Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde

Autores
Shir, Guojun; Franzke, Thomas; Sanchez, Miguel Dario; Xia, Wei; Weis, Frederik; Seipenbusch, Martin; Kasper, Gerhard; Muhler, Martin
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
β‐MoO3/α‐Fe2O3 catalysts synthesized by chemical vapor deposition exhibit a uniform shell–core structure. The structure of the metastable β‐MoO3 film is retained even after calcination in air at 873 K, owing to strong Mo_O_Fe links at the interface. The shell–core β‐MoO3/α‐Fe2O3 catalysts are much more active than, and comparably selective to, the reference α‐MoO3 catalyst in the selective oxidation of methanol to formaldehyde.
Fil: Shir, Guojun. Ruhr University Bochum; Alemania
Fil: Franzke, Thomas. Ruhr University Bochum; Alemania
Fil: Sanchez, Miguel Dario. Universidad Nacional del Sur. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina. Ruhr University Bochum; Alemania
Fil: Xia, Wei. Ruhr University Bochum; Alemania
Fil: Weis, Frederik. Karlsruhe Institute Of Technology; Alemania
Fil: Seipenbusch, Martin. Karlsruhe Institute Of Technology; Alemania
Fil: Kasper, Gerhard. Karlsruhe Institute Of Technology; Alemania. Ruhr University Bochum; Alemania
Fil: Muhler, Martin. Ruhr University Bochum; Alemania
Materia
CHEMICAL VAPOR DEPOSITION
IRON
MOLYBDENUM
METASTABLE COMPOUNDS
OXIDATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/102598
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/102598
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to FormaldehydeShir, GuojunFranzke, ThomasSanchez, Miguel DarioXia, WeiWeis, FrederikSeipenbusch, MartinKasper, GerhardMuhler, MartinCHEMICAL VAPOR DEPOSITIONIRONMOLYBDENUMMETASTABLE COMPOUNDSOXIDATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1β‐MoO3/α‐Fe2O3 catalysts synthesized by chemical vapor deposition exhibit a uniform shell–core structure. The structure of the metastable β‐MoO3 film is retained even after calcination in air at 873 K, owing to strong Mo_O_Fe links at the interface. The shell–core β‐MoO3/α‐Fe2O3 catalysts are much more active than, and comparably selective to, the reference α‐MoO3 catalyst in the selective oxidation of methanol to formaldehyde.Fil: Shir, Guojun. Ruhr University Bochum; AlemaniaFil: Franzke, Thomas. Ruhr University Bochum; AlemaniaFil: Sanchez, Miguel Dario. Universidad Nacional del Sur. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina. Ruhr University Bochum; AlemaniaFil: Xia, Wei. Ruhr University Bochum; AlemaniaFil: Weis, Frederik. Karlsruhe Institute Of Technology; AlemaniaFil: Seipenbusch, Martin. Karlsruhe Institute Of Technology; AlemaniaFil: Kasper, Gerhard. Karlsruhe Institute Of Technology; Alemania. Ruhr University Bochum; AlemaniaFil: Muhler, Martin. Ruhr University Bochum; AlemaniaWiley VCH Verlag2012-04-30info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/102598Shir, Guojun; Franzke, Thomas; Sanchez, Miguel Dario; Xia, Wei; Weis, Frederik; et al.; Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde; Wiley VCH Verlag; Chemcatchem; 4; 6; 30-4-2012; 760-7651867-3880CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/cctc.201200127info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201200127info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:36:52Zoai:ri.conicet.gov.ar:11336/102598instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:36:52.948CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde
title Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde
spellingShingle Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde
Shir, Guojun
CHEMICAL VAPOR DEPOSITION
IRON
MOLYBDENUM
METASTABLE COMPOUNDS
OXIDATION
title_short Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde
title_full Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde
title_fullStr Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde
title_full_unstemmed Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde
title_sort Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde
dc.creator.none.fl_str_mv Shir, Guojun
Franzke, Thomas
Sanchez, Miguel Dario
Xia, Wei
Weis, Frederik
Seipenbusch, Martin
Kasper, Gerhard
Muhler, Martin
author Shir, Guojun
author_facet Shir, Guojun
Franzke, Thomas
Sanchez, Miguel Dario
Xia, Wei
Weis, Frederik
Seipenbusch, Martin
Kasper, Gerhard
Muhler, Martin
author_role author
author2 Franzke, Thomas
Sanchez, Miguel Dario
Xia, Wei
Weis, Frederik
Seipenbusch, Martin
Kasper, Gerhard
Muhler, Martin
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv CHEMICAL VAPOR DEPOSITION
IRON
MOLYBDENUM
METASTABLE COMPOUNDS
OXIDATION
topic CHEMICAL VAPOR DEPOSITION
IRON
MOLYBDENUM
METASTABLE COMPOUNDS
OXIDATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv β‐MoO3/α‐Fe2O3 catalysts synthesized by chemical vapor deposition exhibit a uniform shell–core structure. The structure of the metastable β‐MoO3 film is retained even after calcination in air at 873 K, owing to strong Mo_O_Fe links at the interface. The shell–core β‐MoO3/α‐Fe2O3 catalysts are much more active than, and comparably selective to, the reference α‐MoO3 catalyst in the selective oxidation of methanol to formaldehyde.
Fil: Shir, Guojun. Ruhr University Bochum; Alemania
Fil: Franzke, Thomas. Ruhr University Bochum; Alemania
Fil: Sanchez, Miguel Dario. Universidad Nacional del Sur. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina. Ruhr University Bochum; Alemania
Fil: Xia, Wei. Ruhr University Bochum; Alemania
Fil: Weis, Frederik. Karlsruhe Institute Of Technology; Alemania
Fil: Seipenbusch, Martin. Karlsruhe Institute Of Technology; Alemania
Fil: Kasper, Gerhard. Karlsruhe Institute Of Technology; Alemania. Ruhr University Bochum; Alemania
Fil: Muhler, Martin. Ruhr University Bochum; Alemania
description β‐MoO3/α‐Fe2O3 catalysts synthesized by chemical vapor deposition exhibit a uniform shell–core structure. The structure of the metastable β‐MoO3 film is retained even after calcination in air at 873 K, owing to strong Mo_O_Fe links at the interface. The shell–core β‐MoO3/α‐Fe2O3 catalysts are much more active than, and comparably selective to, the reference α‐MoO3 catalyst in the selective oxidation of methanol to formaldehyde.
publishDate 2012
dc.date.none.fl_str_mv 2012-04-30
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/102598
Shir, Guojun; Franzke, Thomas; Sanchez, Miguel Dario; Xia, Wei; Weis, Frederik; et al.; Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde; Wiley VCH Verlag; Chemcatchem; 4; 6; 30-4-2012; 760-765
1867-3880
CONICET Digital
CONICET
url http://hdl.handle.net/11336/102598
identifier_str_mv Shir, Guojun; Franzke, Thomas; Sanchez, Miguel Dario; Xia, Wei; Weis, Frederik; et al.; Thin‐film β‐MoO3 Supported on α‐Fe2O3 as a Shell–Core Catalyst for the Selective Oxidation of Methanol to Formaldehyde; Wiley VCH Verlag; Chemcatchem; 4; 6; 30-4-2012; 760-765
1867-3880
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/cctc.201200127
info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201200127
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846082837333147648
score 13.22299

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