Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions

Autores
Torres, Gerardo Carlos; Manuale, Débora Laura; Benitez, Viviana Monica; Vera, Carlos Roman; Yori, Juan Carlos
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A study of the different hydrocarbon reactions over Ni doped WO3-ZrO2 catalysts was performed. Ni was found as NiO at low Ni concentration while at high Ni concentrations a small fraction was present as a metal. For both cases, Ni strongly modified total acidity and concentration of strong acid sites. In the cyclohexane dehydrogenation reaction, Ni addition promotes both benzene and methyl cyclopentane production. The hydroconversion activity (n-butane and n-octane) increases with the augment of total acidity produced by Ni. The selectivity to reaction products is modified according to the acid strength distribution changes produced by Ni addition.
Fil: Torres, Gerardo Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Manuale, Débora Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
tunsgten
zirconia
hydroisomerization
nickel
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/53045
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon ReactionsTorres, Gerardo CarlosManuale, Débora LauraBenitez, Viviana MonicaVera, Carlos RomanYori, Juan Carlostunsgtenzirconiahydroisomerizationnickelhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A study of the different hydrocarbon reactions over Ni doped WO3-ZrO2 catalysts was performed. Ni was found as NiO at low Ni concentration while at high Ni concentrations a small fraction was present as a metal. For both cases, Ni strongly modified total acidity and concentration of strong acid sites. In the cyclohexane dehydrogenation reaction, Ni addition promotes both benzene and methyl cyclopentane production. The hydroconversion activity (n-butane and n-octane) increases with the augment of total acidity produced by Ni. The selectivity to reaction products is modified according to the acid strength distribution changes produced by Ni addition.Fil: Torres, Gerardo Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Manuale, Débora Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaSociedade Brasileira de Química2012-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/53045Torres, Gerardo Carlos; Manuale, Débora Laura; Benitez, Viviana Monica; Vera, Carlos Roman; Yori, Juan Carlos; Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions; Sociedade Brasileira de Química; Química Nova; 35; 4-2012; 748-7540100-40421678-7064CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1590/S0100-40422012000400018info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:57:06Zoai:ri.conicet.gov.ar:11336/53045instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:57:07.075CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions
title Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions
spellingShingle Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions
Torres, Gerardo Carlos
tunsgten
zirconia
hydroisomerization
nickel
title_short Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions
title_full Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions
title_fullStr Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions
title_full_unstemmed Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions
title_sort Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions
dc.creator.none.fl_str_mv Torres, Gerardo Carlos
Manuale, Débora Laura
Benitez, Viviana Monica
Vera, Carlos Roman
Yori, Juan Carlos
author Torres, Gerardo Carlos
author_facet Torres, Gerardo Carlos
Manuale, Débora Laura
Benitez, Viviana Monica
Vera, Carlos Roman
Yori, Juan Carlos
author_role author
author2 Manuale, Débora Laura
Benitez, Viviana Monica
Vera, Carlos Roman
Yori, Juan Carlos
author2_role author
author
author
author
dc.subject.none.fl_str_mv tunsgten
zirconia
hydroisomerization
nickel
topic tunsgten
zirconia
hydroisomerization
nickel
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A study of the different hydrocarbon reactions over Ni doped WO3-ZrO2 catalysts was performed. Ni was found as NiO at low Ni concentration while at high Ni concentrations a small fraction was present as a metal. For both cases, Ni strongly modified total acidity and concentration of strong acid sites. In the cyclohexane dehydrogenation reaction, Ni addition promotes both benzene and methyl cyclopentane production. The hydroconversion activity (n-butane and n-octane) increases with the augment of total acidity produced by Ni. The selectivity to reaction products is modified according to the acid strength distribution changes produced by Ni addition.
Fil: Torres, Gerardo Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Manuale, Débora Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description A study of the different hydrocarbon reactions over Ni doped WO3-ZrO2 catalysts was performed. Ni was found as NiO at low Ni concentration while at high Ni concentrations a small fraction was present as a metal. For both cases, Ni strongly modified total acidity and concentration of strong acid sites. In the cyclohexane dehydrogenation reaction, Ni addition promotes both benzene and methyl cyclopentane production. The hydroconversion activity (n-butane and n-octane) increases with the augment of total acidity produced by Ni. The selectivity to reaction products is modified according to the acid strength distribution changes produced by Ni addition.
publishDate 2012
dc.date.none.fl_str_mv 2012-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/53045
Torres, Gerardo Carlos; Manuale, Débora Laura; Benitez, Viviana Monica; Vera, Carlos Roman; Yori, Juan Carlos; Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions; Sociedade Brasileira de Química; Química Nova; 35; 4-2012; 748-754
0100-4042
1678-7064
CONICET Digital
CONICET
url http://hdl.handle.net/11336/53045
identifier_str_mv Torres, Gerardo Carlos; Manuale, Débora Laura; Benitez, Viviana Monica; Vera, Carlos Roman; Yori, Juan Carlos; Modification of the Performance of Wo3-Zro2 Catalysts by Metal Addition in Hydrocarbon Reactions; Sociedade Brasileira de Química; Química Nova; 35; 4-2012; 748-754
0100-4042
1678-7064
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1590/S0100-40422012000400018
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269440835584000
score 13.13397

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