FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO

Autores
Ferreira, María Luján; Galland, G. B.; Damiani, Daniel Eduardo; Villar, Marcelo Armando
Año de publicación
2001
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This article reports the results of propylene/alfa-olefin copolymerization and propylene/ethylene/alfa-olefin terpolymerization using low concentrations(less than 5 mol %) of long alfa-olefins such as 1-octene, 1-decene, and 1-dodecene. Kinetics data are presented and discussed. The highest activity was found with the longest alfa-olefin studied (1-dodecene). A possible explanation is proposed for this and other characteristics of the polymers obtained. The effect of low-ethylene contents (4 mol% in the gas phase) on the copolymerization of propylene/alfa-olefins was also examined. The polymers synthesized were characterized by 13CNMR, gel permeation chromatography, DSC, Fourier transform infrared spectroscopy, and wide-angle X-ray scattering.
Fil: Ferreira, María Luján. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Galland, G. B.. Universidade Federal do Rio Grande do Sul; Brasil
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Propylene copolymerization
Propylene terpolymerization
Metallocene
Long-chain a-olefins polymerization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/101425
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/101425
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAOFerreira, María LujánGalland, G. B.Damiani, Daniel EduardoVillar, Marcelo ArmandoPropylene copolymerizationPropylene terpolymerizationMetalloceneLong-chain a-olefins polymerizationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This article reports the results of propylene/alfa-olefin copolymerization and propylene/ethylene/alfa-olefin terpolymerization using low concentrations(less than 5 mol %) of long alfa-olefins such as 1-octene, 1-decene, and 1-dodecene. Kinetics data are presented and discussed. The highest activity was found with the longest alfa-olefin studied (1-dodecene). A possible explanation is proposed for this and other characteristics of the polymers obtained. The effect of low-ethylene contents (4 mol% in the gas phase) on the copolymerization of propylene/alfa-olefins was also examined. The polymers synthesized were characterized by 13CNMR, gel permeation chromatography, DSC, Fourier transform infrared spectroscopy, and wide-angle X-ray scattering.Fil: Ferreira, María Luján. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Galland, G. B.. Universidade Federal do Rio Grande do Sul; BrasilFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaJohn Wiley & Sons Inc2001-04-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/101425Ferreira, María Luján; Galland, G. B.; Damiani, Daniel Eduardo; Villar, Marcelo Armando; FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO; John Wiley & Sons Inc; Journal of Polymer Science Part A: Polymer Chemistry; 39; 12; 26-4-2001; 2005-20180887-624XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/pola.1176info:eu-repo/semantics/altIdentifier/doi/10.1002/pola.1176info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:06:04Zoai:ri.conicet.gov.ar:11336/101425instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:06:04.343CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO
title FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO
spellingShingle FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO
Ferreira, María Luján
Propylene copolymerization
Propylene terpolymerization
Metallocene
Long-chain a-olefins polymerization
title_short FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO
title_full FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO
title_fullStr FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO
title_full_unstemmed FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO
title_sort FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO
dc.creator.none.fl_str_mv Ferreira, María Luján
Galland, G. B.
Damiani, Daniel Eduardo
Villar, Marcelo Armando
author Ferreira, María Luján
author_facet Ferreira, María Luján
Galland, G. B.
Damiani, Daniel Eduardo
Villar, Marcelo Armando
author_role author
author2 Galland, G. B.
Damiani, Daniel Eduardo
Villar, Marcelo Armando
author2_role author
author
author
dc.subject.none.fl_str_mv Propylene copolymerization
Propylene terpolymerization
Metallocene
Long-chain a-olefins polymerization
topic Propylene copolymerization
Propylene terpolymerization
Metallocene
Long-chain a-olefins polymerization
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This article reports the results of propylene/alfa-olefin copolymerization and propylene/ethylene/alfa-olefin terpolymerization using low concentrations(less than 5 mol %) of long alfa-olefins such as 1-octene, 1-decene, and 1-dodecene. Kinetics data are presented and discussed. The highest activity was found with the longest alfa-olefin studied (1-dodecene). A possible explanation is proposed for this and other characteristics of the polymers obtained. The effect of low-ethylene contents (4 mol% in the gas phase) on the copolymerization of propylene/alfa-olefins was also examined. The polymers synthesized were characterized by 13CNMR, gel permeation chromatography, DSC, Fourier transform infrared spectroscopy, and wide-angle X-ray scattering.
Fil: Ferreira, María Luján. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Galland, G. B.. Universidade Federal do Rio Grande do Sul; Brasil
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Villar, Marcelo Armando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description This article reports the results of propylene/alfa-olefin copolymerization and propylene/ethylene/alfa-olefin terpolymerization using low concentrations(less than 5 mol %) of long alfa-olefins such as 1-octene, 1-decene, and 1-dodecene. Kinetics data are presented and discussed. The highest activity was found with the longest alfa-olefin studied (1-dodecene). A possible explanation is proposed for this and other characteristics of the polymers obtained. The effect of low-ethylene contents (4 mol% in the gas phase) on the copolymerization of propylene/alfa-olefins was also examined. The polymers synthesized were characterized by 13CNMR, gel permeation chromatography, DSC, Fourier transform infrared spectroscopy, and wide-angle X-ray scattering.
publishDate 2001
dc.date.none.fl_str_mv 2001-04-26
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/101425
Ferreira, María Luján; Galland, G. B.; Damiani, Daniel Eduardo; Villar, Marcelo Armando; FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO; John Wiley & Sons Inc; Journal of Polymer Science Part A: Polymer Chemistry; 39; 12; 26-4-2001; 2005-2018
0887-624X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/101425
identifier_str_mv Ferreira, María Luján; Galland, G. B.; Damiani, Daniel Eduardo; Villar, Marcelo Armando; FTIR, 13C NMR, and GPC analysis of high‐propylene content co‐ and terpolymers with ethylene and higher α‐olefins synthesized with EtInd2ZrCl2/MAO; John Wiley & Sons Inc; Journal of Polymer Science Part A: Polymer Chemistry; 39; 12; 26-4-2001; 2005-2018
0887-624X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/pola.1176
info:eu-repo/semantics/altIdentifier/doi/10.1002/pola.1176
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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