Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach

Autores
Di Luca, Carla; Garcia, Jorge; Munoz, Macarena; Fasce, Laura Alejandra; de Pedro, Zahara M.; Casas, Jose A.
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this study, kinetic models for the photo-Fenton oxidation of polystyrene nanoplastics(NPs) in water were developed, considering particles with decreasing diameters. Variousreaction parameters affecting the oxidation rate, such as particle size (140−909 nm), agitation speed (250−1000 rpm), and operating temperature (25 and 60 °C) were investigated. Oxidation progress was evaluated through turbidity measurements, TEM, and FTIR analysis, while leached intermediates were identified via Pyr-GC-MS and IC. Due to changes in NPs surface reactivity, the overall reaction rate was divided into two stages, following a freeradical mechanism. Using equations derived from the classic Shrinking Core Model, the oxidation of NPs was determined to proceed under chemical reaction control, with negligible mass transfer limitations. Additionally, the Prout-Tompkins model was found to accurately represent the degradation process. The proposed mechanisms and models provide valuable insights for describing and predicting the advanced oxidation of NPs under different operating conditions and treatment methods.
Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Garcia, Jorge. Universidad Autónoma de Madrid; España
Fil: Munoz, Macarena. Universidad Autónoma de Madrid; España
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: de Pedro, Zahara M.. Universidad Autónoma de Madrid; España
Fil: Casas, Jose A.. Universidad Autónoma de Madrid; España
Materia
PHOTO-FENTON
ADVANCED OXIDATION PROCESSES
NANOPLASTICS
SOLID FLUID KINETIC MODEL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/265086
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/265086
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approachDi Luca, CarlaGarcia, JorgeMunoz, MacarenaFasce, Laura Alejandrade Pedro, Zahara M.Casas, Jose A.PHOTO-FENTONADVANCED OXIDATION PROCESSESNANOPLASTICSSOLID FLUID KINETIC MODELhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this study, kinetic models for the photo-Fenton oxidation of polystyrene nanoplastics(NPs) in water were developed, considering particles with decreasing diameters. Variousreaction parameters affecting the oxidation rate, such as particle size (140−909 nm), agitation speed (250−1000 rpm), and operating temperature (25 and 60 °C) were investigated. Oxidation progress was evaluated through turbidity measurements, TEM, and FTIR analysis, while leached intermediates were identified via Pyr-GC-MS and IC. Due to changes in NPs surface reactivity, the overall reaction rate was divided into two stages, following a freeradical mechanism. Using equations derived from the classic Shrinking Core Model, the oxidation of NPs was determined to proceed under chemical reaction control, with negligible mass transfer limitations. Additionally, the Prout-Tompkins model was found to accurately represent the degradation process. The proposed mechanisms and models provide valuable insights for describing and predicting the advanced oxidation of NPs under different operating conditions and treatment methods.Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Garcia, Jorge. Universidad Autónoma de Madrid; EspañaFil: Munoz, Macarena. Universidad Autónoma de Madrid; EspañaFil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: de Pedro, Zahara M.. Universidad Autónoma de Madrid; EspañaFil: Casas, Jose A.. Universidad Autónoma de Madrid; EspañaElsevier Science2024-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/265086Di Luca, Carla; Garcia, Jorge; Munoz, Macarena; Fasce, Laura Alejandra; de Pedro, Zahara M.; et al.; Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach; Elsevier Science; Applied Catalysis B: Environmental; 362; 10-2024; 1-440926-3373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0926337324010658info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2024.124751info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:25:34Zoai:ri.conicet.gov.ar:11336/265086instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:25:34.891CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach
title Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach
spellingShingle Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach
Di Luca, Carla
PHOTO-FENTON
ADVANCED OXIDATION PROCESSES
NANOPLASTICS
SOLID FLUID KINETIC MODEL
title_short Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach
title_full Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach
title_fullStr Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach
title_full_unstemmed Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach
title_sort Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach
dc.creator.none.fl_str_mv Di Luca, Carla
Garcia, Jorge
Munoz, Macarena
Fasce, Laura Alejandra
de Pedro, Zahara M.
