Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach
- Autores
- Di Luca, Carla; Garcia, Jorge; Munoz, Macarena; Fasce, Laura Alejandra; de Pedro, Zahara M.; Casas, Jose A.
- Año de publicación
- 2024
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this study, kinetic models for the photo-Fenton oxidation of polystyrene nanoplastics(NPs) in water were developed, considering particles with decreasing diameters. Variousreaction parameters affecting the oxidation rate, such as particle size (140−909 nm), agitation speed (250−1000 rpm), and operating temperature (25 and 60 °C) were investigated. Oxidation progress was evaluated through turbidity measurements, TEM, and FTIR analysis, while leached intermediates were identified via Pyr-GC-MS and IC. Due to changes in NPs surface reactivity, the overall reaction rate was divided into two stages, following a freeradical mechanism. Using equations derived from the classic Shrinking Core Model, the oxidation of NPs was determined to proceed under chemical reaction control, with negligible mass transfer limitations. Additionally, the Prout-Tompkins model was found to accurately represent the degradation process. The proposed mechanisms and models provide valuable insights for describing and predicting the advanced oxidation of NPs under different operating conditions and treatment methods.
Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Garcia, Jorge. Universidad Autónoma de Madrid; España
Fil: Munoz, Macarena. Universidad Autónoma de Madrid; España
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: de Pedro, Zahara M.. Universidad Autónoma de Madrid; España
Fil: Casas, Jose A.. Universidad Autónoma de Madrid; España - Materia
-
PHOTO-FENTON
ADVANCED OXIDATION PROCESSES
NANOPLASTICS
SOLID FLUID KINETIC MODEL - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/265086
Ver los metadatos del registro completo
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Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approachDi Luca, CarlaGarcia, JorgeMunoz, MacarenaFasce, Laura Alejandrade Pedro, Zahara M.Casas, Jose A.PHOTO-FENTONADVANCED OXIDATION PROCESSESNANOPLASTICSSOLID FLUID KINETIC MODELhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this study, kinetic models for the photo-Fenton oxidation of polystyrene nanoplastics(NPs) in water were developed, considering particles with decreasing diameters. Variousreaction parameters affecting the oxidation rate, such as particle size (140−909 nm), agitation speed (250−1000 rpm), and operating temperature (25 and 60 °C) were investigated. Oxidation progress was evaluated through turbidity measurements, TEM, and FTIR analysis, while leached intermediates were identified via Pyr-GC-MS and IC. Due to changes in NPs surface reactivity, the overall reaction rate was divided into two stages, following a freeradical mechanism. Using equations derived from the classic Shrinking Core Model, the oxidation of NPs was determined to proceed under chemical reaction control, with negligible mass transfer limitations. Additionally, the Prout-Tompkins model was found to accurately represent the degradation process. The proposed mechanisms and models provide valuable insights for describing and predicting the advanced oxidation of NPs under different operating conditions and treatment methods.Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Garcia, Jorge. Universidad Autónoma de Madrid; EspañaFil: Munoz, Macarena. Universidad Autónoma de Madrid; EspañaFil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: de Pedro, Zahara M.. Universidad Autónoma de Madrid; EspañaFil: Casas, Jose A.. Universidad Autónoma de Madrid; EspañaElsevier Science2024-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/265086Di Luca, Carla; Garcia, Jorge; Munoz, Macarena; Fasce, Laura Alejandra; de Pedro, Zahara M.; et al.; Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach; Elsevier Science; Applied Catalysis B: Environmental; 362; 10-2024; 1-440926-3373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0926337324010658info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2024.124751info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:44Zoai:ri.conicet.gov.ar:11336/265086instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:44.948CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach |
title |
Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach |
spellingShingle |
Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach Di Luca, Carla PHOTO-FENTON ADVANCED OXIDATION PROCESSES NANOPLASTICS SOLID FLUID KINETIC MODEL |
