmetry C18 5 μm; 4.6 x 150 mm; pre-column: Kromasil 100-5C18; λex: 225 nm; λem: 290 nm. It was found that the commercial textile surfactants analyzed have matching constituents, but also have some unique characteristics that identify and discriminate. Surfactants Tensia MA, Unipal DLE and Croscolor Miro have their own fluorescent compounds, which will be used as contamination indicators to monitor or evaluate the environmental impact of textile effluents on water bodies receiving.
publishDate 2017
dc.date.none.fl_str_mv 2017-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/64409
Martinez, Ramon Alberto; Fechner, Diana Corina; Ruiz, Daniel; Vazquez, Antonio; Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence; Science Domain International; International Research Journal of Pure and Applied Chemistry; 14; 4; 1-2017; 1-10
2231-3443
CONICET Digital
CONICET
url http://hdl.handle.net/11336/64409
identifier_str_mv Martinez, Ramon Alberto; Fechner, Diana Corina; Ruiz, Daniel; Vazquez, Antonio; Analytical Method for the Determination of Surfactants with Fluorescent Activity, Present in Liquid Effluents from Textile Industries, by HPLC-Fluorescence; Science Domain International; International Research Journal of Pure and Applied Chemistry; 14; 4; 1-2017; 1-10
2231-3443
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.9734/IRJPAC/2017/36636
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedomain.org/abstract/21205
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Science Domain International
publisher.none.fl_str_mv Science Domain International
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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