Casas, Jose A.
author Di Luca, Carla
author_facet Di Luca, Carla
Garcia, Jorge
Munoz, Macarena
Fasce, Laura Alejandra
de Pedro, Zahara M.
Casas, Jose A.
author_role author
author2 Garcia, Jorge
Munoz, Macarena
Fasce, Laura Alejandra
de Pedro, Zahara M.
Casas, Jose A.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv PHOTO-FENTON
ADVANCED OXIDATION PROCESSES
NANOPLASTICS
SOLID FLUID KINETIC MODEL
topic PHOTO-FENTON
ADVANCED OXIDATION PROCESSES
NANOPLASTICS
SOLID FLUID KINETIC MODEL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this study, kinetic models for the photo-Fenton oxidation of polystyrene nanoplastics(NPs) in water were developed, considering particles with decreasing diameters. Variousreaction parameters affecting the oxidation rate, such as particle size (140−909 nm), agitation speed (250−1000 rpm), and operating temperature (25 and 60 °C) were investigated. Oxidation progress was evaluated through turbidity measurements, TEM, and FTIR analysis, while leached intermediates were identified via Pyr-GC-MS and IC. Due to changes in NPs surface reactivity, the overall reaction rate was divided into two stages, following a freeradical mechanism. Using equations derived from the classic Shrinking Core Model, the oxidation of NPs was determined to proceed under chemical reaction control, with negligible mass transfer limitations. Additionally, the Prout-Tompkins model was found to accurately represent the degradation process. The proposed mechanisms and models provide valuable insights for describing and predicting the advanced oxidation of NPs under different operating conditions and treatment methods.
Fil: Di Luca, Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Garcia, Jorge. Universidad Autónoma de Madrid; España
Fil: Munoz, Macarena. Universidad Autónoma de Madrid; España
Fil: Fasce, Laura Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: de Pedro, Zahara M.. Universidad Autónoma de Madrid; España
Fil: Casas, Jose A.. Universidad Autónoma de Madrid; España
description In this study, kinetic models for the photo-Fenton oxidation of polystyrene nanoplastics(NPs) in water were developed, considering particles with decreasing diameters. Variousreaction parameters affecting the oxidation rate, such as particle size (140−909 nm), agitation speed (250−1000 rpm), and operating temperature (25 and 60 °C) were investigated. Oxidation progress was evaluated through turbidity measurements, TEM, and FTIR analysis, while leached intermediates were identified via Pyr-GC-MS and IC. Due to changes in NPs surface reactivity, the overall reaction rate was divided into two stages, following a freeradical mechanism. Using equations derived from the classic Shrinking Core Model, the oxidation of NPs was determined to proceed under chemical reaction control, with negligible mass transfer limitations. Additionally, the Prout-Tompkins model was found to accurately represent the degradation process. The proposed mechanisms and models provide valuable insights for describing and predicting the advanced oxidation of NPs under different operating conditions and treatment methods.
publishDate 2024
dc.date.none.fl_str_mv 2024-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/265086
Di Luca, Carla; Garcia, Jorge; Munoz, Macarena; Fasce, Laura Alejandra; de Pedro, Zahara M.; et al.; Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach; Elsevier Science; Applied Catalysis B: Environmental; 362; 10-2024; 1-44
0926-3373
CONICET Digital
CONICET
url http://hdl.handle.net/11336/265086
identifier_str_mv Di Luca, Carla; Garcia, Jorge; Munoz, Macarena; Fasce, Laura Alejandra; de Pedro, Zahara M.; et al.; Modeling polystyrene nanoplastics degradation in water via photo-Fenton treatment: A shrinking-particle approach; Elsevier Science; Applied Catalysis B: Environmental; 362; 10-2024; 1-44
0926-3373
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0926337324010658
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2024.124751
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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