title_short |
Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach |
title_full |
Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach |
title_fullStr |
Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach |
title_full_unstemmed |
Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach |
title_sort |
Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach |
dc.creator.none.fl_str_mv |
Di Luca, Carla Garcia, Jorge Munoz, Macarena Fasce, Laura Alejandra de Pedro, Zahara M. Casas, Jose A. |
author |
Di Luca, Carla |
author_facet |
Di Luca, Carla Garcia, Jorge Munoz, Macarena Fasce, Laura Alejandra de Pedro, Zahara M. Casas, Jose A. |
author_role |
author |
author2 |
Garcia, Jorge Munoz, Macarena Fasce, Laura Alejandra de Pedro, Zahara M. Casas, Jose A. |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
PHOTO-FENTON ADVANCED OXIDATION PROCESSES NANOPLASTICS SOLID FLUID KINETIC MODEL |
topic |
PHOTO-FENTON ADVANCED OXIDATION PROCESSES NANOPLASTICS SOLID FLUID KINETIC MODEL |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
In this study, kinetic models for the photo-Fenton oxidation of polystyrene nanoplastics(NPs) in water were developed, considering particles with decreasing diameters. Variousreaction parameters affecting the oxidation rate, such as particle size (140−909 nm), agitation speed (250−1000 rpm), and operating temperature (25 and 60 °C) were investigated. Oxidation progress was evaluated through turbidity measurements, TEM, and FTIR analysis, while leached intermediates were identified via Pyr-GC-MS and IC. Due to changes in NPs surface reactivity, the overall reaction rate was divided into two stages, following a freeradical mechanism. Using equations derived from the classic Shrinking Core Model, the oxidation of NPs was determined to proceed under chemical reaction control, with negligible mass transfer limitations. Additionally, the Prout-Tompkins model was found to accurately represent the degradation process. The proposed mechanisms and models provide valuable insights for describing and predicting the advanced oxidation of NPs under different operating conditions and treatment methods. Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Garcia, Jorge. Universidad Autónoma de Madrid; España Fil: Munoz, Macarena. Universidad Autónoma de Madrid; España Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: de Pedro, Zahara M.. Universidad Autónoma de Madrid; España Fil: Casas, Jose A.. Universidad Autónoma de Madrid; España |
description |
In this study, kinetic models for the photo-Fenton oxidation of polystyrene nanoplastics(NPs) in water were developed, considering particles with decreasing diameters. Variousreaction parameters affecting the oxidation rate, such as particle size (140−909 nm), agitation speed (250−1000 rpm), and operating temperature (25 and 60 °C) were investigated. Oxidation progress was evaluated through turbidity measurements, TEM, and FTIR analysis, while leached intermediates were identified via Pyr-GC-MS and IC. Due to changes in NPs surface reactivity, the overall reaction rate was divided into two stages, following a freeradical mechanism. Using equations derived from the classic Shrinking Core Model, the oxidation of NPs was determined to proceed under chemical reaction control, with negligible mass transfer limitations. Additionally, the Prout-Tompkins model was found to accurately represent the degradation process. The proposed mechanisms and models provide valuable insights for describing and predicting the advanced oxidation of NPs under different operating conditions and treatment methods. |
publishDate |
2024 |
dc.date.none.fl_str_mv |
2024-10 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/265086 Di Luca, Carla; Garcia, Jorge; Munoz, Macarena; Fasce, Laura Alejandra; de Pedro, Zahara M.; et al.; Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach; Elsevier Science; Applied Catalysis B: Environmental; 362; 10-2024; 1-44 0926-3373 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/265086 |
identifier_str_mv |
Di Luca, Carla; Garcia, Jorge; Munoz, Macarena; Fasce, Laura Alejandra; de Pedro, Zahara M.; et al.; Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach; Elsevier Science; Applied Catalysis B: Environmental; 362; 10-2024; 1-44 0926-3373 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0926337324010658 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2024.124751 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613154510733312 |
score |
13.070432 |