The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates

Autores
Rodríguez, Juan; Onna, Diego Ariel; Sánchez, Luis; Marchi, María Claudia; Candal, Roberto Jorge; Ponce, Silvia; Bilmes, Sara A.
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Spray pyrolysis (SP) and spray-gel (SG) techniques were used to deposit ZnO seeds on Fluor doped tin oxide glasses (FTO), heated at 350 ◦C or 130 ◦C, and PET heated at 90 ◦C. The effect of seeding on the morphology and wettability of ZnO nanorods (NRs) films grown by wet chemical methods was analyzed. The morphology and wettability of ZnO NRs films depend on the seeding process. SP seeds formed from zinc acetate dissolved in water ethanol mixtures yield vertically aligned ZnO NRs, whose diameters and dispersion size are determined by the ethanol/water ratio in the precursor solution. SG seeds formed from a methanol ZnO sol produce a ring patterned distribution on the FTO substrate. The drying of ZnO sol drops impinging on the substrate produces high density of seeds along a ring yielding textured films with NRs vertically oriented on the rings and multi-oriented outside them. This effect was not observed when ZnO NRs grown onto the ZnO/PET substrate, however rod diameter is related with the density of seeds. This way to controlthe density and diameter of NRs deposited onto a substrate modify the wettability and opens new possibilities for the design oftailored nanomaterials for photochemical applications. Both type of NRs films showed a strong luminescence emission in the UV and in the blue, associated with surface and intrinsic defects.
Fil: Rodríguez, Juan. Universidad Nacional de Ingeniería. Facultad de Ciencias; Perú;
Fil: Onna, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Sánchez, Luis. Universidad Nacional de Ingeniería; Perú
Fil: Marchi, María Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Microscopías Avanzadas; Argentina
Fil: Candal, Roberto Jorge. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Ponce, Silvia. Universidad de Lima; Perú
Fil: Bilmes, Sara A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
NANORODS
SPRAY PYROLYSIS
SPRAY-GEL
ZNO
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2362
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/2362
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling The role of seeding in the morphology and wettability of ZnO nanorods films on different substratesRodríguez, JuanOnna, Diego ArielSánchez, LuisMarchi, María ClaudiaCandal, Roberto JorgePonce, SilviaBilmes, Sara A.NANORODSSPRAY PYROLYSISSPRAY-GELZNOhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Spray pyrolysis (SP) and spray-gel (SG) techniques were used to deposit ZnO seeds on Fluor doped tin oxide glasses (FTO), heated at 350 ◦C or 130 ◦C, and PET heated at 90 ◦C. The effect of seeding on the morphology and wettability of ZnO nanorods (NRs) films grown by wet chemical methods was analyzed. The morphology and wettability of ZnO NRs films depend on the seeding process. SP seeds formed from zinc acetate dissolved in water ethanol mixtures yield vertically aligned ZnO NRs, whose diameters and dispersion size are determined by the ethanol/water ratio in the precursor solution. SG seeds formed from a methanol ZnO sol produce a ring patterned distribution on the FTO substrate. The drying of ZnO sol drops impinging on the substrate produces high density of seeds along a ring yielding textured films with NRs vertically oriented on the rings and multi-oriented outside them. This effect was not observed when ZnO NRs grown onto the ZnO/PET substrate, however rod diameter is related with the density of seeds. This way to controlthe density and diameter of NRs deposited onto a substrate modify the wettability and opens new possibilities for the design oftailored nanomaterials for photochemical applications. Both type of NRs films showed a strong luminescence emission in the UV and in the blue, associated with surface and intrinsic defects.Fil: Rodríguez, Juan. Universidad Nacional de Ingeniería. Facultad de Ciencias; Perú;Fil: Onna, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Sánchez, Luis. Universidad Nacional de Ingeniería; PerúFil: Marchi, María Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Microscopías Avanzadas; ArgentinaFil: Candal, Roberto Jorge. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Ponce, Silvia. Universidad de Lima; PerúFil: Bilmes, Sara A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaElsevier Science2013-08-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2362Rodríguez, Juan; Onna, Diego Ariel; Sánchez, Luis; Marchi, María Claudia; Candal, Roberto Jorge; et al.; The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates; Elsevier Science; Applied Surface Science; 279; 15-8-2013; 197-2030169-4332enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2013.04.069info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0169433213007733info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:41:11Zoai:ri.conicet.gov.ar:11336/2362instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:41:11.676CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates
title The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates
spellingShingle The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates
Rodríguez, Juan
NANORODS
SPRAY PYROLYSIS
SPRAY-GEL
ZNO
title_short The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates
title_full The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates
title_fullStr The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates
title_full_unstemmed The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates
title_sort The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates
dc.creator.none.fl_str_mv Rodríguez, Juan
Onna, Diego Ariel
Sánchez, Luis
Marchi, María Claudia
Candal, Roberto Jorge
Ponce, Silvia
Bilmes, Sara A.
author Rodríguez, Juan
author_facet Rodríguez, Juan
Onna, Diego Ariel
Sánchez, Luis
Marchi, María Claudia
Candal, Roberto Jorge
Ponce, Silvia
Bilmes, Sara A.
author_role author
author2 Onna, Diego Ariel
Sánchez, Luis
Marchi, María Claudia
Candal, Roberto Jorge
Ponce, Silvia
Bilmes, Sara A.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv NANORODS
SPRAY PYROLYSIS
SPRAY-GEL
ZNO
topic NANORODS
SPRAY PYROLYSIS
SPRAY-GEL
ZNO
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Spray pyrolysis (SP) and spray-gel (SG) techniques were used to deposit ZnO seeds on Fluor doped tin oxide glasses (FTO), heated at 350 ◦C or 130 ◦C, and PET heated at 90 ◦C. The effect of seeding on the morphology and wettability of ZnO nanorods (NRs) films grown by wet chemical methods was analyzed. The morphology and wettability of ZnO NRs films depend on the seeding process. SP seeds formed from zinc acetate dissolved in water ethanol mixtures yield vertically aligned ZnO NRs, whose diameters and dispersion size are determined by the ethanol/water ratio in the precursor solution. SG seeds formed from a methanol ZnO sol produce a ring patterned distribution on the FTO substrate. The drying of ZnO sol drops impinging on the substrate produces high density of seeds along a ring yielding textured films with NRs vertically oriented on the rings and multi-oriented outside them. This effect was not observed when ZnO NRs grown onto the ZnO/PET substrate, however rod diameter is related with the density of seeds. This way to controlthe density and diameter of NRs deposited onto a substrate modify the wettability and opens new possibilities for the design oftailored nanomaterials for photochemical applications. Both type of NRs films showed a strong luminescence emission in the UV and in the blue, associated with surface and intrinsic defects.
Fil: Rodríguez, Juan. Universidad Nacional de Ingeniería. Facultad de Ciencias; Perú;
Fil: Onna, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Sánchez, Luis. Universidad Nacional de Ingeniería; Perú
Fil: Marchi, María Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Microscopías Avanzadas; Argentina
Fil: Candal, Roberto Jorge. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Ponce, Silvia. Universidad de Lima; Perú
Fil: Bilmes, Sara A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description Spray pyrolysis (SP) and spray-gel (SG) techniques were used to deposit ZnO seeds on Fluor doped tin oxide glasses (FTO), heated at 350 ◦C or 130 ◦C, and PET heated at 90 ◦C. The effect of seeding on the morphology and wettability of ZnO nanorods (NRs) films grown by wet chemical methods was analyzed. The morphology and wettability of ZnO NRs films depend on the seeding process. SP seeds formed from zinc acetate dissolved in water ethanol mixtures yield vertically aligned ZnO NRs, whose diameters and dispersion size are determined by the ethanol/water ratio in the precursor solution. SG seeds formed from a methanol ZnO sol produce a ring patterned distribution on the FTO substrate. The drying of ZnO sol drops impinging on the substrate produces high density of seeds along a ring yielding textured films with NRs vertically oriented on the rings and multi-oriented outside them. This effect was not observed when ZnO NRs grown onto the ZnO/PET substrate, however rod diameter is related with the density of seeds. This way to controlthe density and diameter of NRs deposited onto a substrate modify the wettability and opens new possibilities for the design oftailored nanomaterials for photochemical applications. Both type of NRs films showed a strong luminescence emission in the UV and in the blue, associated with surface and intrinsic defects.
publishDate 2013
dc.date.none.fl_str_mv 2013-08-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2362
Rodríguez, Juan; Onna, Diego Ariel; Sánchez, Luis; Marchi, María Claudia; Candal, Roberto Jorge; et al.; The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates; Elsevier Science; Applied Surface Science; 279; 15-8-2013; 197-203
0169-4332
url http://hdl.handle.net/11336/2362
identifier_str_mv Rodríguez, Juan; Onna, Diego Ariel; Sánchez, Luis; Marchi, María Claudia; Candal, Roberto Jorge; et al.; The role of seeding in the morphology and wettability of ZnO nanorods films on different substrates; Elsevier Science; Applied Surface Science; 279; 15-8-2013; 197-203
0169-4332
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2013.04.069
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0169433213007733
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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